Abstract
In this study, the synthesis of MIL-53(Al) (Material Institute Lavoisier, MIL) material, which is an aluminum-containing metal–organic framework (MOF) and generally produced using the solvothermal method was carried out by microwave method at different synthesis times (30–180 min) and temperatures (120–180 °C). In order to improve the catalytic activity of the MIL-53(Al), it was functionalized by applying sulfonation process and SO3-MIL-53(Al) material was also provided. It has been observed that the changing in the synthesis time and temperature cause changes in the morphologies, surface areas and thermal resistance. The highest surface area value was obtained as 1256.3 m2/g at 180 °C–180 min synthesis condition. MIL-53(Al) and SO3-MIL-53(Al) were investigated as catalysts for the esterification of the oleic acid with methanol by designing response surface methodology (RSM). The SO3-MIL-53(Al) catalyst provided higher conversion of oleic acid to ester than MIL-53(Al) as 97.2% and 65.9%, respectively. The oleic acid esterification reaction for MIL-53(Al) and SO3-MIL-53-(Al) followed the pseudo-first-order kinetics and activation energy values were determined as 22.87 kJ mol−1 and 16.14 kJ mol−1, respectively.
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Acknowledgements
We would like to thank Mersin University Advanced Technology, Education, Research and Application Center (MEITAM), where we benefit from the infrastructure facilities and Mersin University Scientific Research Projects Unit (BAP) (2017-2-TP3-2621) for their financial support.
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Gecgel, C., Turabik, M. Synthesis and Sulfonation of an Aluminum-Based Metal–Organic Framework with Microwave Method and Using for the Esterification of Oleic Acid. J Inorg Organomet Polym 31, 4033–4049 (2021). https://doi.org/10.1007/s10904-021-02027-9
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DOI: https://doi.org/10.1007/s10904-021-02027-9