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Acetylene Hydrogenation on Pd–Zn/Sibunit Catalyst: Effect of Solvent and Carbon Monoxide

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Abstract

The effect of the presence of the N-methyl-2-pyrrolidone (NMP) solvent, on the properties of Pd–Zn/Sibunit catalyst in hydrogenation of a gas mixture enriched in acetylene and hydrogen was studied. It was found that owing to selective solubility of alkanes and alkynes in the NMP medium and to the action of bimetallic Pd–Zn active sites, transformations of the formed C2H4 are efficiently suppressed, so that the ethylene selectivity reaches 85% at the acetylene conversion higher than 90%.. The effect of these factors levels off the modifying effect of carbon monoxide on the ethylene selectivity. Under the conditions of the liquid-phase reaction, the Pd–Zn/Sibunit catalyst demonstrates stable performance with the ethylene yield of 77%.

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REFERENCES

  1. Eliseev, O.L., Russ. J. Gen. Chem., 2009, vol. 79, no. 6, pp. 2509–2519. https://doi.org/10.1134/S1070363209110395

    Article  CAS  Google Scholar 

  2. Zonetti, P.C., Gaspar, A.B., Mendes, F.M.T., Sobrinho, E.V., Sousa-Aguiar, E.F., and Appel, L.G., Fuel Process. Technol., 2010, vol. 91, no. 5, pp. 469–475. https://doi.org/10.1016/j.fuproc.2009.12.006

    Article  CAS  Google Scholar 

  3. Pakhare, D. and Spivey, J., Chem. Soc. Rev., 2014, vol. 43, pp. 7813–7837. https://doi.org/10.1039/C3CS60395D

    Article  CAS  PubMed  Google Scholar 

  4. Johnson, M.M., Peterson, E.R., and Gattis, S.C., The ECLAIRS Process for Converting Natural Gas to Hydrocarbon Liquids, Dallas, 2004.

  5. Johnson, M.M., Peterson, E.R., and Gattis, S.C., US Patent 8410015 B2, 2013.

  6. Johnson, M.M., Peterson, E.R., and Gattis, S.C., US Patent 8460937 B2, 2013.

  7. Zhang, J., Sui, Z., Zhu, Y.-A., Chen, D., Zhou, X., and Yuan, W., Chem. Eng. Technol., 2016, vol. 39, no. 5, pp. 865–873. https://doi.org/10.1002/ceat.201600020

    Article  CAS  Google Scholar 

  8. Zhang, Y., Diao, W., Williams, C.T., and Monnier, J.R., Appl. Catal. A: General, 2014, vol. 469, pp. 419–426. https://doi.org/10.1016/j.apcata.2013.10.024

    Article  CAS  Google Scholar 

  9. Zhou, H., Yang, X., Li, L., Liu, X., Huang, Y., Pan, X., Wang, A., Li, J., and Zhang, T., ACS Catal., 2016, vol. 6, no. 2, pp. 1054–1061. https://doi.org/10.1021/acscatal.5b01933

    Article  CAS  Google Scholar 

  10. Zhang, L., Zhou, M., Wang, A., and Zhang, T., Chem. Rev., 2020, vol. 120, no. 2, pp. 683–733. https://doi.org/10.1021/acs.chemrev.9b00230

    Article  CAS  PubMed  Google Scholar 

  11. Ravanchi, M.T., Sahebdelfar, S., and Komeili, S., Rev. Chem. Eng., 2018, vol. 34, no. 2, pp. 215–237. https://doi.org/10.1515/revce-2016-0036

    Article  CAS  Google Scholar 

  12. Borodziski, A. and Bond, G.C., Catal. Rev., 2008, vol. 50, pp. 379–469. https://doi.org/10.1080/01614940802142102

    Article  CAS  Google Scholar 

  13. Kang, L., Cheng, B., and Zhu, M., Roy. Soc. Open Sci., 2019, vol. 6, no. 11, p. 191155. https://doi.org/10.1098/rsos.191155

    Article  Google Scholar 

  14. Shlyapin, D.A., Glyzdova, D.V., Afonasenko, T.N., Temerev, V.L., and Tsyrul’nikov, P.G., Kinet. Catal., 2019, vol. 60, no. 4, pp. 446–452. https://doi.org/10.1134/S0023158419040165

    Article  CAS  Google Scholar 

  15. Xu, Z., Zhou, S., and Zhu, M., Catal. Commun., 2021, vol. 149, p. 106241. https://doi.org/10.1016/j.catcom.2020.106241

    Article  CAS  Google Scholar 

  16. Hou, R., Wang, T., and Lan, X., Ind. Eng. Chem. Res., 2013, vol. 52, pp. 13305–13312. https://doi.org/10.1016/10.1021/ie303630p

    Article  CAS  Google Scholar 

  17. Larsson, M., Jansson, J., and Asplund, S., J. Catal., 1998, vol. 178, no. 1, pp. 49–57 https://doi.org/10.1006/jcat.1998.2128

    Article  CAS  Google Scholar 

  18. López, N., Bridier, B., and Pérez-Ramírez, J., J. Phys. Chem. C, 2008, vol. 112, pp. 9346–9350. https://doi.org/10.1021/jp711258q

    Article  CAS  Google Scholar 

  19. Afonasenko, T.N., Temerev, V.L., Shlyapin, D.A., and Tsyrul’nikov, P.G., Russ. J. Appl. Chem., 2019, vol. 92, no. 1, pp. 128–134. https://doi.org/10.1134/S1070427219010018X

    Article  CAS  Google Scholar 

  20. Knyazheva, O.A., Baklanova, O.N., and Lavrenov, A.V., Solid Fuel Chem., 2020, vol. 54, no. 6, pp. 345–353. https://doi.org/10.3103/S0361521920060051

    Article  CAS  Google Scholar 

  21. Shitova, N.B., Shlyapin, D.A., Afonasenko, T.N., Kudrya, E.N., Tsyrul’nikov, P.G., and Likholobov, V.A., Kinet. Catal., 2011, vol. 52, no. 2, pp. 251–257. https://doi.org/10.1134/S0023158411020170

    Article  CAS  Google Scholar 

  22. Glyzdova, D.V., Vedyagin, A.A., Tsapina, A.M., Kaichev, V.V., Trigub, A.L., Trenikhin, M.V., Shlyapin, D.A., Tsyrulnikov, P.G., and Lavrenov, A.V., Appl. Catal. A: General, 2018, vol. 563, pp. 18–27. https://doi.org/10.1016/j.apcata.2018.06.029

    Article  CAS  Google Scholar 

  23. Mashkovskii, I.S., Tkachenko, O.P., Baeva, G.N., and Stakheev, A.Yu., Kinet. Catal., 2009, vol. 50, no. 5, pp. 768–774. https://doi.org/10.1134/S0023158409050206

    Article  CAS  Google Scholar 

  24. Karpova, T.R., Buluchevskii, E.A., and Lavrenov, A.V., Katal. Prom–sti, 2017, vol. 17, no. 3, pp. 220–227. https://doi.org/10.1134/S2070050417040055

    Article  CAS  Google Scholar 

  25. Moses, J.M., Weiss, A.H., Matusek, K., and Guczi, L., J. Catal., 1984, vol. 86, no. 2, pp. 417–426. https://doi.org/10.1016/0021-

    Article  CAS  Google Scholar 

  26. Hou, R., Lan, X., and Wang, T., Catal. Today, 2015, vol. 251, pp. 47–52. https://doi.org/10.1016/j.cattod.2014.09.006

    Article  CAS  Google Scholar 

  27. Gaile, A.A. and Zalishchevskii, G.D., N-metilpirrolidon. Poluchenie, svoistva i primenenie v kachestve selektivnogo rastvoritelya (N-Methylpyrrolidone. Synthesis, Properties, and Use as a Selective Solvent), St. Petersburg: Khimizdat, 2005.

  28. Asplund, S., Fornell, C., Holmgren, A., and Irandoust, S., Catal. Today, 1995, vol. 24, pp. 181–187. https://doi.org/10.1016/0920-5861(95)00023-9

    Article  CAS  Google Scholar 

  29. Vattuone, L., Yeo, Y.Y., Kose, R., and King, D.A., Surf. Sci., 2000, vol. 447, pp. 1–14. https://doi.org/10.1016/S0039-6028(99)01192-9

    Article  CAS  Google Scholar 

  30. Dropsch, H. and Baerns, M., Appl. Catal. A: General, 1997, vol. 158, pp. 163–183. https://doi.org/10.1016/S0926-860X(96)00418-8

    Article  CAS  Google Scholar 

  31. Glyzdova, D.V., Afonasenko, T.N., Talsi, V.P., and Shlyapin, D.A., AIP Conf. Proc., 2020, vol. 2301, no. 1, Article no. 030005. https://doi.org/10.1063/5.0032868

  32. Edvinsson, R.K., Holmgren, A.M., and Irandoust, S., Ind. Eng. Chem. Res., 1995, vol. 34, pp. 94–100. https://doi.org/10.1021/ie00040a0

    Article  CAS  Google Scholar 

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov lnstitute of Catalysis (project AAAA-A21-121011390011-4).

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Correspondence to D. V. Glyzdova.

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Translated from Neftekhimiya, 2021, Vol. 61, No. 3, pp. 388–396 https://doi.org/10.31857/S0028242121030102.

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Glyzdova, D.V., Afonasenko, T.N., Temerev, V.L. et al. Acetylene Hydrogenation on Pd–Zn/Sibunit Catalyst: Effect of Solvent and Carbon Monoxide. Pet. Chem. 61, 490–497 (2021). https://doi.org/10.1134/S0965544121050169

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