Abstract
The paper provides experimentally determined thermokinetics of the thermal decomposition of high-viscosity oil (HVO) from the Karazhanbas field, the Republic of Kazakhstan, in the presence of a Fe3O4 nanocatalyst, catalytic additives (nickel catalytic additives in microspheres prepared from coal ash), and polymers (such as polyethylene glycol and polystyrene) as hydrogen donors. The HVO decomposition thermokinetics (activation energy, pre-exponential factor, and rate constants), depending on the presence of nanocatalysts, catalytic additives, and/or polymers, were estimated by thermogravimetry methods in an inert nitrogen atmosphere. The experimental data (including HVO weight loss and weight loss rate vs. temperature) and the estimated thermokinetics of HVO decomposition can be used to create a database appropriate for mathematical modeling of the processing of HVO and heavy oil residues.
REFERENCES
Ali, M.F., Siddiqui, M.N., and Redhwi, H.H., J. Mater. Cycles Waste Manag., 2004, vol. 6, no. 1, pp. 2734. https://doi.org/10.1007/s10163-003-0102-x
Siddiqui, M.N. and Redhwi, H.H., J. Anal. Appl. Pyrolysis., 2009, vol. 86, no. 1, pp. 141–147. https://doi.org/10.1016/j.jaap.2009.05.002
Ali, M.F. and Qureshi, M.S., Petrol. Sci. Technol., 2013, vol. 31, no. 16, pp. 1655–1673. https://doi.org/10.1080/10916466.2010.551239
Ali, M.F. and Siddiqui, M.D., J. Anal. Appl. Pyrol., 2005, vol. 74, nos. 1–2, pp. 282–289. https://doi.org/10.1016/j.jaap.2004.12.010
Ahmaruzzaman, M. and Sharma, D.K., Energy Fuels, 2006, vol. 20, no. 6, pp. 2498–2503. https://doi.org/10.1021/ef060070c
Kadiev, H.M., Dandaev, A.U., Guul’maliev, A.M., Batov, A.E., and Khadzhiev, S.N., Khim. Tverd. Topliva, 2013, no. 2, pp. 65–72. https://doi.org/10.7868/S0023117713020059
Gringolts, M.L., Dement’ev, K.I., Kadiev, H.M., Maksimov, A.L., and Finkel’shtein, E.Sh., Petrol. Chem., 2020, no. 4, pp. 751–761. https://doi.org/10.31857/S002824212004005X
Yizhao, L., Fengyun, M., Xintai, S., Chao, S., Jian-chao, L., Zhiqiang, S., and Yanglong, H., Catal. Commun., 2012, no. 26, pp. 231–234. https://doi.org/10.1016/j.catcom.2012.06.002
Zimon, A.D., Liquid Adhesion and Wetting, Moscow: Khimiya, 1974.
Kopytov, M.A., Golovko, A.K., Kirik, N.P., and Anshits, A.G., Petrol. Chem., 2013, vol. 53, no. 1, pp. 14–19. https://doi.org/10.1134/S0965544113010076
Aitbekova, D.E., Ma, F.J., Meiramov, M.G., Baikenova, G.G., Kumakov, F.E., Tusipkhan, A., Mukhametzhanova, S.K., and Baikenov, M.I., Khim. Tverd. Topliva, 2019, vol. 53, no. 4, pp. 46–55. https://doi.org/10.1134/S0023117719040029
Kuznetsov, B.N., Glubokaya pererabotka burykh uglei s polucheniem zhidkikh topliv i uglerodnykh materialov (Deep Processing of Brown Coal to Obtain Liquid Fuels and Carbon Materials), Novosibirsk: Sib. Otd. Ross. Akad. Nauk, 2012.
Dominguez, A., Blanco, C.G., and Barriocanal, C., J. Chromatograph. A, 2001, vol. 918, no. 1, pp. 135–144. https://doi.org/10.1016/S0021-9673(01)00736-1
Fettes, E.M., Chemical Reactions of Polymers, New York: John Wiley and Sons, 1964.
Totten, G.E. and Clinton, N.A., Macromol. Chem. Phys., 1988, vol. 28, no. 2, pp. 293–337. https://doi.org/10.1080/15583728808085378
Ji, C., Scott, K.S., Jonathan, G.H., and Robin, D.R., Green Chem., 2005, no. 7, pp. 64–82. https://doi.org/10.1039/B413546F
Pereira, J.F., Kurnia, K.A., Freire, M.G., Coutinho, J.A., and Rogers, R.D., ChemPhysChem., 2015, vol. 16, no. 10, pp. 2219–2225. https://doi.org/10.1002/cphc.201500146
Gyul’maliev, A.M., Golovin, G.S., and Gladun, T.G., Teoreticheskie osnovy khimii uglya (Theoretical Foundations of Coal Chemistry), Moscow: Mosk. Gos. Univ., 2003.
Papkov, V.S. and Slonimskii, G.L., Vysokomol. Soedin., 1966, vol. 8, no. 1, pp. 80–87.
Bukvareva, O.F., Buharkina, T.V., Kinetika i termokhimiya protsessov termodestruktsii uglerodsoderzhashchikh veshchestv (Kinetics and Thermochemistry of the Processes of Thermal Destruction of Carbon-Containing Substances), Moscow: RHTU im. D.I. Mendeleeva, 2001.
Lyrshchikov, S.Y., Strizhak, P.A., and Shevyrev, S.A., Coke Chem., 2016, vol. 59, no. 7, pp. 264–270. https://doi.org/10.3103/S1068364X16070048
Strizhakov, D.A., Yusevich, A.I., Yurachka, V.V., Kadiev, H.M., Agabekov, V.E., and Khadzhiev, S.N., Petrol. Chem., 2016, vol. 56, no. 8, pp. 703–710. https://doi.org/10.1134/S0965544116080168
Funding
The work was carried out as part of the Research Program “Thermochemical processing of heavy oil residues mixed with low-temperature coal tar in the atmosphere of coke gas” with financial support from the Ministry of Education and Science of the Republic of Kazakhstan (grant inv. no. 0215RK969).
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Translated from Neftekhimiya, 2021, Vol. 61, No. 3, pp. 319–327 https://doi.org/10.31857/S0028242121030035.
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Yedrissov, A.T., Aitbekova, D.E., Tusipkhan, A. et al. TGA-Based Thermokinetics of High-Viscosity Oil Decomposition in the Presence of Nanocatalysts, Catalytic Additives, and Polymers. Pet. Chem. 61, 431–437 (2021). https://doi.org/10.1134/S0965544121050157
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DOI: https://doi.org/10.1134/S0965544121050157