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Two New 3D Metal-Organic Frameworks Constructed by Polycarboxylate and N-Donor Ligands: Crystal Structure, Photocatalytic Performances, and DFT Calculation

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Abstract

Two new metal-organic frameworks, [Zn(Bdc)(Bip)∙H2O] (I) and {[Cd2(Btc)2(H2O)2](H2Bib)· 6H2O} (II) (H2Bdc = 1,3-benzenedicarboxylic acid, H3Btc = 1,3,5-benzenetricarboxylic acid, Bib = 1,4-bis(2-methylimidazol-1′-yl)butane, Bip = 1,5-bis(2-methylimidazol-1-yl)pentane), have been successfully synthesized solvothermally and characterized by elemental analyses, UV−Vis spectroscopy, photocatalysis and single crystal X-ray diffraction (CIF files CCDC nos. 1982779 (I) and 1982780 (II). Complex I exhibits a 3-fold interpenetrating motif having dmp net with {65·8} topology, complex II possesses 3D anionic network comprising of 3,6-connected {4·62}2{42·610·83} topology. These MOFs could be taken as photocatalysts for degrading the methyl violet (MV), in which indicate their effective photocatalytic behavior for the degradation of MV. In addition, the suggested photocatalytic mechanism through density of states plots for I and II was discussed.

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Funding

The authors acknowledge financial assistance from Sichuan University of Science and Engineering (nos. 2019RC21), the Project of Zigong Science and Technology (nos. 2018YYJC01 and 2019YYJC06), the Student’s Platform for Innovation and Entrepreneurship Training Program (cx2019013), and Special Funds for Scientific Technological Innovation of Undergraduates in Guangdong Province (pdjh2020b0267 and pdjh2020b0265). Dr. Mohd. Muddassir is grateful Researchers Supporting Project (RSP-2019/141), King Saud University, Riyadh, Saudi Arabia for financial assistance.

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Correspondence to J. Wang or A. Q. Ma.

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Tan, X.Y., Wang, J., Rao, C.Y. et al. Two New 3D Metal-Organic Frameworks Constructed by Polycarboxylate and N-Donor Ligands: Crystal Structure, Photocatalytic Performances, and DFT Calculation. Russ J Coord Chem 47, 296–305 (2021). https://doi.org/10.1134/S1070328421040072

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  • DOI: https://doi.org/10.1134/S1070328421040072

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