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Dye-sensitized solar cells concocted with dyes extracted from fresh and dried leaves of Henna using different solvents

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Abstract

Fresh and dried leaves of Lawsonia inermis (Henna) were used in extracting dyes with variety of solvents such as ethanol, acetone and distilled water. To our knowledge, acetone has been used for the first time as solvent to extract henna dye. These extracted dyes were used as sensitizers in Dye-Sensitized Solar Cells (DSSCs). A sum of six DSSCs were fabricated. Spectroscopic studies (UV–Visible and FTIR) were recorded for all the six dyes extracted and for the photo-anodes prepared. J–V Characterization study was performed for all the cells and parameters such as Voc, Jsc, Vm, Jm, fill-factor and efficiency were calculated for the prepared cells. To our knowledge, the efficiency of DSSCs with sensitizer extracted from henna leaves with acetone and distilled water as solvent has been reported for the first time. It was seen that amongst all the cells prepared, the one with dye extracted from dried leaves using acetone as solvent showed higher efficiency of 0.351% with fill-factor of 0.3765.

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Data Availability

The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.

References:

  • Abdel-Latif, M.S., Abuiriban, M.B., Dahoudi, N., Al-Kahlout, A.M., Taya, S.A., El-Agez, T.M., El-Ghamri, H.S.: Dye-sensitized solar cells using fifteen natural dyes as sensitizers of nanocrystalline TiO2. Sci. Technol. Dev. 34(3), 135–139 (2015a)

    Article  Google Scholar 

  • Abdel-Latif, M.S., Abuiriban, M.B., El-Agez, T.M., Taya, S.A.: Dye-sensitized solar cells using dyes extracted from flowers, leaves, parks, and roots of three trees. Int. J. Renew. Energy Res. 5(1), 294–298 (2015b)

    Google Scholar 

  • Al-Alwani, M.A.M., Mohamad, A.B., Ludin, N.A., Kadhum Abd, A.H., Sopian, K.: Dye-sensitised solar cells: development, structure, operation principles, electron kinetics, characterisation, synthesis materials and natural photosensitisers. Renew. Sust. Energ Rev. 65, 183–213 (2016)

    Article  Google Scholar 

  • Alami, A.H., Aokal, K., Zhang, D., Tawalbeh, M., Alhammadi, A., Taieb, A.: Assessment of Calotropis natural dye extracts on the efficiency of dye-sensitized solar cells. Agron. Res. 16(4), 1569–1579 (2018)

    Google Scholar 

  • Alhamed, M., Issa, A.S., Douba, A.W.: Studying of natural dyes properties as photo-sensitizer for dye sensitized solar cells (DSSC). J. Electron. Devices 16, 1370–1383 (2012)

    Google Scholar 

  • Ammar, A.M., Mohamed, H.S.H., Yousef, M.M.K., Abdel-Hafez, G.M., Hassanien, A.S., Khalil, A.S.G.: Dye-sensitized solar cells (DSSCs) based on extracted natural dyes. J. Nanomater. (2019). https://doi.org/10.1155/2019/1867271

    Article  Google Scholar 

  • Ananth, S., Vivek, P., Arumanayagam, T., Murugakoothan, P.: Natural dye extract of lawsonia inermis seed as photo sensitizer for titanium dioxide based dye sensitized solar cells. Spectrochimica Acta Part A. 128, 420–426 (2014)

    Article  ADS  Google Scholar 

  • Andargie, W., Ayele, D.W.: Dye-sensitized solar cells using natural dye as light-harvesting materials extracted from Acanthus sennii chiovenda flower and Euphorbia cotinifolia leaf. J. Sci. Adv. Mater. Devices. (2016). https://doi.org/10.1016/j.jsamd.2016.10.003

    Article  Google Scholar 

  • Cerda, B., Sivakumar, R., Paulraj, M.: Natural dyes as sensitizers to increase the efficiency in sensitized solar cells. Phys. Conf. Ser. 720, 012–030 (2016)

    Article  Google Scholar 

  • Chang, H., Wu, H.M., Chen, T.L., Huang, K.D., Jwo, C.S., Lo, Y.J.: Dye-sensitized solar cell using natural dyes extracted from spinach and ipomoea. J. Alloy Compd. 495, 606–610 (2010)

    Article  Google Scholar 

  • Chawla, P., Tripathi, M.: Novel improvements in the sensitizers of dye-sensitized solar cells for enhancement in efficiency—a review. Int. J. Energy Res. 39, 1579–1596 (2015)

    Google Scholar 

  • Halme. J.: Dye-sensitized nanostructured and organic photovoltaic cells: technical review and preliminary tests Master's thesis. Helsinki University of Technology, Finland. (2002)

  • Hug, H., Bader, M., Mair, P., Glatzel, T.: Biophotovoltaics: natural pigments in dye-sensitized solar cells. Appl. Energy 115, 216–225 (2014)

    Article  Google Scholar 

  • Jasim, K.E.: Nanocrystalline TiO2 based natural dye sensitised solar cells. Int. J. Nanomanufacturing. 4, 242–247 (2009)

    Article  Google Scholar 

  • Jasim, K.E.: Natural dye-sensitized solar cell based on nanocrystalline TiO2. Sains Malays. 41(8), 1011–1016 (2012)

    Google Scholar 

  • Jasim, K.E., Al-Dallal, S., AwatifM. Hassan. : Henna (Lawsonia inermis L.) Dye-Sensitized Nanocrystalline Titania Solar Cell. J. Nanotechnol. (2012). https://doi.org/10.1155/2012/167128

    Article  Google Scholar 

  • Kulkarni, S.S., Hussaini, S.S., Bodkhe, G.A., Shirsat, M.D.: Natural hibiscus dye and synthetic organic Eosin Y dye sensitized solar cells using titanium dioxide nanoparticles photo anode: comparative study. Surf. Rev. Lett. 26(3), 1850164–1850170 (2019)

    Article  ADS  Google Scholar 

  • Kumar Rout, S., Padhi, P., Biswal, M., Debata, S.: A Comparative study of a novel technique for the fabrication of dye sensitized solar cells using nano Tio2 and different dyes. RRJOMS. (2018). https://doi.org/10.4172/2321-6212.1000212

    Article  Google Scholar 

  • Lee, K.E., Charbonneau, C., Shan, G.: Nanocrystalline TiO2 thin film electrodes for dye-sensitized solar cell applications. JOM 61, 52–57 (2009)

    Google Scholar 

  • Li, B., Wang, L., Kang, B., Wang, P., Qiu, Y.: Review of recent progress in solid-state dye-sensitized solar cells. Sol. Energy Mater. Sol. Cells 90, 549–573 (2006)

    Article  Google Scholar 

  • Lim, A., Manaf, N.H., Tennakoon, K., Chandrakanthi, R.L.N., Lim, L.B.L., Bandara, J.M.R.S., Ekanayake, P.: Higher performance of DSSC with dyes from Cladophora sp. as mixed cosensitizer through synergistic effect. J. Biophys. (2015). https://doi.org/10.1155/2015/510467

    Article  Google Scholar 

  • Ludin, N.A., Mahmoud, A..M.. Al.-A., Mohamad, A.B., Kadhum Abd, A.H., Sopian, K., Karim, N.S.A.: Review on the development of natural dye photosensitizer for dye-sensitized solar cells. Renew. Sust. Energ Rev. 31, 386–396 (2014)

    Article  Google Scholar 

  • Mohiuddin, O., Obaidullah, M., Sabah, C.: Improvement in dye sensitized solar cells from past to present. Opt. Quantum Electr. 50, 377–405 (2018)

    Article  Google Scholar 

  • Nupearachchi, C. N., Perera, V. P. S.: Utilization of natural henna in combination with black tea as a sensitizer in dye sensitized solar cells. Annual academic sessions, Open University of Sri Lanka. http://repository.ou.ac.lk/bitstream/handle/94ousl/686/OU7283_000.pdf?sequence=1&isAllowed=y (2011)

  • Onwujiuba, C.V., Onuigbo, I.O., Joshua, O.O., Moses, P., Ifekauche, C., Yahaya, M., Joshua, M., Agboola, B.O., Jahng, W.J.: Application of natural plant sensitizers with polyaniline electrode couple in dye-sensitized solar cells. IJSER. 9(10), 1572–1577 (2018)

    Article  Google Scholar 

  • O’Regan, B., Gratzelt, M.: A low-cost, high-efficiency solar cell based on dye-sensitized colloidal Ti02 films. Nature 353, 737–739 (1991)

    Article  ADS  Google Scholar 

  • Ramanarayanan, R., Nijisha, P., Niveditha, C.V., Sindhu, S.: Natural dyes from red amaranth leaves as light-harvesting pigments for dye-sensitized solar cells. Mater. Res. Bull. 90, 156–161 (2017)

    Article  Google Scholar 

  • Sakthivel, S., Baskaran, V.: Fabrication and electrical properties of dye sensitized solar cells using henna, beetroot and amla dyes. Int. J. Sci. Res. 93–96 (2014)

  • Sakthivel, S., Baskaran, V., Mahenthiran, S.: Dye sensitized solar cell properties and fabrication using Lawsonia Inermis. J. Chem. Sci. 5(2), 85–92 (2015)

    Google Scholar 

  • Sathyajothia, S., Jayavelb, R., Clara Dhanemozhi, A.: The fabrication of natural dye sensitized solar cell (Dssc) based on TiO2 using Henna and beetroot dye extracts. Mater. Today. 4, 668–676 (2017)

    Google Scholar 

  • Souad, A.M., Al-Bat’hi Alaei, I., Sopyan, I.: Natural photosensitizers for dye sensitized solar cells. Int. J. Renew. Energy Res. 3(1), 138–143 (2013)

    Google Scholar 

  • Sowmya, S., Pooja, P., Ruba, N., Janarthanan, B., Nagamani Prabu, A., Chandrasekaran, J.: A study on the fabrication and characterization of dye-sensitized solar cells with Amaranthus redand Lawsonia inermisas sensitizers with maximum absorption of visible light. J. Mater. Sci. Mater. Electron. 31, 6027–6035 (2020)

    Article  Google Scholar 

  • Suyitno Rachmad, D.N., Arifin, Z., Saputra, T.J., Omid, M.A., Yusuf, M.: Effect of natural and synthetic dyes on the performance of dye-sensitized solar cells based on ZnO nanorods semiconductor. Appl. Mech. Mater. 699, 577–582 (2015)

    Article  Google Scholar 

  • Taya, S.A., El-Agez, T.M., Abdel-Latif, M.S., El-Ghamri, H.S., Batniji, A.Y., El-Sheikh, I.R.: Fabrication of dye-sensitized solar cells using dried plant leaves. Int. J. Renew. Energy Res. 4(2), 384–388 (2014)

    Google Scholar 

  • Torchani, A., Saadaoui, S., Gharbi, R., Fathallah, M.: Sensitized solar cells based on natural dyes. Curr. Appl. Phys. 15, 307–312 (2015)

    Article  ADS  Google Scholar 

  • What is henna?. Henna color lab. https://www.hennacolorlab.com/what-is-henna/ Accessed 8 December 2020

  • Zhou, H., Wu, L., Gao, Y., Ma, T.: Dye-sensitized solar cells using 20 natural dyes as sensitizers. J. Photoch. Photobio. A. 219, 188–194 (2011)

    Article  Google Scholar 

Download references

Acknowledgements

Authors would like to acknowledge Dr.J.Chandrasekaran, Associate Professor and Head, Department of Physics, and Mr.P.Vivek, Research Scholar, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore for their timely help and support.

Funding

This work was funded by DST Government of India (EMR/2016/007,874). Authors (Sowmya. S, Inbarajan. K, Pooja Prakash and Ruba. N) wish to acknowledge Karpagam Academy of Higher Education for providing KAHE Research Fellowship to carry out this research work.

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SS: Conceptualization; Investigation; Data curation; Formal analysis; Writing—original draft. NR: Investigation; Resources. KI: Formal analysis; Visualization; Writing- Review and editing. PP: Investigation; Data curation. BJ: Validation; Writing- Review & editing: Supervision.

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Correspondence to S. Sowmya.

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Sowmya, S., Ruba, N., Inbarajan, K. et al. Dye-sensitized solar cells concocted with dyes extracted from fresh and dried leaves of Henna using different solvents. Opt Quant Electron 53, 274 (2021). https://doi.org/10.1007/s11082-021-02953-5

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