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Effect of the Addition of Cerium Acetylacetonate on the Synthesis of ZnO Nanopowder

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Abstract

The effect of the addition of cerium acetylacetonate on the solvothermal synthesis of zinc oxide nanopowder, a promising receptor material for chemical gas sensors, was studied. The obtained products were characterized by DSC/TGA, X-ray powder diffraction analysis, Raman spectroscopy, and scanning and transmission electron microscopy. It was found that an increase in the content of the cerium acetylacetonate additive causes a shift of the maximum of the exothermic event in the DSC curves toward lower temperatures (from 323 to 277°C). The produced ZnO powders have a hexagonal crystal structure of the wurtzite type; no cerium-containing phases were observed. The unit cell parameters of ZnO nanopowders were calculated by the full-profile X-ray phase analysis. It was shown that an increase in the [Ce(O2C5H7)2] leads to noticeable changes in the microstructure of the products.

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Funding

This work was supported by the Russian Science Foundation (project no. 20-73-00309).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. S. Mokrushin, N. P. Simonenko, T. L. Simonenko, E. P. Simonenko, V. G. Sevastyanov & N. T. Kuznetsov

  2. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    I. A. Nagornov

  3. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 199071, Moscow, Russia

    A. A. Averin

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  1. A. S. Mokrushin
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  2. I. A. Nagornov
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Correspondence to A. S. Mokrushin.

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Mokrushin, A.S., Nagornov, I.A., Averin, A.A. et al. Effect of the Addition of Cerium Acetylacetonate on the Synthesis of ZnO Nanopowder. Russ. J. Inorg. Chem. 66, 638–644 (2021). https://doi.org/10.1134/S0036023621050119

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