Abstract
The effect of the means used to synthesize bifunctional cobalt catalysts with HZSM-5 zeolite and a boehmite binder on the catalytic performance of Fischer–Tropsch (FT) synthesis is studied. The synthesized catalysts are characterized via BET, XRD, EDA, SEM, TEM, H2 TPD, and NH3 TPD. They are tested in hydrocarbon synthesis at a pressure of 2.0 MPa, a temperature of 240°C, and a gas hourly space velocity of 1000 h−1. It is shown that the hydrocarbon and fractional composition of the FT synthesis products can be controlled, depending on the means of catalyst synthesis. A promising composite catalyst system for the single-stage synthesis of a low–pour-point diesel fuel has been proposed.
Similar content being viewed by others
REFERENCES
Eliseev, O.L., Savost’yanov, A.P., Sulima, S.I., and Lapidus, A.L., Mendeleev Commun., 2018, vol. 28, no. 4, pp. 345–351. https://doi.org/10.1016/j.mencom.2018.07.001
Khodakov, A.Y., Wei, C., and Fongarland, P., Chem. Rev., 2007, vol. 107, no. 5, pp. 1692–1744. https://doi.org/10.1021/cr050972v
Yang, G., Xing, C., Hirohama, W., Jin, Y., Zeng, C., Suehiro, Y., Wang, T., Yoneyama, Y., and Tsubaki, N., Catal. Today, 2013, vol. 215, pp. 29–35. https://doi.org/10.1016/j.cattod.2013.01.010
Jin, Y., Yang, R., Mori, Y., Sun, J., Taguchi, A., Yoneyama, Y., Abe, T., and Tsubaki, N., Appl. Catal., A, 2013, vol. 456, pp. 75–81. https://doi.org/10.1016/j.apcata.2013.02.014
Kang, S.-H., Ryu, J.-H., Kim, J.-H., Sai Prasad, P.S., Bae, J.W., Cheon, J.-Y., and Jun, K.-W., Catal. Lett., 2011, vol. 141, no. 10, pp. 1464–1471. https://doi.org/10.1007/s10562-011-0626-y
Savost’yanov, A.P., Narochnyi, G.B., Yakovenko, R.E., Saliev, A.N., Sulima, S.I., Zubkov, I.N., Nekroenko, S.V., and Mitchenko, S.A., Pet. Chem., 2017, vol. 57, no. 12, pp. 1186–1189. https://doi.org/10.1134/S0965544117060251
Sineva, L.V., Asalieva, E.Yu., and Mordkovich, V.Z., Russ. Chem. Rev., 2015, vol. 84, no. 11, pp. 1176–1189. https://doi.org/10.1070/RCR4464
Feller, A., Guzman, A., Zuazo, I., and Lercher, J.A., J. Catal., 2004, vol. 224, no. 1, pp. 80–93. https://doi.org/10.1016/j.jcat.2004.02.019
Lipin, P.V., Doronin, V.P., and Gulyaeva, T.I., Pet. Chem., 2010, vol. 50, no. 5, pp. 362–367. https://doi.org/10.1134/S0965544110050075
Zhang, Q., Cheng, K., Kang, J., Deng, W., and Wang, Y., ChemSusChem, 2014, vol. 7, no. 5, pp. 1251–1264. https://doi.org/10.1002/cssc.201300797
Espinosa, G., Domínguez, J.M., Morales-Pacheco, P., Tobon, A., Aguilar, M., and Benítez, J., Catal. Today, 2011, vol. 166, no. 1, pp. 47–52. https://doi.org/10.1016/j.cattod.2011.01.025
Majewska, J. and Michalkiewicz, B., Int. J. Hydrogen Energy, 2016, vol. 41, no. 20, pp. 8668–8678. https://doi.org/10.1016/j.ijhydene.2016.01.097
Lee, D.-K., Kim, D.-S., Kim, T.-H., Lee, Y.-K., and Jeong, S.-E., Le, N.T., Cho, M.-J., and Henam, S.D., Catal. Today, 2010, vol. 154, nos. 3–4, pp. 237–243. https://doi.org/10.1016/j.cattod.2010.03.053
Sartipi, S., Makkee, M., Kapteijn, F., and Gascon, J., Catal. Sci. Technol., 2014, vol. 4, no. 4, pp. 893–907. https://doi.org/10.1039/C3CY01021J
Adeleke, A.A., Liu, X., Lu, X., Moyo, M., and Hildebrandt, D., Rev. Chem. Eng., 2020, vol. 36, no. 4, pp. 437–457. https://doi.org/10.1515/revce-2018-0012
Lin, Q., Yang, G., Li, X., Yoneyama, Y., Wan, H., and Tsubaki, N., ChemCatChem, 2013, vol. 5, no. 10, pp. 3101–3106. https://doi.org/10.1002/cctc.201300336
Sartipi, S., Parashar, K., Valero-Romero, M.J., Santos, V.P., der Linden, B., Makkee, M., Kapteijn, F., and Gascon, J., J. Catal., 2013, vol. 305, pp. 179–190. https://doi.org/10.1016/j.jcat.2013.05.012
Zhu, C. and Bollas, G.M., Appl. Catal., B, 2018, vol. 235, pp. 92–102. https://doi.org/10.1016/j.apcatb.2018.04.063
Kibby, C., Jothimurugesan, K., Das, T., Lacheen, H.S., Rea, T., and Saxton, R.J., Catal. Today, 2013, vol. 215, pp. 131–141. https://doi.org/10.1016/j.cattod.2013.03.009
Cheng, S., Mazonde, B., Zhang, G., Javed, M., Dai, P., Cao, Y., Tu, S., Wu, J., Lu, C., Xing, C., and Shan, S., Fuel, 2018, vol. 223, pp. P. 354–359. https://doi.org/10.1016/j.fuel.2018.03.042
Subramanian, V., Zholobenko, V.L., Cheng, K., Lancelot, C., Heyte, S., Thuriot, J., Paul, S., Ordomsky, V.V., and Khodakov, A.Y., ChemCatChem, 2016, vol. 8, no. 2, pp. 380–389. https://doi.org/10.1002/cctc.201500777
Nakanishi, M., Uddin, Md.A., Kato, Y., Nishina, Y., and Hapipi, A.M., Catal. Today, 2017, vol. 291, pp. 124–132. https://doi.org/10.1016/j.cattod.2017.01.017
De la Osa, A.R., Romero, A., Díez-Ramírez, J., Valverde, J.L., and Sánchez, P., Top. Catal., 2017, vol. 60, nos. 15–16, pp. 1082–1093. https://doi.org/10.1007/s11244-017-0792-2
Li, Z., Wu, L., Han, D., and Wu, J., Fuel, 2018, vol. 220, pp. 257–263. https://doi.org/10.1016/j.fuel.2018.02.004
Velichkina, L.M., Vosmerikova, L.N., Korobitsyna, L.L., Kanashevich, D.A., Vosmerikov, A.V., and Abdiyusupov, G.G., Neftepererab. Neftekhim., 2016, no. 1, pp. 13–19.
Sartipi, S., Parashar, K., Makkee, M., Gascon, J., and Kapteijn, F., Catal. Sci. Technol., 2013, vol. 3, no. 3, pp. 572–575. https://doi.org/10.1039/C2CY20744C
Sartipi, S., Alberts, M., Meijerink, M.J., Keller, T.C., Pérez-Ramírez, J., Gascon, J., and Kapteijn, F., ChemSusChem, 2013, vol. 6, no. 9, pp. 1646–1650. https://doi.org/10.1002/cssc.201300339
Yao, M., Yao, N., Liu, B., Li, S., Xu, L., and Li, X., Catal. Sci. Technol., 2015, vol. 5, no. 5, pp. 2821–2828. https://doi.org/10.1039/C5CY00017C
Calleja, G., Lucas, A., and Grieken, R., Fuel, 1995, vol. 74, no. 3, pp. 445–451. https://doi.org/10.1016/0016-2361(95)93480-2
Dalil, M., Sohrabi, M., and Royaee, S.J., J. Ind. Eng. Chem., 2012, vol. 18, no. 2, pp. 690–696. https://doi.org/10.1016/j.jiec.2011.11.114
Englin, B.A., Primenenie zhidkikh topliv pri nizkikh temperaturakh (Application of Liquid Fuels at Low Temperatures), Moscow: Khimiya, 1980.
Kinzul’, A.P., Khandarkhaev, S.V., Pisarenko, N.O., Buryukin, F.A., and Tverdokhlebov, V.P., Mir Nefteprod., 2012, no. 8, pp. 7–11.
Tavasoli, A., Mortazavi, Y., Khodadadi, A.A., Mousavian, M.A., Sadagiani, K., and Karimi, A., Iran. J. Chem. Chem. Eng., 2005, vol. 24, no. 3, pp. 9–17.
Narochnyi, G.B., Savost’yanov, A.P., Yakovenko, R.E., and Bakun, V.G., Catal. Ind., 2016, vol. 8, no. 2, pp. 139–144. https://doi.org/10.1134/S2070050416020070
Chu, W., Chernavskii, P.A., Gengembre, L., Pankina, G.A., Fongarland, P., and Khodakov, A.Y., J. Catal., 2007, vol. 252, no. 2, pp. 215–230. https://doi.org/10.1016/j.jcat.2007.09.018
Savost’yanov, A.P., Yakovenko, R.E., Narochnyi, G.B., Zubkov, I.N., Sulima, S.I., Soromotin, V.N., and Mitchenko, S.A., Pet. Chem., 2020, vol. 60, no. 1, pp. 81–91. https://doi.org/10.1134/S0965544120010120
PDF-2 Data Base, International Centre for Diffraction Data, 2012. https://www.icdd.com/pdf-2/. Cited February 23, 2021.
Xu, D., Li, W., Duan, H., Ge, Q., and Xu, H., Catal. Lett., 2005, vol. 102, nos. 3–4, pp. 229–235. https://doi.org/10.1007/s10562-005-5861-7
Jacobs, G., Das, T.K., Zhang, Y., Li, J., Racoillet, G., and Davis, B.H., Appl. Catal., A., 2002, vol. 233, nos. 1–2, pp. 263–281. https://doi.org/10.1016/S0926-860X(02)00195-3
Parnian, M.J., Najafabadi, A.T., Mortazavi, Y., Khodadadi, A.A., and Nazzari, I., Appl. Surf. Sci., 2014, vol. 313, pp. 183–195. https://doi.org/10.1016/j.apsusc.2014.05.183
Conte, M., Xu, B., Davies, T.E., Bartley, J.K., Carley, A.F., Taylor, S.H., Khalid, K., and Hutchings, G.J., Microporous Mesoporous Mater., 2012, vol. 164, pp. 207–213. https://doi.org/10.1016/j.micromeso.2012.05.001
Pardo-Tarifa, F., Cabrera, S., Sanchez-Dominguez, M., and Boutonnet, M., Int. J. Hydrogen Energy, 2017, vol. 42, no. 15, pp. 9754–9765. https://doi.org/10.1016/j.ijhydene.2017.01.056
ACKNOWLEDGMENTS
It was performed on equipment at Platov South Russian State Polytechnic University’s Nanotechnology shared resource center.
Funding
This work was supported by the Russian Science Foundation, project no. 19-73-00089.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by M. Timoshinina
Rights and permissions
About this article
Cite this article
Yakovenko, R.E., Bakun, V.G., Zubkov, I.N. et al. Effect of the Means Used to Synthesize Bifunctional Fischer–Tropsch Catalysts on the Composition and Properties of Synthetic Fuels. Catal. Ind. 13, 38–47 (2021). https://doi.org/10.1134/S2070050421010116
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2070050421010116