Abstract
Comparative studies were made of the microelement composition of rock samples from Domanik deposits of different lithologo-facial types: from Semiluki–Mendym (Domanik) deposits of the Berezovskaya area and from carbonate domanikoid deposits of the Dankovo–Lebedyan horizon of the Zelenogorskaya area of the Romashkino oilfield. These samples differ in the organic matter (OM) content and in the content and composition of petroleum hydrocarbons (HCs) and kerogen. Distinctive features of the composition and distribution of biogenic, rare earth, and radioactive microelements (MEs) in the initial rocks, rock extracts, and asphaltenes recovered from them were revealed. The Domanik carbonate–silica rock of the Berezovskaya area, in contrast to the carbonate rock of the Zelenogorskaya area, is characterized by diversity and high concentrations of all the ME groups with the highest content of V, Ti, Fe, Zn, Ni, Cu, Cr, Ba, Mo, and Mn. In the carbonate rock from domanikoid deposits of the Zelenogorskaya area, the concentration of these MEs is considerably lower, as well as the concentrations of rare earth and radioactive elements; the group of highly volatile chalcophilic MEs including Ge, Ga, As, Se, Cd, Sb, Te, Re, Hg, Tl, and Bi is virtually absent. Both types of rocks contain Sr. In the extracts and asphaltenes, V, Ni, Fe, and Zn are the most abundant MEs. The highest concentrations of V, Ni, and Zn were detected in carbenes and carboids of the Berezovskaya area. The ME composition suggests different conditions of the OM transformation and ME accumulation in rocks from Domanik deposits of different lithologo-facial types due to different intensity of the development of tectonic processes and supply of deep hydrothermal fluids into the deposit strata on the examined territory of the Romashkino oilfield.
REFERENCES
Stupakova, A.V., Kalmykov, G.A., Korobova, N.I., Fadeeva, N.P., Gatovskii, Yu.A., Suslova, A.A., Sautkin, R.S., Pronina, N.V., Bol’shakova, M.A., Zav’yalova, A.P., Chupakhina, V.V., Petrakova, N.N., and Miftakhova, A.A., Georesursy, 2017, special issue, part 1, pp. 112–124. https://doi.org/10.18599/grs.19.12
Khisamov, R.S., Bazarevskaya, V.G., Mikhailova, O.V., and Podavalov, V.B., Nedropol’zovanie XXI Vek, 2016, no. 3, pp. 82–91.
Anan’ev, V.V., Smelkov, V.M., and Pronin, N.V., Geol. Nefti Gaza, 2007, no. 1, pp. 32–38.
Punanova, S.A. and Nukenov, D., Aktual’n. Probl. Nefti Gaza, 2019, no. 1 (24), pp. 1–20. https://doi.org/10.29222/ipng.2078-5712.2019-24.art5
Nadirov, N.K., Kotova, A.V., Kam’yanov, V.F., Titov, V.I., Aleshin, G.N., Solodukhin, V.P., Bakirova, S.F., Glukhov, G.G., and Koryabina, N.M., Novye nefti Kazakhstana i ikh ispol’zovanie: Metally v neftyakh (New Kazakhstan Crude Oils and Their Use: Metals in Crude Oils), Alma-Ata: Nauka, 1984.
Gottikh, R.P., Grunis, E.B., and Pisotskii, B.I., Geol. Nefti Gaza, 2017, no. 2, pp. 60–70.
Xu, Jian-bing, Cheng, Bin, Deng, Qian, Liang, Yun-gan, Faboya, O. L., and Liao, Ze-wen, Acta Geochim., 2018, vol. 37, no. 6, pp. 886–900. https://doi.org/10.1007/s11631-018-0297-0
Ivanov, K.S., Erokhin, Yu.V., Ronkin, Yu.L., Plotnikova, I.N., and Kayukova, G.P., Carbon Potential of the Foundation of Juvenile and Ancient Platforms: Proc. Int. Scientific Conf., Kazan: Kazan State Univ., Sept. 6–8, 2006, pp. 100–103.
Ivanov, K.S., Biklov, K.Sh., and Erokhin, Yu.V., Vestn. Inst. Geol. Komi Nauchn. Tsentra Ural’sk. Otdel. Ross. Akad. Nauk, 2013, August, pp. 2–6.
Swart, P.K., Sedimentology, 2015, vol. 62, no. 5, pp. 1233–1304. https://doi.org/10.1111/sed.12205
Babaev, F.R. and Punanova, S.A., Geokhimicheskie aspekty mikroelementnogo sostava neftei (Geochemical Aspects of the Microelement Composition of Crude Oils), Moscow: Nedra, 2014.
Punanova, S.A., Georesursy, 2020, vol. 22, no. 2, pp. 45–50. https://doi.org/10.18599/grs.2020.2.45-55
Serebrennikova, O.V., Filippova, T.Yu., and Krasnoyarova, N.A., Petrol. Chem., 2003, vol. 43, no. 3, pp. 145–149.
Yakubov, M.R., Sinyashin, K.O., Abilova, G.R., Tazeeva, E.G., Milordov, D.V., Yakubova, S.G., Borisov, D.N., Gryaznov, P.I., Mironov, N.A., and Borisova, Y.Y., Petrol. Chem., 2017, vol. 57, no. 10, pp. 849–854. https://doi.org/10.1134/S096554411710019X
Punanova, S.A. and Rodkin, M.V., Georesursy, 2019, vol. 21, no. 3, pp. 14–24. https://doi.org/10.18599/grs.2019.3.14-24
Minnegalieva, A.M., Kayukova, G.P., Vandyukova, I.I., Morozov, V.I., and Khasanova, N.M., Tekhnol. Nefti Gaza, 2007, no. 2, pp. 40–47.
Gottikh, R.P., Pisotsky, B.I., and Zhuravlev, D.Z., Dokl. Earth Sci., 2008, vol. 422, no. 7, part 2, pp. 1084–1088. https://doi.org/10.1134/S1028334X08070180
Mukhametshin, R.Z. and Punanova, S.A., Geol. Nefti Gaza, 2011, no. 4, pp. 74–83.
Mikhailova, A.N., Kayukova, G.P., and Gabdrakhmanov, D.T., Mezhdunarodnaya nauchno-prakticheskaya konferentsiya “Uglebvodorodnyi i mineral’no-syr’evoi potentsial kristallicheskogo fundamenta” (Int. Scientific and Practical Conf. “Hydrocarbon and Mineral Resource Potential of Crystalline Foundation”), Kazan, Sept. 2–3, 2019, Kazan: Ikhlas, 2019, pp. 212–215.
Plotnikova, I.N., Ostroukhov, S.B., Laptev, A.A., Gazizov, I.G., Emel’yanov, V.V., Pronin, N.V., Nosova, F.F., and Salikhov, A.D., Georesursy, 2017, vol. 19, no. 4, pp. 348–355. https://doi.org/10.18599/grs.19.4.7
Ostroukhov, S.B., Plotnikova, I.N., Nosova, F.F., and Pronin, N.V., Georesursy, 2015, no. 3–1 (62), pp. 42–46.
Schwark, L. and Frimmel, F., Chem. Geol., 2004, vol. 206, pp. 231–248. https://doi.org/10.1016/j.chemgeo.2003.12.008
Kiseleva, Yu.A., Zheglova, T.P., Dakhnova, M.V., Mozhegova, S.V., Nazarova, E.S., and Nechitailo, G.S., Geol. Geofiz., 2017, vol. 58, no. 3–4, pp. 384–397.
Maganov, N.U., Khisamov, R.S., Bazarevskaya, V.G., Ziyatdinov, Ya.G., Mikhailova, O.V., and Podavalov, V.B., Alternative methods for the development of Domanik deposits, Sbornik trudov TatNIPIneft’ (Coll. of Scientific Works of Tatar Research and Designing Institute of Oil), Moscow: Neftyanoe Khozyaistvo, 2016, pp. 35–40.
Cheng, H., Shi, W., Ding, D., and Zhang, C., Geofluids, 2017, vol. 2017, article ID 3028974. https://doi.org/10.1155/2017/3028974
Lin, L., Lai, D., Shi, Z., Han, Z., and Xu, G., RSC Adv., 2017, no. 7, pp. 21467–21474. https://doi.org/10.1039/C7RA02347B
Khisamov, R.S., Zakirov, I.S., Zakharova, E.F., Bazarevskaya, V.G., Abusalimova, R.R., and Timirov, D.A., Nef. Khozyaystvo-Oil Industry, 2018, no. 11, pp. 78–83. https://doi.org/10.24887/0028-2448-2018-11-78-83
Kayukova, G.P, Mikhailova, A.N., Morozov, V.P., Musin, R.Z., Vandyukova, I.I., Sotnikov, O.S., and Remeev, M.M., Petrol. Chem., 2019, vol. 59, no. 10, pp. 1124–1137. https://doi.org/10.1134/S0965544119100050
Kayukova, G.P., Mikhailova, A.N., Kosachev, I.P., Eskin, A.A., and Morozov, V.I., Petrol. Chem., 2019, vol. 59, no. 1, pp. 24–33. https://doi.org/10.1134/S0965544119010080
Kayukova, G.P., Kiyamova, A.M., Mikhailova, A.N., Kosachev, I.P., Petrov, S.M., Romanov, G.V., Sitdikova, L.M., Plotnikova, I.N., and Vakhin, A.V., Chem. Technol. Fuels Oils, 2016, vol. 52, no. 2, pp. 149–161. https://doi.org/10.1007/s10553-016-0685-2
Kayukova, G.P., Kiyamova, A.M., and Romanov, G.V., Petrol. Chem., 2012, vol. 52, no. 1, pp. 5–14. https://doi.org/10.1134/S0965544111060089
Smirnov, P.V., Batalin, G.A., Gareev, B.I., and Trifonov, A.A., Izv. Tomsk. Politekh. Univ. Inzh. Georesurs., 2020, vol. 331, no. 8, pp. 40–52.
Vernadsky, V.I., Khimicheskoe stroenie biosfery Zemli i ee okruzheniya (Chemical Structure of the Earth Biosphere and Its Surrounding), Moscow: Nauka, 2001.
Kovalsky, V.V., Problemy biogeokhimii mikroelementov i geokhimicheskoi ekologii. Izbrannye trudy (Problems of Biogeochemistry of Microelements and Geochemical Ecology. Selected Works), Ernst, L.K., Ed., Kovalsky, Yu.V., Compiler, Moscow: Rossel’lkhozakademiya, 2009.
Filippova, V.A. and Lysenkova, A.V., Probl. Ekol., 2013, vol. 4, no. 38, pp. 72–78.
ACKNOWLEDGMENTS
The authors are grateful to staff members of the Center for Shared Use–Spectral and Analytical Center for Studying the Structure, Composition, and Properties of Substances and Materials at the Federal Research Center Kazan Scientific Center, Russian Academy of Sciences for the studies performed.
Funding
The study was performed within the framework of the government assignment for the Federal Research Center Kazan Scientific Center, Russian Academy of Sciences. The work of B.I. Gareev, Z.R. Nasyrova, and A.V. Vakhin was supported by the Ministry of Science and Higher Education of the Russian Federation under agreement no. 075-15-2020-931 within the framework of the development program for a world-class Research Center “Efficient development of the global liquid hydrocarbon reserves.”
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Kayukova, G.P., Mikhailova, A.N., Gareev, B.I. et al. Composition and Distribution of Microelements in Rocks, Extracts, and Asphaltenes from Domanik Deposits of Various Lithologo-Facial Types of Romashkino Oilfield. Pet. Chem. 61, 576–587 (2021). https://doi.org/10.1134/S0965544121060086
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DOI: https://doi.org/10.1134/S0965544121060086