Abstract
The crystal structure of a potentially new mineral, the Fe2+-dominant analogue of armalcolite with the idealized formula Fe2+Ti2O5 has been solved. The sample studied originates from a pneumatolytic association related to the lamproite complex of SE Spain. The mineral is orthorhombic, space group Cmcm, the unit-cell parameters are a = 3.7325(1) Å, b = 9.7649(4) Å, c = 9.9902(3) Å, V = 364.12(2) Å3. The crystal-chemical formula \({{^{M}}^{1}}{{({\text{M}}{{{\text{g}}}_{{0.19}}}{\text{Fe}}_{{0.25}}^{{2 + }}{\text{Fe}}_{{0.26}}^{{3 + }}{\text{T}}{{{\text{i}}}_{{0.30}}})}^{{2.86 + }}}\)\({{{{[}^{M}}^{2}{{({\text{T}}{{{\text{i}}}_{{0.65}}}{\text{Fe}}_{{0.27}}^{{3 + }}{\text{Fe}}_{{0.08}}^{{2 + }})}^{{3.57 + }}}]}_{2}}{{{\text{O}}}_{5}}\) (Z = 4) is in good agreement with the chemical composition of the mineral.
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Funding
XRD studies were supported by the Russian Science Foundation, project no. 19-17-00050. Analytical studies and crystal chemical analysis were supported by a State Assignment, project no. ААAА-А19-119092390076-7. XRDP studies performed in the Center for X-ray Diffraction Studies (St. Petersburg State University research park).
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Translated by M.S. Nickolsky
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Kazheva, O.N., Zubkova, N.V., Schäfer, C. et al. The Pseudobrookite Group: Crystal Chemical Features of the Armalcolite Fe2+ Analogue. Dokl. Earth Sc. 497, 305–309 (2021). https://doi.org/10.1134/S1028334X21040097
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DOI: https://doi.org/10.1134/S1028334X21040097