Abstract
Polyurethane (PU)/poly(lactic acid) (PLA) blends having different weight ratios (80:20, 60:40, 50:50, 40:60 and 20:80) were prepared in a suitable solvent environment. A new non-woven fiber surface with a single structure was obtained from the prepared PU/PLA blend solutions by electrospinning method. The effect of different weight ratios on the characteristic properties of PU/PLA fibers was investigated. The obtained electrospun mats were characterized by thermogravimetric analysis (TGA), scanning electron microscopy (SEM), X-ray diffractometry (XRD), differential scanning calorimetry (DSC), Fourier-transform infrared spectroscopy (FTIR), tensile and contact angle tests. The most homogeneous fiber distribution was observed at the structure of 6PU/4PLA (60PU:40PLA w/w) nanofiber. Besides, this fiber was determined to have the highest strength and tensile strain-at-break. Among all fibers, the highest contact angle was observed for 8PU/2PLA (80PU:20PLA w/w) fiber, indicating a hydrophobic structure. According to the DSC results, the melting values of the soft and hard segments of pure PU showed only a melting peak. In XRD results, all electrospun mats which were obtained by blending PLA and PU showed a semi-crystalline structure with low crystallinity. However, these specified fibers showed the thinnest diameter. Thanks to PU/PLA fibers, a new, thinner and more flexible biodegradable surface with perfectly good physical and mechanical properties was obtained. It is expected that the obtained PU/PLA fibers will find a wide range of applications in filtration, liquid-repellent surfaces, medical as wound dressing, and industrial fields.
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References
Huang ZM, Zhang YZ, Kotaki M, Ramakrishna S (2003) A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Compos Sci Technol 63:2223–2253
Tijing LD, Ruelo MTG, Amarjargal A, Pant HR, Park CH, Kim DW, Kim CS (2012) Antibacterial and superhydrophilic electrospun polyurethane nanocomposites fibers containing tourmaline nanoparticles. Chem Eng J 197:41–48
Shi Q, Vitchuli N, Nowak J, Noar J, Caldwell JM, Breidt F, Bourham M, McCord M, Zhang XW (2011) One-step synthesis of silver nanoparticle-filled nylon 6 nanofibers and their antibacterial properties. J Mater Chem 21:10330–10335
Nataraj S, Yang K (2012) Polyacrylonitrile-based nanofibers A state of the art review. Polym Sci 37:487–513
Auras R, Harte B, Selke S (2004) An overview of polylactides as packaging materials. Macromol Biosci 4:835–864
Vink ET, Rabago KR, Glassner DA, Gruber PR (2003) Applications of life cycle assessment to NatureWorksTM polylactide (PLA) production. Polym Degrad Stabil 80:403–419
Vink ET, Rábago K, Glassner DA, Springs B, Q’Connor RP, Kolstad J (2004) The sustainability of NatureworksTM polylactide polymers and IngeoTM polylactide fibersa: an update of the future. Macromol Biosci 4:551–564
Hazer S, Çoban M, Aytaç A (2018) A study on carbon fiber reinforced poly(lactic acid)/polycarbonate composites. J Appl Polym Sci 135:46881–46890
Seki M, Sato K, Yosomiya R (1992) Polyurethane elastomer-LiCIO4 complexes as a polymeric solid electrolyte. Macro Chem Phys 193:2971–2980
Vanheumen JD, Stevens JR (1995) The role of lithium salts in the conductivity and phase morphology of a thermoplastic polyurethane. Macromolecules 28:4268–4277
Kuo HH, Chen WC, Wen TC, Gopalan A (2002) A novel composite gel polymer electrolyte for rechargeable lithium batteries. J Power Sources 110:27–33
Du YL, Wen TC (2001) The feasibility study of composite electrolytes comprising thermoplastic polyurethane and poly(ethylene oxide). Mater Chem Phys 71:62–69
Santhosh P, Vasudevan T, Gopalan A, Lee KP (2006) Preparation and characterization of polyurethane/poly(vinylidene fluoride) composites and evaluation as polymer electrolytes. Mater Sci Eng B 135:65–73
Long J, Liu B, Zhang J (2009) Properties of poly(lactic acid)/poly(butylene adipate-co-terephthalate)/nanoparticle ternary composites. Ind Eng Chem Res 48:7594–7602
Han JJ, Huang HX (2011) Preparation and characterization of biodegradable polylactide/thermoplastic polyurethane elastomer blends. J Appl Polym Sci 120:3217–3223
Feng F, Ye L (2011) Morphologies and mechanical properties of polylactide/thermoplastic polyurethane elastomer blends. J Appl Polym Sci 119:2778–2783
Li Y, Shimizu H (2007) Toughening of polylactide by melt blending with a biodegradable poly(ether)urethane elastomer. Macromol Biosci 7:921–928
Pachon EYG, Graziano RV, Campos RM (2014) Structure of poly(lactic-acid) PLA nanofibers scaffolds prepared by electrospinning. IOP Conf Series Mat Sci Eng 59:012003
Touny AH, Bhaduri SB (2010) A reactive electrospinning approach for nanoporous PLA/monetite nanocomposite fibers. Mater Sci Eng C 30:1304–1312
Huang C, Thomas NL (2018) Fabricating porous poly(lactic acid) fibres via electrospinning. EurPolym J 99:464–476
Lee K, Lee B, Kim C, Kim H, Kim K, Nah C (2005) Stress-strain behavior of the electrospun thermoplastic polyurethane elastomer fiber mats. Macromol Res 13:441–445
Lee S, Obendorf S (2007) Use of electrospun nanofiber web for protective textile materials as barriers to liquid penetration. Textile Res J 77:696–702
Yuryev Y, Mohanty AK, Misra M (2017) Novel biocomposites from biobased PC/PLA blend matrix system for durable applications. Compos B 130:158–166
Schiffman JD, Schauer CL (2007) Cross-linking chitosan nanofibers. Biomacromol 8:594–601
Zhao YY, Yang QB, Lu XF, Wang C, Wei Y (2005) Study on correlation of morphology of electrospun products of polyacrylamide with ultrahigh molecular weight. J Polym Sci B 43:2190–2195
Xu J, Zhang J, Gao W, Liang H, Wang H, Li J (2009) Preparation of chitosan/PLA blend micro/nanofibers by electrospinning. Mater Lett 63:658–660
Pradhan KC, Nayak PL (2012) Synthesis and characterization of polyurethane nanocomposite from castor oil- hexamethylene diisocyanate (HMDI). Adv Appl Sci Res 5:3045–3052
Raja M, Ryu SH, Shanmugharaj AM (2013) Thermal, mechanical and electroactive shape memory properties of polyurethane (PU)/poly (lactic acid) (PLA)/CNT nanocomposites. Eur Polym J 49:3492–3500
Silva GG, Calado HDR, Musumeci AW, Martens W, Waclawik ER (2006) Polymer nanocomposites based on P3OT, TPU and SWNT: preparation and characterization. Int Conf Nanosc Nanotech 2006 IEEE, https://doi.org/10.1109/ICONN.2006.340581
Deshmukh KA, Khajanji P, Chopra S, Deshmukh A, Peshwe DR (2020) The influence of micro-graphite addition on nucleation efficiency and isothermal crystallization kinetics of thermoplastic polyurethane (TPU). Mater Today Proc 28:642–650
Lostocco MR, Huang SJ (1998) The hydrolysis of poly(lactic acid)/poly(hexamethylene succinate) blends. Poly Degrad Stabil 61:225–230
Ploypetchara N, Suppakula P, Atong D, Pechyena C (2014) Blend of polypropylene/poly(lactic acid) for medical packaging application: physicochemical, thermal, mechanical, and barrier properties. Energy Procedi 56:201–210
Yuan Y, Ruckenstein E (1998) Polyurethane toughened polylactide. Polym Bull 40:485–490
Lai SM, Lan YC (2013) Shape memory properties of melt-blended polylactic acid(PLA)/thermoplastic polyurethane (TPU) bio-based blends. J Polym Res 20:140–148
Trovati G, Sanches EA, Neto SC, Mascarenhas YP, Chiericeet GO (2010) Characterization of polyurethane resins by FTIR, TGA and XRD. Inc J Appl Polym Sci 115:263–268
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Samatya Yilmaz, S., Aytac, A. Poly(lactic acid)/polyurethane blend electrospun fibers: structural, thermal, mechanical and surface properties. Iran Polym J 30, 873–883 (2021). https://doi.org/10.1007/s13726-021-00944-7
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DOI: https://doi.org/10.1007/s13726-021-00944-7