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Dynamics of Acetamiprid Decomposition in Grapes and Grape Juice

  • PLANT PROTECTION
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Russian Agricultural Sciences Aims and scope

Abstract

Acetamiprid belongs to the modern systemic neonicotinoid insecticides. The acetamipride content in grapes and grape juice was determined after double treatment of vegetative plants with the insecticide Mospilan SP (200 g/kg) with a recommended rate of 0.35 kg/ha in Krasnodar region and the Republic of Crimea. A quantitative evaluation of its residual amounts was performed and degradation dynamics were studied. The analytical method was based on the determination of acetamipride content using reverse phase high-performance liquid chromatography (HPLC) with a triple quadrupole mass detector in the dynamic multireaction monitoring mode. It was found that acetamiprid was absent in grapes and in harvest samples 15 days after the last treatment. The application of Mospilan SP on grapes is safe if all application regulations are kept.

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REFERENCES

  1. Petrova, M.O. and Chermenskaya, T.D., Search for pesticide residues in agricultural products: The way to safe food, Biosfera, 2019, vol. 11, no. 1, pp. 40–47.

    Google Scholar 

  2. The State Catalog of Pesticides and Agrochemicals Permitted for Use on the Territory of the Russian Federation, Prilozh. Zh. Zashch. Karantin Rast., 2020, no. 4.

  3. The Pesticide Manual, Tomlin, C., Ed., Surrey: BCPC, 2003, 13th ed.

    Google Scholar 

  4. MU № 2051-79. Unifitsirovannye pravila otbora prob sel’skokhozyaistvennoi produktsii, produktov pitaniya i ob”ektov okruzhayushchei sredy dlya opredeleniya mikrokolichestv pestitsidov (MU no. 2051–79: Unified Rules for Sampling Agricultural Products, Food Products, and Environmental Objects for Determination of Trace Amounts of Pesticides), Moscow: Minzdrav SSSR, 1979.

  5. Dolzhenko, V.I., Laptiev, A.B., Burkova, L.A., et al., Metodicheskie ukazaniya po registratsionnym ispytaniyam pestitsidov v chasti biologicheskoi effektivnosti. Obshchaya chast’ (Guidelines for Registration Tests of Pesticides in Terms of Biological Effectiveness. The General Part), Moscow: Minsel’khoz Ross., 2018.

  6. MUK 4.1.3351–16: Mnogoostatochnoe opredelenie pestitsidov razlichnoi khimicheskoi prirody v produktsii rastenievodstva: Metodicheskie ukazaniya (MUK 4.1.3351–16: Multiple Determination of Pesticides of Various Chemical Nature in Crop Production: Methodological Guidelines), Moscow: Fed. Tsentr Gig. Epidemiol. Rospotrebnadzora, 2016.

  7. Zhou, L.Y., Zhang, L.J., Sun, S.L., et al., Degradation of the neonicotinoid insecticide acetamiprid via the N-carbamoylimine derivate (IM-1-2) mediated by the nitrile hydratase of the nitrogenfixing bacterium Ensifer meliloti CGMCC 7333, Agric. Food Chem., 2014, vol. 62, no. 41, pp. 9957–9964.

    Article  CAS  Google Scholar 

  8. Lazić, S., Sunjka, D., and Jovanov, P., LC-MS/MS determination of acetamiprid residues in sweet cherries, Rom. Biotechnol. Lett., 2017, vol. 23, no. 1, pp. 13317–13326.

    Google Scholar 

  9. Jun, W., Qing, Z., and Zhong-Cheng, G., Determination of acetamiprid and imidacloprid residues in tobacco by UPLC-MS/MS, Tob. Sci. Technol., 2010, vol. 10, pp. 41–43.

    Google Scholar 

  10. Ye, J., Wu, J., and Qin, F., Analysis of 213 pesticide residues in grapes by LC-MS/MS with time-managed MRM, Food Beverage, 2018, vol. 3, p. 527.

    Google Scholar 

  11. Chermenskaya, T.D., Chelovechkova, V.V., and Alekseev, E.Yu., Determination of residual amounts of acetamiprid in agricultural products, in Nauchnoe obespechenie razvitiya APK v usloviyakh importozameshcheniya: Sbornik nauchnykh trudov mezhdunarodnoi nauchno-prakticheskoi konferentsii professorsko-prepodavatel’skogo sostava “Nauchnoe obespechenie razvitiya sel’skogo khozyaistva i snizhenie tekhnologicheskikh riskov v prodovol’stvennoi sfere” (Scientific Support for the Development of the Agro-Industrial Complex in the Context of Import Substitution: Collection of Scientific Papers of the International Scientific and Practical Conference of the Faculty Members “Scientific Support for the Development of Agriculture and Reducing Technological Risks in the Food Sector”), St. Petersburg: S.-Peterb. Gos. Agrar. Univ., 2017, part 1, pp. 173–176.

  12. Dolzhenko, V.I., Tsibul’skaya, I.A., Chermenskaya, T.D., et al., Determination of residual amounts of acetamiprid in tops and root crops of sugar beet by high performance liquid chromatography (MUK 4.1.3188–14), in Opredelenie ostatochnykh kolichestv pestitsidov v pishchevykh produktakh, sel’skokhozyaistvennom syr’e i ob"ektakh okruzhayushchei sredy: Sbornik metodicheskikh ukazanii (Determination of Residual Amounts of Pesticides in Food Products, Agricultural Raw Materials, and Environmental Objects: Collection of Methodological Instructions), Kuchurova, L.S., Ed., Moscow: Fed. Tsentr Gig. Epidemiol. Rospotrebnadzora, 2015, pp. 84–96.

  13. Nawaz, A., Niaz, A., and Ilyas, M., Determination and extraction of acetamiprid residues in fruits and vegetables, Int. J. Food Allied Sci., 2015, vol. 1, no. 2, pp. 63–66.

    Article  Google Scholar 

  14. Obana, H., Okihashi, M., and Akutsu, K., Determination of acetamiprid, imidacloprid, and nitenpyram residues in vegetables and fruits by high-performance liquid chromatography with diode-array detection, J. Agric. Food Chem., 2002, vol. 50, no. 16, pp. 4464–4467.

    Article  CAS  Google Scholar 

  15. Cara, M., Vorpsi, V., Harizaj, F., et al., J. Environ. Prot. Ecol., 2011, vol. 12, no. 1, pp. 74–81.

    CAS  Google Scholar 

  16. Lee, J., Kim, B.J., and Kim, E., Kinetics and the pre-harvest residue limits of acetamiprid and chlorantraniliprole in kimchi cabbage using ultra-performance liquid chromatography-tandem mass spectrometry, Molecules, 2019, vol. 24, no. 14, p. 2616.

    Article  CAS  Google Scholar 

  17. Martínez Vidal, J.L., Gil García, M.D., and Martínez Galera, M., Determination of acetamiprid by HPLC-fluorescence with post-column photoderivatization and HPLC-mass selective detection, J. Liquid Chromatogr. Relat. Technol., 2002, vol. 25, no. 17, pp. 2695–2707.

    Article  Google Scholar 

  18. Yeter, O. and Aydın, A., The fate of acetamiprid and its degradation during long-term storage of honey, Food Addit. Contam., A, 2020, vol. 37, no. 2, pp. 288–303.

  19. Alister, C., Araya, M., and Morandé, J., Effects of wine grape cultivar, application conditions and the winemaking process on the dissipation of six pesticides, Int. J. Agric. Nat. Resour., 2014, vol. 41, no. 3, pp. 375–386.

    Google Scholar 

  20. Faraji, M., Noorbakhsh, R., and Shafieyan, H., Determination of acetamiprid, imidacloprid, and spirotetramat and their relevant metabolites in pistachio using modified QuECHeRS combined with liquid chromatographytandem mass spectrometry, Food Chem., 2018, vol. 240, pp. 634–641.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. All-Russia Institute of Plant Protection, 196608, St. Petersburg, Pushkin, Russia

    A. S. Komarova & V. V. Chelovechkova

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  1. A. S. Komarova
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  2. V. V. Chelovechkova
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Correspondence to A. S. Komarova.

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The authors declare that they have no conflict of interest. This article does not contain any studies involving animals or human participants performed by any of the authors.

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Translated by L. A. Solovyova

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Komarova, A.S., Chelovechkova, V.V. Dynamics of Acetamiprid Decomposition in Grapes and Grape Juice. Russ. Agricult. Sci. 47, 129–131 (2021). https://doi.org/10.3103/S1068367421020105

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  • DOI: https://doi.org/10.3103/S1068367421020105

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