Abstract
In the present work, Ag loading SnO2 nanoparticles were synthesized using simple hydrothermal method with different Ag weight percentage concentrations (2, 4, and 6) wt%. The structural and morphological properties of the prepared samples were characterized and analyzed by field emission scanning electron microscopy (FE-SEM) and X-ray diffraction. The XRD analysis showed a tetragonal rutile phase of SnO2 with high crystalline, and the grain size was observed to decrease with the increase of Ag concentration. FE-SEM images depict the formation of spherically shaped and small-sized nanoparticles with average diameter of 69–77 nm and its decrease to 24 nm after doping with Ag. The gas sensing result showed maximum sensitivity to NO2 gas for the sample with 6 wt% Ag concentration at operating temperature 100 °C and NO2 gas concentration 50 ppm.
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E. Nunez Carmona, A. Bertuna, M. Abbatangelo, V. Sberveglieri, E Comini, G. Sberveglieri, "BC-MOS: The novel bacterial cellulose based MOS gas sensors". Mater. Lett. 237, 69–71 (2019)
C.E. Kim, M. Moon, S. Kim, J.M. Myoung, H.W. Jang, “Effect of carrier concentration on optical bandgap shift in ZnO: Ga thin films.” Thin Solid Films 518, 6304–6307 (2010)
E. Núñez-Carmona, M. Abbatangelo, V. Sberveglieri, Innovative, “Sensor approach to follow Campylobacter jejuni development.” Biosensors 9, 8 (2019)
A.K. Singh, S.B. Patil, S.S. Multani, ZnO nano-rods and nanopolypods synthesized using microwave assisted wet chemical and thermal evaporation method. Indian J. Pure Appl. Phys. 49, 270–276 (2011)
C. Jaeschke, O. Gonzalez, M. Padilla, K. Richardson, J Glockler, J. Mitrovics, B. Mizaiko, " Novel modular system for breath analysis using temperature modulated MOX sensors". Proceedings 14, 49 (2019)
D. Li, W.Y. Lai, Y.Z. Zhang, W.Huang, Printable "Transparent conductive films for flexible electronics". Adv. Mater. 30, 1–24 (2018)
F. Yan, G. Shen, X. Yang , T. Qi , J. Sun, X. Li, M. Zhang, Low operating temperature and highly selective NH3 chemiresistive gas sensors based on Ag3PO4 semiconductor. Appl. Surf. Sci. 479, 1141–1147 (2019)
M. Abbatangelo, E. Núñez-Carmona,V. Sberveglieri, E. Comini, G. Sberveglieri, "k-NN and k-NN-ANN combined classifier to assess MOX gas sensors performances affected by drift caused by early life aging" Chemosensors, 8, 6 (2020). 10.3390.
H. Hayashi, Y. Hakuta, Hydrothermal synthesis of metal oxide nanoparticles in supercritical water. Materials 3, 3794–3817 (2010)
S. Blessi, M.M.L. Sonia, S. Vijayalakshmi, S. Pauline, Preparation and characterization of SnO2 nanoparticles by hydrothermal method. Int J. Chem. Tech. Res. 6(3), 2153–2155 (2014)
Y.C. Lee, Hui Huang, O.K. Tan, M.S. Tse, Semiconductor gas sensor based on Pd-loading SnO2 nanorod thin films. Sens. Actuators. B. 132, 239–242 (2008)
H.J. Snaith, C. Ducati, SnO2-based dye-sensitized hybrid solar cells exhibiting near unity absorbed pho-ton-to-electron conversion efficiency. Nano. Lett. 10(4), 1259–1265 (2010)
P.S. Joshi, S.M. Jogade, P.A. Lohar, D.S. Sutrave, Antimony loading tin oxide thin films: Co gas sensor. J. Nano- Electron. Phys. 3(1), 956–962 (2011)
A.K. Singh, U.T. Nakate1, Microwave synthesis, characterization and photo catalytic properties of SnO2 nanoparticles. Advances in Nanoparticles, 2, 66–70 (2013)
Wen Zeng1, Tianmo Liu1 and Zhongchang Wang, "UV light activation of TiO2-doped SnO2 thick film for sensing ethanol at room temperature", Mater. Trans. 51(2), 243- 245 (2010)
I.G. Atanasov, A.O. Dimitrov, Dikovska," Investigation on the structural and optical properties of tin oxide films grown by pulsed laser deposition". J. Optoelectron. Adv. Mater. 7(3), 1335–1340 (2005)
J. Li, D. Gu, Y. Yang, H. Du, X. Li, UV light activated SnO2/ZnO nanofibers for gas sensing at room temperature. Front. Mater. 6, 1–8 (2019)
Y.M. Lu, J. Jiang, M. Becker, B. Kramm, L. Chen, A. Polity, Y.B. He, P.J. Klar, B.K. Meyer, "Polycrystalline SnO2 films grown by chemical vapor deposition on quartz glass, Vacuum, 122, Part B, 347–352 (2015)
T. J. Stanimirova, P. A. Novinrooz, Abdoljavad, P. Sarabadani, J. Garousi, "Characterization of pure and antimony doped SnO2 thin Films prepared by the sol-gel technique" Iran. J. Chem. Chem. Eng. 25(2), 31–38 (2006)
M. Ferreira, J. Loureiro, A. Nogueira, A. Rodrigues, R. Martins, I. Ferreira, "SnO2 thin film oxides produced by rf sputtering for transparent thermoelectric devices", Mater. Today. 2(2), 647–653 (2015)
M.A.M. Akhir, S.A. Rezan, K. Mohamed, M.M. Arafat, H.L. Lee, “Synthesis of SnO2 nanoparticles via hydrothermal method and their gas sensing applications for ethylene detection”, Mater. Today. 17. Part 3, 810–819 (2019)
E.S. Hassan, A.K. Elttayef, S.H. Mostafa, M.H. Salim, S.S. Chiad, Silver oxides nanoparticle in gas sensors applications, J. Mater. Sci. Mater. Electron. 3(17), 15943–15951 (2019)
S.K. Muhammad, E.S. Hassan, K.Y. Qader, K.H. Abass, S.S. Chiad, N.F. Habubi, Effect of vanadium on structure and morphology of SnO2 thin films. Nano Biomedicine and Engineering 12(1), 67–74 (2020)
N.F. Habubi, K.A. Mishjil, S.S. Chiad, Structural properties and refractive index dispersion of cobalt doped SnO2 thin films. Indian J. Phys. 87(3), 235–239 (2013)
N.F. Habubi, S.F. Oboudi, S.S. Chiad, Study of some optical properties of mixed SnO2-CuO thin films, Journal of Nano- and Electronic Physics. 4(4), 04008 (2012)
K.Y. Qader, R.A. Ghazi, A.M. Jabbar, K.H. Abass, S.S. Chiad, Reduce of energy gap of CuO nano structure film by Ag doping. Journal of Green Engineering 10(10), 7387–7398 (2020)
H.T. Salloom, E.H. Hadi, N.F. Habubi, S.S. Chiad, M. Jadan, J.S. Addasi, Characterization OF silver content upon properties of nanostructured nickel oxide thin films. Dig. J. Nanomater. Biostruct. 15(4), 1189–1195 (2020)
S. Balachandran, K. Selvam, B. Babub, M. Swaminathan, The simple hydrothermal synthesis of Ag–ZnO–SnO2 Nanochain and its multiple applications. Dalton Trans. 42, 16365 (2013)
E.P. Ganesh, D.K. Dnyaneshwar, B.G. Vishwas, H.J. Gotan, Preparation and characterization of SnO2 nanoparticles by hydrothermal route, International Nano Letters, 2(17), 2228–5326, (2012)
W. Chao, B. Bin, T. Fengbo, L. Yuncai, P. Shudi, S. Wei, Z. Qu, Hydrothermal synthesis and structural characterization of NiO/SnO2 composites and hydrogen sensing properties, J. Spectrosc. 6 (2015)
E.S. Hassan, T.H. Mubarak, K.H. Abass, S.S. Chiad, N.F. Habubi, M.H. Rahid, A.A. Khadayeir, M.O. Dawod I.A. Al-Baidhany, Structural, morphological and optical characterization of tin doped zinc oxide thin film by (SPT), J. Phys. Conf. Ser. 1234(1), 012013 (2019)
A.A. Khadayeir, E.S. Hassan, S.S. Chiad, N.F. Habubi, K.H. Abass, M.H. Rahid, T.H. Mubarak, M.O. Dawod, I.A. Al-Baidhany, Structural and optical properties of boron doped cadmium oxide. J. Phys. Conf. Ser. 1234(1), 012014, 20119.
E.S. Hassan, T.H. Mubarak, S.S. Chiad, N.F. Habubi, A.A. Khadayeir, M.O. Dawood, I.A. Al-Baidhany, Physical properties of indium doped cadmium sulfide thin films prepared by (SPT). J. Phys: Conf. Ser. 1294(2), 022008 (2019)
E.S. Hassan, A.K. Elttayef, S.H. Mostafa, M.H. Salim, S.S. Chiad, Silver oxides nanoparticle in gas sensors applications. J. Mater. Sci.: Mater. Electron. 30(17), 15943–15951 (2019)
J.H. Kim, K.A. Jeon, E.S. Shim, S.Y. Lee, Laser wavelength effect on the light emission properties of nanocrystalline Si on Si substrate fabricated by pulsed laser deposition. Mater. Sci. Eng., B 89, 70–72 (2002)
I. Simon, N. Barsan, M. Bauer, Micromachined metal oxide gas sensors: opportunities to improve sensor performance. Sens. Actuat. B 73, 1–26 (2001)
A. Gurlo, R. Riedel, In situ operando spectroscopy for assessing mechanisms of gas sensing. Angew Chem. Int. Ed. 46, 3826–3848 (2007)
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Authors are grateful to the staff of material laboratory in Physics Department, College of Science, Mustansiriyah University, for supporting this work.
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Abbas, A.M., Naif, H.A. & Hassan, E.S. Silver Loading Tin Oxide Nanostructure for Gas Sensing Application. Braz J Phys 51, 618–624 (2021). https://doi.org/10.1007/s13538-021-00872-0
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DOI: https://doi.org/10.1007/s13538-021-00872-0