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A Zr-Substituted Polyoxotungstate Built by [β-GeW10O38]12− and [A-α-PW9O34]9− Fragments: Synthesis, Structure and Properties

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Abstract

A new Zr-substituted polyoxotungstate, [H2N(CH3)2]11KNa5H7[Zr4K2(β-GeW10O38)2(A-α-PW9O34)2]·39H2O (1), has been hydrothermally synthesized and characterized by single crystal X-ray diffraction, IR spectrum, UV–vis diffuse-reflectance spectrum, elemental analysis, powder X-ray diffraction, ICP-MS test and thermogravimetric analysis. The prominent feature of 1 is that mixed Keggin-type dilacunary [β-GeW10O38]12− fragment and trilacunary [A-α-PW9O34]9− fragment construct the basic framework of 1. And 1 displays special 1D double-chain and 2D thick layer formed by K+/Na+ ions. 1 exhibits well electrocatalytic behavior in the reduction of BrO3−. Also, the experimental results of catalytic oxidation of representative thioethers manifest that 1 possesses a good catalytic capacity.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 21831001, 21571016, 91122028) and the National Natural Science Foundation of China for Distinguished Young Scholars (No. 20725101).

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  1. MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China

    Yuan-Hui Sheng, Jun-Jun Sun, Peng-Yun Zhang & Guo-Yu Yang

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Correspondence to Guo-Yu Yang.

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Sheng, YH., Sun, JJ., Zhang, PY. et al. A Zr-Substituted Polyoxotungstate Built by [β-GeW10O38]12− and [A-α-PW9O34]9− Fragments: Synthesis, Structure and Properties. J Clust Sci 33, 1677–1684 (2022). https://doi.org/10.1007/s10876-021-02065-w

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