Skip to main content
SpringerLink
Log in

Varying the Conditions of ZrO2⋅nH2O Precipitation and Aging as a Way of Controlling the Phase Composition and Texture of ZrO2

  • GENERAL PROBLEMS OF CATALYSIS
  • Published:
Catalysis in Industry Aims and scope Submit manuscript

Abstract

The effect of the precipitation mode, temperature, and ZrO2⋅nH2O aging time on the porous texture, phase composition, and thermal transformations of ZrO2⋅nH2O and ZrO2 has been studied. It has been found that varying the mode of precipitation allows changes in the specific surface area, pore volume, and average pore size of ZrO2⋅nH2O and ZrO2; an increase in the contribution from mesopores to the pore space of ZrO2⋅nH2O; and a change the ZrO2 particle size. It has been shown that raising the temperature of ZrO2⋅nH2O aging results in intense development of the mesoporous structure, an increase in the specific surface area of ZrO2⋅nH2O and ZrO2, and a reduction in the size of ZrO2 particles. At the same time, the ratio of the ZrO2 phases undergoes a nonmonotonic change upon an increase in the period of aging. The selection of the conditions of precipitation and aging allows us to double the pore volume of ZrO2, relative to the respective parameter of a sulfated zirconia isomerization catalyst and increase the surface area without introducing additional components. The best characteristics of the pore structure of ZrO2 (Ssp = 140 m2/g and Vpore = 0.404 cm3/g) are achieved with precipitation at a constant pH value and subsequently aging ZrO2⋅nH2O for 12 h at 90°C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Urzhuntsev, G.A. and Echevskii, G.V., Katal. Prom-sti, 2018, no. 1, pp. 60–66.

  2. Bugrova, T.A. and Mamontov, G.V., Kinet. Catal., 2018, vol. 59, no. 2, pp. 143–149.

    Article  CAS  Google Scholar 

  3. Otroshchenko, T., Radnik, J., Schneider, M., Rodemerck, U., Linke, D., and Kondratenko, E.V., Chem. Commun., 2016, vol. 52, pp. 8164–8167.

    Article  CAS  Google Scholar 

  4. Abdullah, B., Abd Ghani, N.A., and Vo, D.-V.N., J. Clean. Prod., 2017, vol. 162, pp. 170–185.

    Article  CAS  Google Scholar 

  5. Charisiou, N.D., Papageridis, K.N., Siakavelas, G., Tzounis, L., Kousi, K., Baker, M.A., Hinder, S.J., Sebastian, V., Polychronopoulou, K., and Goula, M.A., Top. Catal., 2017, vol. 60, nos. 15–16, pp. 1226–1250.

  6. Omarov, Sh.O., Vlasov, E.A., Sladkovskiy, D.A., Semikin, K.V., Matveyeva, A.N., Fedorov, S.P., Oganesyan, G.V., and Murzin, D.Yu., Appl. Catal., B, 2018, vol. 230, pp. 246–259.

    Article  CAS  Google Scholar 

  7. Lavrenov, A.V., Perelevskii, E.V., Finevich, V.P., Zaikovskii, V.I., Paukshtis, E.A., Duplyakin, V.K., and Bal’zhinimaev, B.S., Russ. J. Appl. Chem., 2003, vol. 76, no. 4, pp. 550–557.

    Article  CAS  Google Scholar 

  8. Smirnova, M.Yu., Toktarev, A.V., Ayupov, A.B., and Echevsky, G.V., Catal. Today, 2010, vol. 152, nos. 1–4, pp. 17–23.

  9. Karpova, T.R., Buluchevskii, E.A., Lavrenov, A.V., Leont’eva, N.N., Gulyaeva, T.I., and Savel’eva, G.G., Zh. Sib. Fed. Univ., Khim., 2012, vol. 5, no. 4, pp. 376–387.

    Google Scholar 

  10. Breysse, M., Afanasiev, P., Geantet, C., and Vrinat, M., Catal. Today, 2003, vol. 86, nos. 1–4, pp. 5–16.

  11. Ivanova, A.S., Moroz, E.M., and Litvak, G.S., Kinet. Katal., 1992, vol. 33, nos. 5–6, pp. 1208–1214.

    CAS  Google Scholar 

  12. Ivanova, A.S., Fedotov, M.A., Litvak, G.S., and Moroz, E.M., Inorg. Mater., 2000, vol. 36, no. 4, pp. 352–358.

    Article  CAS  Google Scholar 

  13. Charisiou, N.D., Siakavelas, G., Tzounis, L., Dou, B., Sebastian, V., Hinder, S.J., Baker, M.A., Polychronopoulou, K., and Goula, M.A., Int. J. Hydrogen Energy, 2020, vol. 45, no. 17, pp. 10442–10460.

    Article  CAS  Google Scholar 

  14. Nichele, V., Signoretto, M., Pinna, F., Menegazzo, F., Rossetti, I., Cruciani, G., Cerrato, G., and Di Michele, A., Appl. Catal., B, 2014, vols. 150–151, pp. 12–20.

  15. Smolikov, M.D., Shkurenok, V.A., Yablokova, S.S., Kir’yanov, D.I., Paukshtis, E.A., Leont’eva, N.N., Belyi, A.S., and Drozdov, V.A., Catal. Ind., 2017, vol. 9, no. 1, pp. 54–61.

    Article  Google Scholar 

  16. Ivanova, A.S., Kinet. Catal., 2012, vol. 53, no. 4, pp. 425–439.

    Article  CAS  Google Scholar 

  17. Matveyeva, A.N., Pakhomov, N.A., and Murzin, D.Yu., Ind. Eng. Chem. Res., 2016, vol. 55, no. 34, pp. 9101–9108.

    Article  CAS  Google Scholar 

  18. Bedilo, A.F. and Klabunde, K.J., J. Catal., 1998, vol. 176, no. 2, pp. 448–458.

    Article  CAS  Google Scholar 

  19. Yang, P., Zhao, D., Margolese, D.I., Chmelka, B.F., and Stucky, G.D., Chem. Mater., 1999, vol. 11, no. 10, pp. 2813–2826.

    Article  CAS  Google Scholar 

  20. Urzhuntsev, G.A., Ovchinnikova, E.V., Chumachenko, V.A., Yashnik, S.A., Zaikovsky, V.I., and Echevsky, G.V., Chem. Eng. J., 2014, vol. 238, pp. 148–156.

    Article  CAS  Google Scholar 

  21. Tichit, D., El Alami, D., and Figueras, F., Appl. Catal., A, 1996, vol. 145, nos. 1–2, pp. 195–210.

  22. Chuah, G.K., Jaenicke, S., and Pong, B.K., J. Catal., 1998, vol. 175, no. 1, pp. 80–92.

    Article  CAS  Google Scholar 

  23. Chuah, G.K., Jaenicke, S., Cheong, S.A., and Chan, K.S., Appl. Catal., A, 1996, vol. 145, nos. 1–2, pp. 267–284.

  24. Gavrilov, V.Yu. and Zenkovets, G.A., Kinet. Catal., 2000, vol. 41, no. 5, pp. 715–719.

    Article  CAS  Google Scholar 

  25. Thommes, M., Kaneko, K., Neimark-Alexander, V., Olivier-James, P., Rodriguez-Reinoso, F., Rouquerol, J., and Sing-Kenneth, S.W., Pure Appl. Chem., 2015, vol. 87, nos. 9–10, pp. 1051–1069.

  26. Toraya, H., Yoshimura, M., and Somiya, S., J. Am. Chem. Soc., 1984, vol. 67, no. 6, pp. C119–C121.

    CAS  Google Scholar 

  27. Yamaguchi, T., Catal. Today, 1994, vol. 20, no. 2, pp. 199–217.

    Article  CAS  Google Scholar 

  28. Sato, T., J. Therm. Anal. Calorim., 2002, vol. 69, no. 1, pp. 255–265.

    Article  CAS  Google Scholar 

  29. Buyanov, R.A. and Krivoruchko, O.P., React. Kinet. Catal. Lett., 1987, vol. 35, nos. 1–2, pp. 293–302.

  30. Denkewicz, R.P., Tenhuisen, K.S., and Adair, J.H., J. Mater. Res. 1990, vol. 5, no. 11, pp. 2698–2705.

    Article  CAS  Google Scholar 

  31. Pozhidaeva, O.V., Korytkova, E.N., Romanov, D.P., and Gusarov, V.V., Russ. J. Gen. Chem., 2002, vol. 72, no. 6, pp. 849–853.

    Article  CAS  Google Scholar 

  32. Clearfield, A., Serrette, G.P.D., and Khazi-Syed, A.H., Catal. Today, 1996, vol. 20, nos. 1–4, pp. 295–312.

  33. Bokhimi, X., Morales, A., Novaro, O., Portilla, M., López, T., Tzompantzi, F., and Gómez, R., J. Solid State Chem., 1998, vol. 135, pp. 28–35.

    Article  CAS  Google Scholar 

  34. Srinivasan, R., Harris, M.B., De Angelis, R.J., and Burton, D.H., J. Mater. Res., 1988, vol. 3, no. 4, pp. 787–797.

    Article  CAS  Google Scholar 

  35. Kobayashi, Y., Sasaki, T., Takagi, I., and Moriyama, H., J. Nucl. Sci. Technol., 2007, vol. 44, no. 1, pp. 90–94.

    Article  CAS  Google Scholar 

  36. Pakhomov, N.A., Nauchnye osnovy prigotovleniya katalizatorov (Scientific Foundations of Catalyst Preparation), 2011, Novosibirsk: Izd. SO RAN.

  37. Sato, S., Takahashi, R., Sodesawa, T., Tanaka, S., Oguma, K., and Ogura, K., J. Catal., 2000, vol. 196, no. 1, pp. 190–194.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. St. Petersburg State Institute of Technology (Technical University), 190013, St. Petersburg, Russia

    Sh. O. Omarov & N. A. Pakhomov

  2. Ioffe Institute, Russian Academy of Sciences, 194021, St. Petersburg, Russia

    Sh. O. Omarov

Authors
  1. Sh. O. Omarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. A. Pakhomov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Sh. O. Omarov.

Additional information

Translated by M. Timoshinina

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Omarov, S.O., Pakhomov, N.A. Varying the Conditions of ZrO2⋅nH2O Precipitation and Aging as a Way of Controlling the Phase Composition and Texture of ZrO2 . Catal. Ind. 13, 12–20 (2021). https://doi.org/10.1134/S2070050421010086

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070050421010086

Keywords:

Search

Navigation