Investigation of the passivation-induced VTH shift in p-GaN HEMTs with Au-free gate-first process

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Abstract

In this work, we observe the distinct VTH characteristics in the Au-free gate-first processing p-GaN/AlGaN/GaN HEMTs with two commonly used passivation layers, i.e., SiN and SiO2. The lower incorporated H was found in the p-GaN/AlGaN/GaN heterostructure with higher activation anneal temperature (i.e., 700 °C). Furthermore, Photoluminescence (PL) spectrum demonstrates a higher blue luminescence (BL) intensity after higher annealing treatment. The X-ray photoelectron spectroscopy (XPS) spectrum near valence band edge depicts a similar valence band maximum (VBM) characteristic, by means no impact on p-GaN surface bending by using distinct thermal treatment. The device with SiN shows a depletion-mode (D-mode) characteristic (VTH ~ -5 V) whereas the device with SiO2 passivation exhibits an enhancement-mode (E-mode) characteristic (VTH ~ +0.7 V). Moreover, Transmission Line Model (TLM) devices are fabricated to investigate the effects of the passivation on two-dimensional electron gas (2DEG) in p-GaN/AlGaN/GaN stack. The results indicate that a low Rsh is obtained while passivating device surface with SiN layer, suggesting that 2DEG is present, which is most probably due to an unfunctional p-GaN layer. The secondary ion mass spectrometry (SIMS) results indicate a high hydrogen intensity in the p-GaN/AlGaN/GaN stack with a SiN passivation layer. Thus, the p-GaN deactivation process that correlates to the formation of complex Mgsingle bondH after SiN passivation is proposed to explain the D-mode characteristic in the device with a SiN passivation layer.

Introduction

Nowadays, the GaN-based High Electron Mobility Transistors (HEMTs) have been considered as a promising technology for high-efficient power switching applications. Over more than 20 years' development, the GaN power devices have demonstrate for the applications such as electrical vehicle (EV) inverter, laptop adaptor, wireless power transfer, UPS, or even space applications [[1], [2], [3], [4]]. However, the reliability still remains the challenges in GaN power devices. In addition to the evaluation of typical device parameters and Safe Operation Area (SOA), various reliability tests need to be considered, i.e., hard switching [5], semi-on stress [6,7], high temperature gate bias (HTGB) [8], time dependent dielectric breakdown (TDDB) [9,10], Mean-time-to-failure (MTTF) [11], and JEDEC standard qualifications [12].

Generally, the GaN-based HEMTs have the superior characteristics, featuring with a low RDS,on due to an inherent two-dimension electron gas (2DEG) between AlGaN and GaN layer, wide bandgap (EG) of 3.4 eV, low gate charge (QG), nearly zero reverse recovery charge (Qrr), and high critical electric field (EC ~ 3.3MV/cm) [13].

Considering the common usage preference, an E-mode characteristic is adopted for commercial applications due to an easier integration and fail-safe operation. Various approaches have been proposed to achieve a normally-off operation in GaN-based HEMTs, e.g., fluorine-based treatment [14], gate recess [[15], [16], [17]], hybrid-MIS structure [18], p-GaN/AlGaN gate [19,20]. Recently, AlGaN/GaN HEMTs with a p-GaN Schottky gate attract lots of attentions toward an enhancement-mode characteristic. High performance AlGaN/GaN HEMTs with a p-GaN Schottky gate with robust stability have been demonstrated so far [21,[23], [24], [25]]. Moreover, the surface passivation is used to modulate the strain in access region, further reducing the access resistance due to the additional polarizations [26]. The surface passivation is also effective to improve the breakdown performance [27] and stability of dynamic on-resistance [28,29]. Nevertheless, the impact of the passivation on the characteristics of p-GaN gate HEMTs still needs more investigation.

In this work, the secondary ion mass spectrometry (SIMS), photoluminescence (PL), and X-ray photoelectron spectroscopy (XPS) analyses are used to analyze the p-GaN/AlGaN/GaN stack and the p-GaN gate HEMTs are fabricated with two different passivation layers, i.e., SiN and SiO2, to evaluate the impacts of the passivation on the VTH characteristics. To further understand the effects of passivation layer, we fabricated the Transmission Line Model (TLM) devices in p-GaN/AlGaN/GaN stack. Finally, a physical model is proposed to explain the p-GaN deactivation mechanisms after the device is passivated by SiN layer.

Section snippets

Device structure and fabrication

The schematic of the process flows and device structure of Au-free gate-first p-GaN/AlGaN/GaN high electron mobility transistors (HEMTs) with SiN and SiO2 are shown in Fig. 1. The epi-stack used in this work were grown on 6-inch Si (111) substrate by metal-organic chemical vapor deposition (MOCVD), consisting of an AlN nucleation layer, a GaN buffer layer, an unintentionally doped 12-nm AlGaN barrier layer, and a 80-nm Mg doped p-GaN layer.

The main process steps are described in Fig. 1(a). In

SIMS, PL, XPS analysis in p-GaN layer with different activation anneal temperature

To investigate the effects of activation anneal temperature in the p-GaN layer, SIMS, PL, XPS are used to analyze the p-GaN layer in p-GaN/AlGaN/GaN heterostructure grown in MOCVD with different p-GaN activation anneal temperature (670 °C and 700 °C). Fig. 3 shows the H intensity in p-GaN layer with different temperature annealing. The incorporated H shows the p-GaN epitaxial layer with 700 °C thermal treatment exhibits the lowest H intensity. The low H intensity in p-GaN may correlate to the

Conclusion

In conclusion, we investigate the impact of the SiN and SiO2 passivation layer on the device characteristics of p-GaN gate HEMTs. First of all, we investigate the impacts of the activation anneal temperature in p-GaN/AlGaN/GaN heterostructure using SIMS, PL, and XPS analyses. The BL intensity of the p-GaN/AlGaN/GaN stack under higher annealing temperature exhibits the higher intensity. However, the observed lowest incorporated H in p-GaN/AlGaN/GaN stack with 700 °C activation anneal

CRediT authorship contribution statement

Shun-Wei Tang: Conceptualization, Methodology, Investigation, Data curation, Writing- Original draft preparation.

Zhen-Hong Huang, Yi-Cheng Chen, Cheng-Hung Wu, Pin-Hau Lin, Zheng-Chen Chen, Ming-Hao Lu: Investigation, Data curation.

Kuo-Hsing Kao: Writing- Reviewing and Editing, Supervision.

Tian-Li Wu: Conceptualization, Writing- Reviewing and Editing, Supervision, Project administration, Funding acquisition.

Declaration of competing interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Acknowledgment

This work was supported in part by the “Center for the Semiconductor Technology Research” from The Featured Areas Research Center Program within the framework of the Higher Education Sprout Project by the Ministry of Education, Taiwan (MOE) in Taiwan, in part by the Ministry of Science and Technology (MOST), Taiwan, under Grant MOST 110-2634-F-009-027, and in part by the Young Scholar Fellowship Program under Grant MOST 110-2636-E-009-023.

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