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Accurate Measurement of Thermo-optical Parameters of Trichloromethane–Alcohol Mixtures by Laser Thermal Lens Spectroscopy

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Abstract

The laser thermal lens spectroscopy (TLS) was used to measure the thermo-optical parameters of alcohols(1)–trichloromethane(2) binary mixtures with high accuracy. Using this spectroscopic method, the thermal lens characteristic time (tc), thermal diffusivity (Dth), thermal conductivity (k), thermo-optic coefficient (dn/dT), and the refractive index changes with the sample deposited heat (dn/dQ) were measured for each of the pure components of this binary mixture at 298 K and fixed laser energy. The experimental results are in good agreement with the reference data. Then, for these binary mixtures, the dependency of k, dn/dT, and dn/dQ on the concentration was obtained and molecularly analyzed. The results show that increasing the volume fraction of alcohol in these binary mixtures leads to increasing k, dn/dT, and dn/dQ of these binary mixtures.

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  1. Department of Physics, Faculty of Science, Malayer University, Malayer, Iran

    M. R. Mohebbifar

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Mohebbifar, M.R. Accurate Measurement of Thermo-optical Parameters of Trichloromethane–Alcohol Mixtures by Laser Thermal Lens Spectroscopy. Int J Thermophys 42, 117 (2021). https://doi.org/10.1007/s10765-021-02872-3

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