Skip to main content
SpringerLink
Log in

Solvent Effects on Spin-Spin Coupling Constants in Organomercury Compounds

  • Published:
Journal of Contemporary Physics (Armenian Academy of Sciences) Aims and scope

Abstract

For better visualization of solvent effects on spin-spin coupling constants (SSCCs) we have investigated some organomercury compounds, which have large solvent induced changes on one-bond C-Hg SSCCs. Extra large solvent effects (up to 20% of SSCC value) have been observed, which allow to more carefully examine the peculiarities of SSCC’s solvent and electric field dependencies in various media.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Ando, I., Encyclopedia of NMR, Chichester: Wiley, 1996, pp. 2512–2515.

    Google Scholar 

  2. Reichardt, C., Solvent and Solvent Effects in Organic Chemistry, Weinheim: Wiley-VCH, 2003.

    Google Scholar 

  3. Dracinsky, M. and Bour, P., J. Chem. Theory Comput., 2010, vol. 6, p. 288.

    Article  Google Scholar 

  4. Barfield, M. and Johnston, M.D., Chem. Rev., 1973, vol. 73, p. 53.

    Article  Google Scholar 

  5. Jokisaari, J. and Raisanen, K., Mol. Phys., 1978, vol. 36, p. 113.

    Article  ADS  Google Scholar 

  6. Shahkhatuni, A.A., Sahakyan, A.B., Shahkhatuni, A.G., Panosyan, H.A., and Mamyan, S.S., Chem. Phys. Lett., 2012, vol. 542, p. 56.

    Article  ADS  Google Scholar 

  7. Shahkhatuni, A.A., Shahkhatuni, A.G., Minasyan, N.S., Panosyan, H.A., and Sahakyan, A.B., J. Mol. Struct., 2015, vol. 1083, p. 175.

    Article  ADS  Google Scholar 

  8. Shakhatuni, A.A., Mamyan, S.S., Minasyan, N.S., Shakhatuni, A.G., and Panosyan, A.G., Proceedings of the STCOPC of NAS RA., issue 3, Yerevan: Antares, 2017, pp. 220–240 (in Russian).

Download references

Funding

The study was carried out with the financial support of the Science Committee of the Ministry of Education, Science, Culture and Sport of the Republic of Armenia (18T-1D392). The authors are grateful to A.M. Arzumanyan for providing organomercury compounds.

Author information

Authors and Affiliations

  1. Scientific Technological Center of Organic and Pharmaceutical Chemistry, NAS of Armenia, Yerevan, Armenia

    A. A. Shahkhatuni & A. G. Shahkhatuni

  2. Yerevan State University, Yerevan, Armenia

    A. S. Movsisyan & A. A. Shahinyan

Authors
  1. A. A. Shahkhatuni
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. S. Movsisyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Shahinyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. G. Shahkhatuni
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Shahkhatuni.

Ethics declarations

The authors declare no conflict of interest.

Additional information

Translated by A. Shahkhatuni

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shahkhatuni, A.A., Movsisyan, A.S., Shahinyan, A.A. et al. Solvent Effects on Spin-Spin Coupling Constants in Organomercury Compounds. J. Contemp. Phys. 56, 69–72 (2021). https://doi.org/10.3103/S1068337221010114

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1068337221010114

Keywords:

Search

Navigation