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Influence of Synthesis Conditions on the Physicochemical Properties of Poly-2-[(2E)-1-methyl-2-buten-1-yl]aniline

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Abstract

A new polymer, poly-2-(1-methylbut-2-en-1-yl)aniline, is synthesized using doping and oxidizing agents. The influence of its preparation conditions on the physicochemical properties of materials is considered. The morphology of polymers is investigated by scanning electron microscopy, their solubility and IR and UV spectral characteristics are studied, and the photoluminescent properties are revealed. It is shown that the properties of the polymer depend on the nature of the doping agent. It is found that the use of FeCl3 as an oxidizing agent makes it possible to obtain the material in the doped form and with the highest luminescence intensity. The synthesized polymers are tested as an active material in moisture sensors.

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Funding

This work was supported by the Russian Foundation for Basic Research (project no. 19-33-90147\19) and was carried out within the framework of the State Assignment AAAA-A19-119020890014-7.

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Authors and Affiliations

  1. Bashkir State University, 450076, Ufa, Russia

    A. N. Andriianova, D. E. Gribko, I. N. Mullagaliev, R. B. Salikhov & A. G. Mustafin

  2. Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences, 450054, Ufa, Russia

    A. N. Andriianova & A. G. Mustafin

Authors
  1. A. N. Andriianova
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  2. D. E. Gribko
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  3. I. N. Mullagaliev
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  4. R. B. Salikhov
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  5. A. G. Mustafin
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Correspondence to A. N. Andriianova.

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Andriianova, A.N., Gribko, D.E., Mullagaliev, I.N. et al. Influence of Synthesis Conditions on the Physicochemical Properties of Poly-2-[(2E)-1-methyl-2-buten-1-yl]aniline. Polym. Sci. Ser. B 63, 135–141 (2021). https://doi.org/10.1134/S1560090421020032

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  • DOI: https://doi.org/10.1134/S1560090421020032

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