Melt spinning of special chips of poly(butylene terephthalate)-block-(tetramethylene oxide) was studied. The obtained fiber possesses rubber-like elasticity at room temperature. The basic properties of this elastomer fiber are fineness 1.7 dtex, tensile strength 3.35 cN/dtex, breaking extension 68%, and elastic recovery >95% at 15% elongation. A new type of elastomer staple fiber of this block-copolymer is successfully fabricated by a traditional production line for melt spinning.
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We wish to express our deep gratitude to Prof. Shuangcheng Liu of Sichuan University for his assistance with the translation of this manuscript into Russian. This work was supported partly by Higher Education and TVET program of Ethiopia of German Development Bank with KfW project 51235.
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Translated from Khimicheskie Volokna, No. 6, pp. 19-23, November—December, 2020.
Appendix 1
Appendix 1
[Diagram], where the ratio of x (number of hard polyester segments in the copolymer chain) to y (number of soft polyether segments) determines the softness and elasticity of the obtained block-copoly(ester-ether). However, the ratio of hard to soft segments in Hytrel™ 4GT/PTMEG copolymers is calculated from the content of hard segments in the range from 33 to 86 mass% [8].
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Haile, M.B., Liu, X., Li, R. et al. Fabrication and Basic Properties of Elastomeric Staple Fiber Based on Poly(Butylene Terephthalate)-Block-(Tetramethylene Oxide) by Melt Spinning. Fibre Chem 52, 400–404 (2021). https://doi.org/10.1007/s10692-021-10220-2
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DOI: https://doi.org/10.1007/s10692-021-10220-2