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Negative thermal expansion: Mechanisms and materials

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Abstract

Negative thermal expansion (NTE) of materials is an intriguing phenomenon challenging the concept of traditional lattice dynamics and of importance for a variety of applications. Progresses in this field develop markedly and update continuously our knowledge on the NTE behavior of materials. In this article, we review the most recent understandings on the underlying mechanisms (anharmonic phonon vibration, magnetovolume effect, ferroelectrorestriction and charge transfer) of thermal shrinkage and the development of NTE materials under each mechanism from both the theoretical and experimental aspects. Besides the low frequency optical phonons which are usually accepted as the origins of NTE in framework structures, NTE driven by acoustic phonons and the interplay between anisotropic elasticity and phonons are stressed. Based on the data documented, some problems affecting applications of NTE materials are discussed and strategies for discovering and design novel framework structured NET materials are also presented.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 11874328, 11774078, and 21905252) and China Postdoctoral Science Foundation (No. 2019M652558).

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  1. Key Laboratory of Materials Physics of Ministry of Education of China, and School of Physics & Microelectronics, Zhengzhou University, Zhengzhou, 450001, China

    Erjun Liang, Qiang Sun, Huanli Yuan, Jiaqi Wang, Gaojie Zeng & Qilong Gao

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  1. Erjun Liang
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Special Topic: Thermodynamics and Thermal Metamaterials (Editor: Ji-Ping Huang). This article can also be found at http://journal.hep.com.cn/fop/EN/10.1007/s11467-021-1070-0.

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Liang, E., Sun, Q., Yuan, H. et al. Negative thermal expansion: Mechanisms and materials. Front. Phys. 16, 53302 (2021). https://doi.org/10.1007/s11467-021-1070-0

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