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The Surface Properties of Solutions of Dicationic Imidazolium Surfactants with Short Bridge Fragments

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Abstract—

The pendant drop shape and oscillating pendant drop methods have been employed to study the surface tension and the dilatational rheological surface characteristics at the solution–air interface for aqueous solutions of dicationic imidazolium surfactants with extremely short bridge fragments. A high surface activity has been revealed for these surfactants. High values of the dilatational viscoelasticity modulus have been found for the surfactant solutions. The modulus values increase with a decrease in the length of bridge fragments and an increase in the length of hydrocarbon radicals in surfactant molecules.

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ACKNOWLEDGEMENTS

We are grateful to Cand. Sc. (Chem.) V.A. Mikhailov (Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry) for synthesizing the diimidazolium surfactants used in this work.

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  1. Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry, 283114, Donetsk-114, Ukraine

    A. A. Kotenko & S. L. Khil’ko

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  1. A. A. Kotenko
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  2. S. L. Khil’ko
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Correspondence to S. L. Khil’ko.

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Translated by E. Khozina

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Kotenko, A.A., Khil’ko, S.L. The Surface Properties of Solutions of Dicationic Imidazolium Surfactants with Short Bridge Fragments. Colloid J 83, 211–218 (2021). https://doi.org/10.1134/S1061933X21020058

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