Skip to main content
SpringerLink
Log in

Hierarchical highly porous composite ceramic material modified by hydrophobic methyltrimetoxysilane-based aerogel

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

A highly porous composite material consisting of silicon dioxide microfibers filled with nanoporous methyltrimethoxysilane-based aerogel was synthesized by a sol–gel procedure followed by supercritical drying in isopropanol and CO2. The textural and mechanical properties of the composite were studied. A synergism of the mechanical properties of components was demonstrated. The material showed high hydrophobic properties—the water drop contact angle was 142° after 14 days under 100% humidity and low water absorption was found. The composite material retained its mechanical integrity after several freeze-thaw procedures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Scheme 1
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. B.V. Shchetanov, Y.A. Ivakhnenko, V.G. Babashov, Russ. J. Gen. Chem. 81, 978 (2011)

    Article  CAS  Google Scholar 

  2. J.C. Fletcher, M. Smith, D. Leiser. US3952083 (1976)

  3. J. Marschall, F.S. Milos, J. Thermophys. Heat Transf. 12, 528 (1998)

    Article  CAS  Google Scholar 

  4. D.J. Green, J. Am. Ceram. Soc. 66, 288 (1983)

    Article  Google Scholar 

  5. H.K. Tran, D.J. Rasky, L. Esfahani, J. Spacecr. Rockets 31, 993 (1994)

    Article  CAS  Google Scholar 

  6. A.S. Dorcheh, M.H. Abbasi, J. Mater. Process. Technol. 199, 10 (2008)

    Article  Google Scholar 

  7. X.Y. Yang, L.H. Chen, Y. Li, J.C. Rooke, C. Sanchez, B.L. Su, Chem. Soc. Rev. 46, 481 (2017)

    Article  CAS  Google Scholar 

  8. A. Parvathy Rao, A. Venkateswara Rao, J. Mater. Sci. 45, 51 (2010)

    Article  Google Scholar 

  9. H.X. Liu, F. Tang, R. Shao, R. Dong, M.L. Jia, S. Chen, Proc. Natl. Conf. Chin. Funct. Mater. Appl. 307, 20 (2010)

    Google Scholar 

  10. W.J. Malfait, S. Zhao, R. Verel, S. Iswar, D. Rentsch, R. Fener, Y. Zhang, B. Milow, M.M. Koebel, Chem. Mater. 27, 6737 (2015)

    Article  CAS  Google Scholar 

  11. A.Y. Fadeev, T.J. McCarthy, Langmuir 15, 7238 (2002)

    Article  Google Scholar 

  12. K.G. Marinova, D. Christova, S. Tcholakova, E. Efremov, N.D. Denkov, Langmuir 21, 11729 (2005)

    Article  CAS  Google Scholar 

  13. L. Mayrhofer, G. Moras, N. Mulakaluri, S. Rajagopalan, P.A. Stevens, M. Moseler, J. Am. Chem. Soc. 138, 4018 (2016)

    Article  CAS  Google Scholar 

  14. J.C. Biffinger, H.W. Kim, S.G. DiMagno, ChemBioChem 5, 622 (2004)

    Article  CAS  Google Scholar 

  15. A.S. Bespalov, V.M. Buznik, D.V. Grashchenkov, L.N. Nikitin, V.K. Ivanov, V.O. Lebed’, I.S. Chashchin, Inorg. Mater. 52, 386 (2016)

    Article  CAS  Google Scholar 

  16. A. Venkateswara Rao, S.D. Bhagat, H. Hirashima, G.M. Pajonk, J. Colloid Interface Sci. 300, 279 (2006)

    Article  Google Scholar 

  17. G. Hayase, K. Kanamori, K. Nakanishi, J. Mater. Chem. 21, 17077 (2011)

    Article  CAS  Google Scholar 

  18. S. Yun, H. Luo, Y. Gao, RSC Adv. 4, 4535 (2014)

    Article  CAS  Google Scholar 

  19. S.A. Lermontov, N.A. Sipyagina, A.N. Malkova, A.E. Baranchikov, V.K. Ivanov, Russ. J. Inorg. Chem. 59, 1392 (2014)

    Article  CAS  Google Scholar 

  20. S.A. Lermontov, N.A. Sipyagina, A.N. Malkova, A.E. Baranchikov, K.E. Erov, D.I. Petukhov, V.K. Ivanov, Russ. J. Inorg. Chem. 60, 488 (2015)

    Article  CAS  Google Scholar 

  21. N. Hüsing, U. Schubert, Angew. Chem. Int. Ed. 37, 22 (1998)

    Article  Google Scholar 

  22. A. Venkateswara Rao, N.D. Hegde, H. Hirashima, J. Colloid Interface Sci. 305, 124 (2007)

    Article  CAS  Google Scholar 

  23. L.W. Hrubesh, P.R. Coronado, J.H. Satcher, J. Non-Cryst. Solids 285, 328 (2001)

    Article  CAS  Google Scholar 

  24. W.-C. Li, M. Comotti, A.-H. Lu, F. Schüth, Chem. Commun. 2, 1772 (2006)

    Article  Google Scholar 

  25. A. Venkateswara Rao, G.M. Pajonk, J. Non-Cryst. Solids 285, 202 (2001)

    Article  CAS  Google Scholar 

  26. T.S. Zemanian, G.E. Fryxell, J.L.J. Liu, S. Mattigod, Y.S.Y. Shin, J.A. Franz, O. Ustyugov, Z.N.Z. Nie, in Proceedings of the 2001 1st IEEE Conference on Nanotechnology. IEEE-NANO 2001 (Cat. No.01EX516) 288 (2001)

  27. A.B.D. Cassie, S. Baxter, Trans. Faraday Soc. 40, 546 (1944)

    Article  CAS  Google Scholar 

  28. R.N. Wenzel, Ind. Eng. Chem. 28, 988 (1936)

    Article  CAS  Google Scholar 

  29. B. Chal, G. Foray, B. Yrieix, K. Masenelli-Varlot, L. Roiban, J.M. Chenal, Microporous Mesoporous Mater. 272, 61 (2018)

    Article  CAS  Google Scholar 

  30. D.P. Kiryukhin, A.S. Bespalov, V.M. Bouznik, D.V. Grashchenkov, V.K. Ivanov, I.A. Zvereva, G.A. Kichigina, P.P. Kushch, Perspekt. Mater. 10, 54 (2018). https://doi.org/10.30791/1028-978X-2018-10-54-62 ((in Russian))

    Article  Google Scholar 

  31. M. Schwan, M. Rößler, B. Milow, L. Ratke, Gels 2, 1 (2015)

    Article  Google Scholar 

  32. S. Zhao, W.J. Malfait, A. Demilecamps, Y. Zhang, S. Brunner, L. Huber, P. Tingaut, A. Rigacci, T. Budtova, M.M. Koebel, Angew. Chem. Int. Ed. 54, 14282 (2015)

    Article  CAS  Google Scholar 

  33. S.A. Lermontov, A.N. Malkova, N.A. Sipyagina, A.E. Baranchikov, D.I. Petukhov, V.K. Ivanov, Russ. J. Inorg. Chem. 60, 1169 (2015)

    Article  CAS  Google Scholar 

  34. S. Lermontov, A. Malkova, L. Yurkova, E. Straumal, N. Gubanova, A. Baranchikov, M. Smirnov, V. Tarasov, V. Buznik, V. Ivanov, J. Supercrit. Fluids 89, 28 (2014)

    Article  CAS  Google Scholar 

  35. K. Tajiri, K. Igarashi, T. Nishio, J. Non-Cryst. Solids 186, 83 (1995)

    Article  CAS  Google Scholar 

  36. C.C. Ballard, E.C. Broge, R.K. Iler, D.S. St. John, J.R. McWhorter, J. Phys. Chem. 65, 20 (1961)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the Russian Foundation for Basic Research (Grant No. 18-29-06014), synthesis and studying of the TZMK composites hydrophobicity were accomplished within the IPAC RAS state assignment of 2020 (Theme No. 0090-2019-0002) using the equipment of the IPAC RAS Joint Research Centre.

Author information

Authors and Affiliations

  1. Institute of Physiologically Active Compounds of the Russian Academy of Sciences, Chernogolovka, Russia, 142432

    S. A. Lermontov, N. A. Sipyagina & A. N. Malkova

  2. All-Russian Scientific Research Institute of Aviation Materials, Moscow, Russia, 105005

    V. M. Buznik, A. S. Bespalov & D. V. Grashchenkov

  3. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Moscow, Russia, 119991

    A. E. Baranchikov

Authors
  1. S. A. Lermontov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. M. Buznik
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. A. Sipyagina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. S. Bespalov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. N. Malkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. D. V. Grashchenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. E. Baranchikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. A. Lermontov.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (TIF 2920 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lermontov, S.A., Buznik, V.M., Sipyagina, N.A. et al. Hierarchical highly porous composite ceramic material modified by hydrophobic methyltrimetoxysilane-based aerogel. J Porous Mater 28, 1237–1244 (2021). https://doi.org/10.1007/s10934-021-01075-3

Download citation

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-021-01075-3

Keywords

Search

Navigation