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Selective hydrogen combustion over Rh-Sn/Al2O3 catalysts during propane dehydrogenation

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Abstract

A series of Rh-Sn/Al2O3 catalysts were prepared by 0.5 wt% of Rh and varied amounts of Sn from 0 to 3.0 wt%. Rh-Sn catalysts were evaluated to determine if selective hydrogen combustion(SHC) can be effectively applicable to propane dehydrogenation (PDH). PDH is an endothermic reaction and SHC can generate partial heat energy. In this study, two separate SHC reactions were examined. One was to look into the quantification of competitive combustion states over Rh-Sn catalysts in the presence of hydrogen, propylene, oxygen, and nitrogen. The other was to evaluate SHC with Rh-Sn catalysts in the presence of hydrogen, propane, oxygen, and nitrogen. The factor that we entitled A factor, was employed to analyze the effect of Sn amount. The result showed that the best performance was achieved by 0.5Rh-1.5Sn/Al2O3 catalyst for both SHC reactions. Characteristics of catalysts were analyzed by CO chemisorption, XPS, TEM-EDX and TPR.

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Acknowledgement

This work was financed by an industry core-technology project called “Development of high yield propylene production process technology” of the Ministry of Trade, Industry and Energy (project No.: 100052754-Korea Evaluation Institute of Industrial Technology). This work was also financed by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2017R1D1A1B03034244).

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Authors and Affiliations

  1. Department of Chemical Engineering, RCCT, Hankyong National University, Anseong, 17579, Korea

    Jae-Won Jung & Hyoung Lim Koh

  2. Chemical and Environmental Technology Department, Inha Technical College, Inha-ro 100, Michuhol-gu, Incheon, 22212, Korea

    Kyeongseok Oh

  3. Clean Energy Research Center, Korean Institute of Science and Technology, P. O. Box 131, Cheongryang, Seoul, 02792, Korea

    Kwang-Deog Jung

  4. R&D Business Lab., Hyosung Co., 74 Simin-daero, Dongan-gu, Anyang, Gyeounggi, 14080, Korea

    Won Il Kim

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  1. Jae-Won Jung
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  2. Kyeongseok Oh
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Correspondence to Kwang-Deog Jung or Hyoung Lim Koh.

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Jung, JW., Oh, K., Jung, KD. et al. Selective hydrogen combustion over Rh-Sn/Al2O3 catalysts during propane dehydrogenation. Korean J. Chem. Eng. 38, 1197–1204 (2021). https://doi.org/10.1007/s11814-021-0769-5

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  • DOI: https://doi.org/10.1007/s11814-021-0769-5

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