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A Study of the Step of Alkene Activation under Ligand-Free Conditions in the Mizoroki–Heck Reaction with Unreactive Aryl Chlorides

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Abstract

The results of a kinetic study on the character (fast or slow) of a step of alkene activation in the catalytic cycle of the Mizoroki–Heck reaction with unreactive aryl chlorides in the presence of a so-called ligand-free catalytic system based on palladium are presented. An analysis of integral kinetic curves of the consumption of two competing alkenes in the reaction with aryl chloride showed that alkenes participate in a fast step of the catalytic cycle.

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Funding

This work was supported by the Russian Science Foundation (project no. 19-73-10004) and performed using the equipment of the Center for Collective Use of Analytical Equipment at the Irkutsk State University (http://ckp-rf.ru/ckp/3264/).

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Authors and Affiliations

  1. Department of Chemistry, Irkutsk State University, 664003, Irkutsk, Russia

    A. A. Kurokhtina, E. V. Larina, E. V. Vidyaeva, N. A. Lagoda & A. F. Schmidt

Authors
  1. A. A. Kurokhtina
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  2. E. V. Larina
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  3. E. V. Vidyaeva
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  4. N. A. Lagoda
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  5. A. F. Schmidt
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Corresponding author

Correspondence to A. F. Schmidt.

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The authors declare that they have no conflicts of interest.

Additional information

Translated by V. Makhlyarchuk

Abbreviations and designations: DMF, N,N-dimethylformamide.

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Kurokhtina, A.A., Larina, E.V., Vidyaeva, E.V. et al. A Study of the Step of Alkene Activation under Ligand-Free Conditions in the Mizoroki–Heck Reaction with Unreactive Aryl Chlorides. Kinet Catal 62, 307–314 (2021). https://doi.org/10.1134/S0023158421020051

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  • DOI: https://doi.org/10.1134/S0023158421020051

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