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Synthesis and Properties of Polymerization-Filled Composites Based on Polypropylene and Single-Wall Carbon Nanotubes

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Abstract

Composites based on polypropylene and single-wall carbon oxygen-containing nanotubes with a specific surface area of 360 and 500 m2/g are synthesized in the medium of liquid propylene using the catalytic system rac-Me2Si(2-Me-4-PhInd)2ZrCl2/МАО. Optimum polymerization conditions ensuring a fairly high rate of the process are determined, and the composites with the filler content in the range from 0.3 to 13.0 wt % are obtained. It is shown that the presence of functional groups enhances the filler agglomeration tendency during composite formation. Effects of the type of carbon nanofiller on the thermal stability, thermo-oxidative resistance, and thermal and electrophysical characteristics of the composites are studied. It is found that the filler inhibits the processes of oxidation and destruction of polypropylene crystallites.

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ACKNOWLEDGMENTS

We are grateful to A.Ya. Gorenberg for SEM analyses of the samples and T.M. Medintseva for the mechanical testing of the composites.

Funding

This work was carried out within the framework of State Assignment no. 0082-2019-0004.

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Authors and Affiliations

  1. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    O. M. Palaznik, P. M. Nedorezova & V. G. Krasheninnikov

  2. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, 117393, Moscow, Russia

    V. G. Shevchenko

  3. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    T. V. Monakhova

  4. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    A. A. Arbuzov

Authors
  1. O. M. Palaznik
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  2. P. M. Nedorezova
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  3. V. G. Shevchenko
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  4. V. G. Krasheninnikov
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  5. T. V. Monakhova
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  6. A. A. Arbuzov
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Corresponding author

Correspondence to P. M. Nedorezova.

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Translated by T. Soboleva

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Palaznik, O.M., Nedorezova, P.M., Shevchenko, V.G. et al. Synthesis and Properties of Polymerization-Filled Composites Based on Polypropylene and Single-Wall Carbon Nanotubes. Polym. Sci. Ser. B 63, 161–174 (2021). https://doi.org/10.1134/S1560090421020093

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  • DOI: https://doi.org/10.1134/S1560090421020093

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