Skip to main content
SpringerLink
Log in

Various Types of Combustion of a Ti + C Granular Mixture with a Different Content of the Gasifying Additive

  • Published:
Combustion, Explosion, and Shock Waves Aims and scope

Abstract

This paper touches upon the effect of a polyvinyl butyral content (0–2.3%) on the combustion of a Ti + C granular mixture with different types of titanium. Experiments are carried out with no external gas flow, so conductive combustion is expected to be observed due to a low decomposition temperature and a small amount of polyvinyl butyral. However, convective combustion is manifested in rapidly burning mixtures because the granule surface is ignited with hot gaseous decomposition products of polyvinyl butyral. It is explained how undecomposed polyvinyl butyral falls behind the ignition front, and it is revealed that the type of combustion of the Ti + C granular mixture depends on its burning rate in the case where no gas flows through the sample. Based on the experimental and theoretical analysis of the combustion process, it is established that granules are ignited during convective combustion at a temperature of the \(\alpha \to \beta\) transition in titanium. The different effect of a polyvinyl butyral content on slowly and rapidly burning Ti + C mixtures is qualitatively explained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

REFERENCES

  1. A. Varma and A. S. Mukasyan, “Combustion Synthesis of Advanced Materials: Fundamentals and Applications," Korean J. Chem. Eng.21 (2), 527–536 (2004).

    Article  Google Scholar 

  2. K. V. Manukyan, Y.-C. Lin, S. Rouvimov, et al., “Microstructure–Reactivity Relationship of Ti + C Reactive Nanomaterials," J. Appl. Phys. 113, 024302 (2013); doi.org/10.1063/1.4773475.

  3. H. H. Nersisyan, J. H. Lee, J.-R. Ding, et al., “Combustion Synthesis of Zero-, One-, Two- and Three-Dimensional Nanostructures: Current Trends and Future Perspectives," Prog. Energy Combust. Sci. 63, 79–118 (2017); dx.doi.org/10.1016/j.pecs.2017.07.002.

    Article  Google Scholar 

  4. B. S. Seplyarskii, “The Nature of the Anomalous Dependence of the Velocity of Combustion of ‘Gasless’ Systems on the Sample Diameter," Dokl. Akad. Nauk 396 (5), 640–643 (2004) [Dokl. Phys. Chem. 396 (5), 130–133 (2004)].

  5. B. S. Seplyarskii and S. G. Vadchenko, “Role of Convective Heat Transfer in Gasless Combustion by the Example of Combustion of the Ti–C System," Dokl. Akad. Nauk 398 (1), 72–76 (2004) [Dokl. Phys. Chem. 398 (1), 203–207 (2004)].

  6. B. S. Seplyarskii, S. G. Vadchenko, S. V. Kostin, and G. B. Brauer, “Combustion of Ti+0.5C and Ti+C Mixtures of Bulk Density in Inert Gas Coflow," Fiz. Goreniya Vzryva 45 (1), 30–37 (2009) [Combust., Expl., Shock Waves 45 (1), 25–31 (2009)].

  7. A. Varma and J.-P. Lebrat, “Combustion Synthesis of Advanced Materials," Chem. Eng. Sci. 47 (9-11), 2179–2194 (1992).

    Article  Google Scholar 

  8. A. I. Kirdyashkin, Yu. M. Maksimov, and E. A. Nekrasov, “Titanium–Carbon Interaction Mechanism in a Combustion Wave," Fiz. Goreniya Vzryva 17 (4), 33–36 (1981) [Combust., Expl., Shock Waves 17 (4), 25–31 (1981)].

  9. M. A. Ponomarev, V. A. Shcherbakov, and A. S. Shteinberg, “Combustion of Thin Layers of a Titanium–Boron Powder Mixture," Dokl. Akad. Nauk 340 (5), 642–645 (1995).

  10. A. K. Filonenko, V. A. Bunin, and V. I. Vershinnikov, “Burning Rate versus Diameter for Some Gasless Compositions," Khim. Fiz.1 (2), 260–264 (1982).

    Google Scholar 

  11. B. S. Seplyarskii and R. A. Kochetkov, “Combustion of Powder and Ti + xC (\(x>0.5\)) Granular Compositions in a Cocurrent Gas Flow," Khim. Fiz.36 (9), 23–31 (2017); DOI: 10.7868/S0207401X17090126.

  12. B. S. Seplyarskii and R. A. Kochetkov, “Granulation as a Tool for Stabilization of SHS Reactions," Int. J. Self-Propag. High-Temp. Synth. 26 (2), 134–136 (2017); DOI: 10.3103/S106138621702011X.

    Article  Google Scholar 

  13. N. A. Kochetov and S. G. Vadchenko, “Effect of the Time of Mechanical Activation of a Ti + 2B Mixture on Combustion of Cylindrical Samples and Thin Foils," Fiz. Goreniya Vzryva51 (4), 77–81 (2015) [Combust., Expl., Shock Waves51 (4), 467–471 (2015)]; DOI: 10.1134/S0010508215040103.

  14. A. G. Merzhanov and A. S. Mukas’yan, Solid-Flame Combustion (Torus Press, Moscow, 2007) [in Russian].

  15. B. S. Seplyarskii, R. A. Kochetkov, T. G. Lisina, et al., “Phase Composition and Structure of Titanium Carbide/Nickel Binder Synthesis Products," Neorg. Mater. 5 (11), 1169–1175 (2019) [Inorg. Mater. 55 (11), 1104–1110 (2019)]; DOI: 10.1134/S0002337X19110113.

  16. A. A. Zenin, A. G. Merzhanov, and G. A. Nersisyan, “Thermal Wave Structure in SHS Processes (by the Example of Boride Synthesis)," Fiz. Goreniya Vzryva 17 (1), 79–90 (1981) [Combust., Expl., Shock Waves 17 (1), 63–71 (1981)].

  17. B. S. Seplyarskii, R. A. Kochetkov, and T. G. Lisina, “Convective Combustion of a Ti + 0.5C Granulated Mixture. Domain of Existence and Fundamental Phenomena," Fiz. Goreniya Vzryva 55 (3), 57–62 (2019) [Combust., Expl., Shock Waves 55 (3), 295–299 (2019)]; 10.1134/S0010508219030079.

  18. A. V. Lykov, Theory of Thermal Conductivity(Vysshaya Shkova, Moscow, 1967) [in Russian].

  19. N. G. Kasatskii, V. M. Filatov, and Yu. S. Naiborodenko,Self-Propagating High-Temperature Synthesis (Izd. Tomsk. Univ., Tomsk, 1991) [in Russian].

  20. M. A. Gol’dshtik, Transfer Processes in a Grain Layer (Kutateladze Institute of Thermophysics of the Siberian Branch of the Academy of Sciences of the USSR, Novosibirsk, 1984) [in Russian].

  21. L. K. Gusachenko, V. E. Zarko, A. D. Rychkov, and N. Yu. Shokina, “Filtration Combustion of an Energetic Material in a Cocurrent Flow of Its Combustion Products. Critical Combustion Conditions," Fiz. Goreniya Vzryva 39 (6), 97–103 (2003) [Combust., Expl., Shock Waves 39 (6), 694–700 (2003)].

  22. B. S. Seplyarskii, R. A. Kochetkov, and T. G. Lisina, “Theoretical and Experimental Method for Calculating the Conditions of the Convective Mode of Combustion," Khim. Fiz. 38 (3), 24–29 (2019) [Russian Journal of Phys. Chem. B. 13 (2), 267–272 (2019)]; DOI: 10.1134/S0207401X19030063.

  23. B. S. Seplyarskii, R. A. Kochetkov, and T. G. Lisina, “Coflow Combustion in Granulated Ti + xC Mixtures: Boundary Conditions for Convection-Driven Wave Propagation," Int. J. Self-Propag. High-Temp. Synth. 28 (3), 183–186 (2019); DOI: 10.3103/s1061386219030129.

    Article  Google Scholar 

  24. B. S. Seplyarskii et al., “Combustion of Granulated Ti—C Blends: Influence of Granule Size," Int. J. Self-Propag. High-Temp. Synth. 29 (2), 126–127 (2020); DOI: 10.3103/s1061386220020090.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    B. S. Seplyarskii, R. A. Kochetkov, T. G. Lisina & N. I. Abzalov

Authors
  1. B. S. Seplyarskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. A. Kochetkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. G. Lisina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. I. Abzalov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. S. Seplyarskii.

Additional information

Translated from Fizika Goreniya i Vzryva, 2021, Vol. 57, No. 3, pp. 88–96.https://doi.org/10.15372/FGV20210308.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Seplyarskii, B.S., Kochetkov, R.A., Lisina, T.G. et al. Various Types of Combustion of a Ti + C Granular Mixture with a Different Content of the Gasifying Additive. Combust Explos Shock Waves 57, 334–342 (2021). https://doi.org/10.1134/S0010508221030084

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0010508221030084

Keywords

Search

Navigation