Microstructure, Residual Stresses, and Strain-Rate-Dependent Deformation and Fracture Behavior of AISI 304L Joints Brazed with NiCrSiB Filler Metals
Abstract
:1. Introduction
2. Materials and Methods
2.1. Production of Filler Metals and Alloy Compositions
2.2. Brazing Process
2.3. Specimen Geometry and Manufacturing
2.4. Microstructural Analysis
2.5. Residual Stress Measurements
2.6. Residual Stress Calculation with the Finite Element Method
2.7. Mechanical Testing Methods
2.7.1. Impact Tests
2.7.2. Instrumented Tensile Tests at a Low Strain Rate
2.7.3. Tensile Tests at a High Strain Rate
3. Results and Discussion
3.1. Alloying and Holding-Time-Dependent Microstructure Formation
3.2. Residual Stresses
3.2.1. Measured Distribution in the Radial and Axial Directions
3.2.2. Influence of Alloying and Holding Time
3.2.3. Calculated Distribution of Residual Stresses after Brazing
3.3. Mechanical Test Results
3.3.1. Effect of Brazing Process Parameters on the Base Material
3.3.2. Local Deformation Behavior
3.3.3. Thermal, Electrical, and Magnetic Material Responses
3.3.4. Strain Rate Dependency
3.3.5. Comparison of Ultimate Tensile Strength and Impact Toughness
3.4. Fracture Mechanism
4. Summary and Conclusions
- It was found that the formation of brittle phases was particularly evident with a high chromium content that, at 20 wt.%, exceeded the content in the base material in combination with molybdenum for a short holding time of 15 min.
- The longer holding time of 40 min led to the homogenization of the brazing seam with fewer borides and silicides in all filler metals.
- Using an EBSD analysis, it was shown that martensite formation can occur in the diffusion zone due to the brazing process.
- Using X-ray diffraction measurements, a significant gradient from the brazing seam to the base material was proved, and a dependency on the filler metals used was established.
- Due to the different diffusion-related sizes of the brazing seam width for the two holding times investigated, it was not possible to compare different holding times for a fixed collimator diameter.
- An FEM simulation based on an experimentally determined coefficient of thermal expansion showed high compressive residual stresses for the inner seam. These simulated stresses were comparable with the measured residual stresses considering post-processing.
- The annealing of the base material AISI 304L, according to the time–temperature curve of the brazing process, leads to a tensile strength reduction of about 20%.
- For two of the three alloy variations, a holding time of 40 min led to an ultimate tensile strength (UTS) that was close to that of the base material in the annealed state.
- The critical effect of brittle phases was most present under impact loadings.
- In the high-speed tensile tests, it was found that high strain rates increased the UTS of all variations and shifted the other mechanical properties.
- The best results were shown by the filler metals Ni7Cr7.5Si4Fe1.5B (ST07) and Ni15Cr7.5Si4Fe4Mo1.5B wt.% (ST15), demonstrating impact toughness of 86 ± 3 J/cm2 and 90 ± 2 J/cm2, respectively, as well as almost identical UTS values: 629 ± 9 MPa for the low strain rate and 700 ± 5 MPa for the high strain rate.
- Large brittle phases that were located in the center of the brazed seam showed the most negative influence on the initiation and propagation of cracks.
- Brittle borides in the diffusion zone can break inside the surrounding metal matrix under testing without extending into the matrix of the base material.
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Alloy | Alloy Composition (wt.%) | Melting Range * (°C) | ||||||||
---|---|---|---|---|---|---|---|---|---|---|
Fe | Ni | Cr | C | Si | Mn | Mo | B | |||
AISI 304L | bal. | 8.03 | 18.14 | 0.023 | 0.30 | 1.54 | 0.34 | – | Tsolidus | Tliquidus |
ST07 | 4.0 | bal. | 7.0 | – | 7.5 | – | – | 1.5 | 958 | 1111 |
ST15 | 4.0 | bal. | 15.0 | – | 7.5 | – | 4.0 | 1.5 | 1049 | 1115 |
ST20 | 4.0 | bal. | 20.0 | – | 7.5 | – | 4.0 | 1.5 | 1078 | 1125 |
Mode | Heating Rate 1 | First Holding Time | Heating Rate 2 | Final Holding Time |
---|---|---|---|---|
Mode 1 | 40 K/min | 15 min at 900 °C | 20 K/min | 15 min at 1160 °C |
Mode 2 | 40 K/min | 15 min at 900 °C | 20 K/min | 40 min at 1160 °C |
Parameter | Sign, (Unit) | Value | Parameter | Sign, (Unit) | Value |
---|---|---|---|---|---|
Target | −, (−) | Cu | Tilt | ψ, (°) | +/−0, +/−11.25, +/−22.5, +/−33.75, +/−45 |
Wavelength kα1 | λ, (nm) | 0.1540549 | Azimuth Positions | φ, (°) | 0 and 180, 90 and 270 |
Bragg Angle | 2θ, (°) | 147.200 | Measurement Modus | −, (−) | Side Inclination |
Diffraction Plane | {hkl}, (−) | 420 | Scale Factor.0 | s1{hkl}, (10−6 mm2/N) | 1.79×10−6 mm2/N |
Current | i, (mA) | 40 | Scale Factor | ½ s2{hkl}, (10−6 mm2/N) | 7.48×10−6 mm2/N |
Voltage | u, (kV) | 40 | Poisson’s Ratio | ν, (−) | 0.31 |
Collimator Diameter | −, (µm) | 0.30 | Young’s Modulus | E, (GPa) | 176 |
Material | Density (g/cm3) | CTE (10−6 1/K) | Young’s Modulus (GPa) | Poisson’s Ratio (−) | |||
---|---|---|---|---|---|---|---|
RT | RT | 1160 °C | RT | 1160 °C | RT | 1160 °C | |
AISI 304L | 7.9 | 13.9 | 21.0 | 193 | 82 | 0.12 | 0.30 |
Brazing Seam | 8.0 | 12.2 | 23.5 | 195 | 111 | 0.31 | 0.35 |
Position (mm) | Holding Time 40 min | Holding Time 15 min | AISI 304L | ||||
---|---|---|---|---|---|---|---|
ST20 | ST15 | ST07 | ST20 | ST15 | ST07 | ||
+2.0 | −296 ± 30 | −264 ± 76 | −261 ± 59 | −277 ± 23 | −170 ± 101 | −103 ± 197 | −219 ± 73 |
+1.0 | −248 ± 27 | −236 ± 65 | −209 ± 70 | −237 ± 91 | −180 ± 41 | −183 ± 78 | −247 ± 58 |
+ 0.1 | −314 ± 68 | −281 ± 47 | −214 ± 78 | −293 ± 39 | −209 ± 68 | −280 ± 138 | −249 ± 62 |
0.0 | −490 ± 57 | −475 ± 28 | −409 ± 36 | −395 ± 76 | −384 ± 124 | −375 ± 107 | −287 ± 65 |
−0.1 | −315 ± 98 | −291 ± 62 | −230 ± 68 | −245 ± 78 | −293 ± 197 | −213 ± 211 | −214 ± 30 |
−1.0 | −225 ± 40 | −242 ± 69 | −227 ± 74 | −209 ± 68 | −217 ± 147 | −146 ± 62 | −257 ± 29 |
−2.0 | −252 ± 61 | −278 ± 73 | −270 ± 56 | −246 ± 62 | −212 ± 135 | −69 ± 73 | −292 ± 54 |
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Otto, J.L.; Penyaz, M.; Möhring, K.; Gerdes, L.; Schaum, T.; Ivannikov, A.; Schmiedt-Kalenborn, A.; Kalin, B.; Walther, F. Microstructure, Residual Stresses, and Strain-Rate-Dependent Deformation and Fracture Behavior of AISI 304L Joints Brazed with NiCrSiB Filler Metals. Metals 2021, 11, 593. https://doi.org/10.3390/met11040593
Otto JL, Penyaz M, Möhring K, Gerdes L, Schaum T, Ivannikov A, Schmiedt-Kalenborn A, Kalin B, Walther F. Microstructure, Residual Stresses, and Strain-Rate-Dependent Deformation and Fracture Behavior of AISI 304L Joints Brazed with NiCrSiB Filler Metals. Metals. 2021; 11(4):593. https://doi.org/10.3390/met11040593
Chicago/Turabian StyleOtto, Johannes L., Milena Penyaz, Kerstin Möhring, Lars Gerdes, Thorge Schaum, Alexander Ivannikov, Anke Schmiedt-Kalenborn, Boris Kalin, and Frank Walther. 2021. "Microstructure, Residual Stresses, and Strain-Rate-Dependent Deformation and Fracture Behavior of AISI 304L Joints Brazed with NiCrSiB Filler Metals" Metals 11, no. 4: 593. https://doi.org/10.3390/met11040593