Abstract
A series of double-perovskite oxides Sr2Sr1-xCaxTeO6 (0 ≤ x ≤ 1) samples have been prepared in order to study the effect of composition on phase formation and the related optical properties. The objective of this work is to study the possibility of calcium insertion with different percentages since calcium in known to enhance the electrical properties. In this work a well detailed structure and phase transitions investigation of the compounds were conducted and probed by X-ray diffraction and Raman spectroscopy techniques at room temperature. Both Rietveld refinements and Raman studies revealed that two phase transitions took place as the calcium amount x increases; a first from a triclinic to a hexagonal in the range 0.1 < x < 0.25 and a second from the hexagonal to a monoclinic structure in the range 0.5 < x < 0.6. The optical absorption α(λ) was also determined as a function of calcium content in the series samples using UV-vis analysis. It was revealed that a remarkable change occured in the cut-off wavelength, confirming the sequence of phase transitions C1 → R\( \overline{3} \)m → P21/n. The optical band gap measurements showed that the triclinic Sr3TeO6 and the monoclinic Sr2CaTeO6 phases have band gap values of 2.75 and 2.81 eV, respectively. When the calcium increased to x = 0.25 (Sr2.75Ca0.25TeO6), remarkable decrease of the band gap value was observed, with Eg = 2.627 eV.
Similar content being viewed by others
References
B. Stöger, M. Weil, E. Zobetz, Zeitschrift Fur Krist. 225(4), 125–138 (2010)
J.A. Baglio, S. Natansohn, J. Appl. Crystallogr 2, 252, 1969
S. Y. J. T. K. I. H. Tetsuka H., Solid State Commun. 137, 345 (2006)
M. Drache, J. Ravez, P. Hagenmuller, Solid State Commun. 37(2), 139–143 (1981)
H. Schulz, G. Bayer, Acta Crystallogr. Sect. B 27(4), 815–821 (1971)
H.-G. Burckhardt, C. Platte, M. Trömel, Acta Crystallogr. Sect. B Struct. Crystallogr. Cryst. Chem. 38(9), 2450–2452 (1982)
W. Luan, Y.J. Shan, M. Itoh, H. Imoto, Ceram. Int. 31(1), 129–133 (2005)
H. Tetsuka, Y. Shan, K. Tezuka, H. Imoto, Mater. Res. Bull. 40(7), 1223–1232 (2005)
E.D. Politova, Y.N. Venevtsev, Mater. Res. Bull. 10(4), 319–325 (1975)
A. Dias, G. Subodh, M.T. Sebastian, M.M. Lage, R.L. Moreira, Chem. Mater. 20(13), 4347–4355 (2008)
T. Application, T. Wu, and P. Gao, 1 (2018)
T. Maiti, M. Saxena, and P. Roy, 107 (2019)
M. Saxena, K. Balani, T. Maiti, Mater. Sci. Eng. B 244, 65 (2019)
D.J. Singh, M. Ghita, M. Fornari, S.V. Halilov, Ferroelectrics 338(1), 73–79 (2006)
J. Rodriguez-Carvajal, FULLPROF 2000: A Rietveld Refinement and Pattern Matching Analysis Program (2008)
T. Roisnel, J. Rodríquez-Carvajal, Mater. Sci. Forum 378–381, 118 (2001)
M. Azdouz, B. Manoun, M. Azrour, L. Bih, L. El Ammari, S. Benmokhtar, P. Lazor, J. Mol. Struct. 963(2-3), 258–266 (2010)
H. Bih, L. Bih, B. Manoun, M. Azdouz, S. Benmokhtar, P. Lazor, J. Mol. Struct. 936(1-3), 147–155 (2009)
Y. Tamraoui, B. Manoun, F. Mirinioui, I. Saadoune, R. Haloui, A. Elhachmi, E. Saad, P. Lazor, J. Mol. Struct. 1131, 103–113 (2017)
B. Manoun, F. Mirinioui, Y. Tamraoui, A. Solhy, W. Yang, P. Lazor, J. Alloys Compd. 689, 233–245 (2016)
E. Kim, Z.-T. Jiang, and K. No, Jpn. J. Appl. Phys. 39, 4820 (2000), Part 1, No. 8, 4825
R. Kitamura, L. Pilon, M. Jonasz, Appl. Opt. 46(33), 8118–8133 (2007)
P.R. Wessel, Phys. Rev. 132(5), 2062–2064 (1963)
P. Kubelka, F. Munk, Z. Tech, Phys 12, 593 (1931)
J. Tauc, Mater. Res. Bull. 3(1), 37–46 (1968)
A. Boultif, D. Loueer, D. Louër, J. Appl. Crystallogr. 24(6), 987–993 (1991)
T.J. Prior, V.J. Couper, P.D. Battle, J. Solid State Chem. 178(1), 153–157 (2005)
G. King, A.M. Abakumov, J. Hadermann, A.M. Alekseeva, M.G. Rozova, T. Perkisas, P.M. Woodward, G. Van Tendeloo, E.V. Antipov, Inorg. Chem. 49(13), 6058–6065 (2010)
A. Faik, M. Gateshki, J.M. Igartua, J.L. Pizarro, M. Insausti, R. Kaindl, A. Grzechnik, J. Solid State Chem. 181(8), 1759–1766 (2008)
J.E. Medvedeva, A.J. Freeman, Europhys. Lett. 69(4), 583–587 (2005)
A. Escobedo Morales, E. Sánchez Mora, and U. Pal, Rev. Mex. Fis. Suppl. Vol. 53, No. 5, p.18–22 53, 18 (2007)
G.P. Joshi, N.S. Saxena, R. Mangal, A. Mishra, T.P. Sharma, Bull. Mater. Sci. 26(4), 387–389 (2003)
A.M. Glazer, Acta Crystallogr. Sect. A 31(6), 756–762 (1975)
A.M. Glazer, Acta Crystallogr. Sect. B Struct. Crystallogr. Cryst. Chem. 28(11), 3384–3392 (1972)
E. Kroumova, M.I. Aroyo, J.M. Perez-Mato, A. Kirov, C. Capillas, S. Ivantchev, H. Wondratschek, Phase Transit. 76(1-2), 155–170 (2003)
Y. Tamraoui, B. Manoun, F. Mirinioui, R. Haloui, and P. Lazor, J. Alloys Compd. 603, (2014)
B. Manoun, Y. Tamraoui, I. Saadoune, P. Lazor, W. Yang, J. Alami, Mater. Res. Express 4(10), 105018 (2017)
A. P. Ayala, I. Guedes, E. N. Silva, M. S. Augsburger, M. del C. Viola, and J. C. Pedregosa, J. Appl. Phys. 101, 123511 (2007)
H. Zheng, G. D.. Csete de Györgyfalva, R. Quimby, H. Bagshaw, R. Ubic, I.. Reaney, and J. Yarwood, J. Eur. Ceram. Soc. 23, 2653 (2003), 14, 2659
Acknowledgements
The authors are grateful to the University Hassan 1st for its support, the Office Chérifien des Phosphates in the Moroccan Kingdom (OCP group) and Mohammed VI Polytechnic University for their support as well as the Swedish Research Council for the financial grant SRL(MENA) # 348- 2014-4287.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Tamraoui, Y., El Bachraoui, F., Mirinioui, F. et al. On the structural phase transitions and optical properties of Sr2Sr1-xCaxTeO6 (0 ≤ x ≤ 1) ceramics. J Electroceram 46, 1–13 (2021). https://doi.org/10.1007/s10832-021-00237-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10832-021-00237-8