Homophase synthesis of copolymers based on acrylonitrile and 2-acrylamide-2-methylpropanesulfonic acid in aqueous NaSCN solution (51.5%) with 0-25 mass% of the acidic copolymer in the monomer mixture was examined. The relative reactivities of the monomers were determined. The content of the acidic monomer in the starting reaction mixture was found to affect the integral synthesis kinetics, the monomer composition of the copolymers, and the properties of their dilute and concentrated solutions in DMF. Fibrous materials with special properties could be spun from the synthesized ionizable copolymers.
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L. A. Shcherbina, E. A. Alekhina, et al., Khim. Volokna, No. 6, 31-35 (1994).
B. E. Geller, L. A. Shcherbina, and O. N. Korotkaya, Khim. Volokna, No. 2, 23-26 (2000).
B. E. Geller and L. A. Shcherbina, Khim. Volokna, No. 4, 18-24 (2002).
L. A. Shcherbina and B. E. Geller, in: Proceedings of an International Conference on Chemical Fibers “Chemical Fibers 2000” [in Russian], May 16-19, 2000, Tver, 2000, pp. 409-412.
B. E. Geller, K. I. Kaminskii, and L. A. Shcherbina, in: Proceedings of the IInd Belarusian Scientific-Practical Conference [in Russian], Dec. 15-16, 2001, Mogilev, MGTI, Mogilev, 2002, pp. 136-146.
L. A. Shcherbina, B. E. Geller, and A. A. Geller, A priori Assessment of Several Physicochemical Properties of Film- and Fiber-forming Polymers [in Russian], MGUP, Mogilev, 2008, 136 pp.
V. A. Ogorodnikov, N. N. Stolyarova, and L. A. Shcherbina, Khim. Volokna, No. 2, 23-28 (2014).
V. A. Ogorodnikov, L. A. Shcherbina, and I. A. Budkute, Khim. Volokna, No. 4, 73-78 (2016).
A. V. Nikolaichenko, E. V. Rabchenko, et al., in: Proceedings of the International Conference “Composite-2010” [in Russian], Saratov, 2010, pp. 198-200.
I. A. Budkute, B. E. Geller, and L. A. Shcherbina, Khim. Volokna, No. 5, 40-45 (2004).
L. A. Shcherbina, I. A. Budkute, and K. Yu. Ustinov, in: Proceedings of the International Scientific-Technical Conference “Innovative Technologies in the Textile and Light Industry” [in Russian], Nov. 26-27 2014, Vitebsk, VGTU, 2014, pp. 339-341.
G. E. Ham (ed.), Copolymerization, Interscience, New York, 1964.
A. A. Geller, B. E. Geller, and L. A. Shcherbina, High-Molecular-Weight Compounds, in 2 vols., Part 2: Synthesis and Modification of Fiber-forming Polymers [in Russian], MGUP, Mogilev, 2016, 192 pp.
L. A. Shcherbina, N. I. Il’icheva, et al., Kjeldahl Method [in Russian], BGTU, Minsk, 2007, 86 pp.
L. A. Shcherbina, Candidate Dissertation in Technical Sciences, MGUP, Mogilev, 2002, 161 pp.
A. A. Geller, B. E. Geller, and L. A. Shcherbina, High-Molecular-Weight Compounds, in 2 vols., Part 1: Properties of Fiber-forming Polymers [in Russian], MGUP, Mogilev, 2016, 260 pp.
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Translated from Khimicheskie Volokna, No. 6, pp. 24-29, November—December, 2020.
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Shcherbina, L.A. Synthesis and Properties of Copolymers Based on Acrylonitrile and 2-Acrylamide-2-Methylpropanesulfonic Acid . Fibre Chem 52, 405–410 (2021). https://doi.org/10.1007/s10692-021-10221-1
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DOI: https://doi.org/10.1007/s10692-021-10221-1