Abstract
Clay fractions of the hypogene kaolin deposits from Ipoh granite and Jerai pegmatite are composed of kaolinite, while the greenish kaolin horizon of Ipoh area comprises of illite and kaolinite. Al2O3 and SiO2 are the main constituents in the studied kaolins with very low concentrations of other oxides. K2O occurs in relatively high contents in the illite-rich kaolin that formed by hydrothermal alteration of biotite-granite of the greenish kaolin horizon of Ipoh area. The higher contents of Ba, Cr, Cs, Ga, Rb, Sc, and Sn in the illite-rich horizon are inherited from its source rock. The relative enrichment of light rare earth elements (LREE) over heavy rare earth elements (HREE) as indicated from the high (La/Yb)n ratios and positive correlations between ΣREE and P2O5 in the studied kaolins suggest the occurrence of REE as authigenic florencite, churchite and/or rhabdophane and, therefore, reflect the kaolinitization process rather than the parent rocks. δH and δO values are similar in both Ipoh and Jerai kaolins with dH values range from −84 to −99‰ and positive δO values varying between 0.95 and 5.47%. H- and O-isotopes data fall close to the left side of the kaolinite line in equilibrium with meteoric water at temperatures of > 100 °C. The pronounced negative Eu anomalies, absence of positive Ce anomaly and high crystallization temperature (94–113 °C) indicate the hydrothermal (hypogene) origin of the studied kaolins as a result of the Triassic post-magmatic hydrothermal activities in Peninsular Malaysia. Mineralogical and geochemical variations among the studied deposits although they formed by the same kaolinitization process, suggest a significant role of parent rocks in their compositions.
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References
Alderton, D.H.M., and Rankin, A.H., 1983, The character and evolution of hydrothermal fluids associated with the kaolinized St. Austell granite, SW England. Journal of the Geological Society, 140, 297–309.
Ariffin, S., 1993, General geology with emphasis on geotechnical studies and slope stability of Simpang Pulai-Pos Slim Road (km 0-km 15), Keramat Pulai, Perak. Unpublished B.Sc. Thesis, Universiti of Malaya, Kuala Lumpur (in Malay). 136 p
Ariffin, K.S., Rahman, H.A., Hussin, H., and Hadi, K.A., 2008, The genesis and characteristics of primary kaolinitic clay occurrence at Bukit Lampas, Simpang Pulai, Ipoh. Geological Society of Malaysia Bulletin, 54, 9–16.
Baioumy, H. and Gilg, H.A., 2011, Pisolitic flint kaolin from Kalabsha, Egypt: a laterite-derived facies. Sedimentary Geology, 236, 141–152.
Bau, M. and Dulski, P., 1999, Comparing yttrium and rare earths in hydrothermal fluids from the Mid-Atlantic Ridge: implications for Y and REE behavior during near vent mixing and for the Y/Ho ratio of Proterozoic seawater. Chemical Geology, 155, 77–90.
Bedassa, G, Getaneh, W., and Hailu, B., 2019, Geochemical and mineralogical evidence for the supergene origin of kaolin deposits — Central Main Ethiopian Rift. Journal of African Earth Sciences, 149, 143–153.
Bigeleisen, J., Perlman, M.L., and Prosser, H.C., 1952, Conversion of hydrogenic materials to hydrogen for isotopic analysis. Analytical Chemistry, 24, 1356–1357.
Bignell, J.D. and Snelling, N.J., 1977, Geochronology of Malayan Granites. Overseas Geology and Mineral Recourses Series, British Geological Survey, London, 47, 72 p.
Bird, M.I. and Chivas, A.R., 1988, Stable-isotope evidence for low-temperature kaolinitic weathering and post-formational hydrogen-isotope exchange in Permian kaolinites. Chemical Geology: Isotope Geoscience, 72, 249–265.
Bradford, E.F., 1972, Geology and mineral resources of the Gunung Jerai area, Kedah. Geological Survey Malaysia District Memoir, 13, 242 p.
Cheong, K.W., 1990, Geology of the central portion of Kinta Valley, with special emphasis on mineralization and geotechnique. Unpublished B.Sc. Thesis, University of Malaya, Kuala Lumpur, 47 p.
Clauer, N., Fallick, A.E., Galán, E., Aparicio, P., Miras, A., Fernández-Caliani, J.C., and Aubert, A., 2015, Stable isotope constraints on the origin of kaolin deposits from Variscan granitoids of Galicia (NW Spain). Chemical Geology, 417, 90–101.
Clayton R.N. and Mayeda T.K., 1963, The use of bromine pentafluoride in the extraction of oxygen from oxides and silicates for isotopic analysis. Geochimica et Cosmochimica Acta, 27, 43–52.
Craig, H., 1961, Isotopic variations in meteoric waters. Science, 133, 1702–1703.
Cravero, F., Domınguez, E., and Iglesias, C., 2001, Genesis and applications of the Cerro Rubio kaolin deposit, Patagonia (Argentina). Applied Clay Science, 18, 157–172.
Dill, H.G., Bosse, R., Henning, H., and Fricke, A., 1997, Mineralogical and chemical variations in hypogene and supergene kaolin deposits in a mobile fold belt the Central Andes of northwestern Peru. Mineral Deposita, 32, 149–163.
Dill, H.G., Fricke, A., and Henning, K.H., 1995, The origin of Ba- and REE-bearing alumino-phosphate minerals from Lohrheim kaolinitic clay deposit (Rheinisches Schiefergebirge, Germany). Applied Clay Science, 10, 231–245.
Fernández-Caliani, J.C., 2018, Rare-earth element and stable isotope signatures of kaolin from a Pliocene lateritic weathering profile at mid-latitude region (Andalusia, Spain): implications for paleoweathering and paleoclimatic reconstructions. Catena, 167, 160–170.
Fernández-Caliani, J.C., Galán, E., Aparicio, P., Miras, A., and Márquez, M.G., 2010, Origin and geochemical evolution of the Nuevo Montecastelo kaolin deposit (Galicia, NW Spain). Applied Clay Science, 49, 91–97.
Fleet, M.E., Deer, W.A., Howie R.A., and Zussman, J., 2003, Rock-forming Minerals, Volume 3A: Micas (2nd edition). The Geological Society, London, 758 p.
Fowler, A.D. and Doig, R., 1983, The significance of europium anomalies in the REE spectra of granites and pegmatites, Mont Laurier, Quebec. Geochimica et Cosmochimica Acta, 47, 1131–1137.
Galán, E. and Ferrell, R.E., 2013, Genesis of clay minerals. In: Bergaya, F. and Lagaly, G. (eds.), Handbook of Clay Science (2nd edition). Elsevier, 5, p. 83–126.
Gilg, H.A., Hülmeyer, S., Miller, H., and Sheppard, S.M.F., 1999, Supergene origin of the Lastarria kaolin deposit, south-central Chile, and paleoclimatic implications. Clay and Clay Minerals, 47, 201–211.
Gilg, H.A. and Sheppard, S.M.F., 1996, Hydrogen isotope fractionation between kaolinite and water revisited. Geochimica et Cosmochimica Acta, 60, 529–533.
Gobbett, D.J., 1971, Joint pattern and faulting in Kinta, West Malaysia. Bulletin of the Geological Society of Malaysia, 4, 39–47.
Hayba, D.O., Bethke, P.M., Heald, P., and Faley, N.K., 1985, Geologic, mineralogic and geochemical characteristics of volcanic-hosted epithermal precious-metal deposits. In: Berger, B.R. and Bethke, P.M. (eds.), Geology and Geochemistry of Epithermal Systems. Reviews in Economic Geology, 2, p. 129–167.
Hosking, K.F.G., 1973, The primary tin mineralization patterns of West Malaysia. Geological Society Malaysia Bulletin, 6, 297–308.
Hutchison, C.S. and Tan, D.N.K., 2009, Geology of Peninsular Malaysia. Geological Society of Malaysia, Kuala Lumpur, 479 p.
Jamil, A., Ghani, A.A., Zaw, K., Othman, S., and Quek, L.X., 2016, Origin and tectonic implications of the 200 Ma, collision-related Jerai pluton of the Western Granite Belt, Peninsular Malaysia. Journal of Asian Earth Sciences, 127, 32–46.
Kadir, S., Erman, H., and Erkoyun, H., 2011, Mineralogical and geochemical characteristics and genesis of hydrothermal kaolinite deposits within Neogenevolcanites, Kütahya (western Anatolia), Turkey. Clays and Clay Minerals, 59, 250–276.
Kadir, S., Kulah, T., Eren, M., Onalgil, N., and Guril, A., 2014, Mineralogical and geochemical characteristics and genesis of the Güzelyurt alunite-bearing kaolinite deposit within the Late Miocene Gördeles ignimbrite, central Anatolia, Turkey. Clays and Clay Minerals, 62, 477–499.
Kostitsin, Y.A., 2000, Accumulation of trace elements in granites. Priroda, 2, 26–34.
Lackschewitz, K.S., Singer, A., Botz, R., Garbe-Schönberg, D., and Stoffers, P., 2000, Mineralogy and geochemistry of clay minerals near a hydrothermal site in the Escanaba trough, Gorda Ridge, northeast Pacific Ocean. In: Zierenberg, R.A., Fouquet, Y., Miller, D.J., and Normark, W.R. (eds.), Proceedings of the Ocean Drilling Program. Scientific Results, 169, p. 1–24.
Lim, B.K., 1979, The nature of the contact between the quartz porphyry and the Jerai Formation in the Rest House area, Gunung Jerai, Kedah. Warta Geologi, 5, 67–72.
Marumo, K., 2003, Genesis of kaolin minerals and pyrophyllite in Kuroko deposits of Japan: implications for the origins of the hydrothermal fluids from mineralogical and stable isotope data. Geochimica et Cosmochimica Acta, 53, 2915–2924.
Meng, C.C., Pubellier, M., Abdeldayem, A., and Sum, C.W., 2016, Deformation styles and structural history of the Paleozoic limestone, Kinta Valley, Perak, Malaysia. Bulletin of the Geological Society of Malaysia, 62, 37–45.
Mohd Azamie, W.A.G. and Azman, A.G., 2003. Petrology of granitic rocks along new Pos Slim to Kpg Raja highway (km 0 to km 22): identification of different granitic bodies, its field and petrographic characteristics. Bulletin of the Geological Society of Malaysia, 46, 35–40.
Murray, H.H., 1988, Kaolin minerals: their genesis and occurrences. Reviews in Mineralogy and Geochemistry, 19, 67–89.
Neiva, A.M.R., 1995, Distribution of trace elements in feldspars granitic aplites and pegmatites from Alijo-Sanfins, northern Portugal. Mineralogical Magazine, 59, 35–45.
Ng, S.W.P, Whitehouse, M.J., Searle, M.P., Robb, L.J., Ghani, A.A., Chung, S., Oliver, G.J.H., Sone, M., Gardiner, N.J., and Roselee, M.H., 2015, Petrogenesis of Malaysian granitoids in the Southeast Asian tin belt: Part 2. U-Pb zircon geochronology and tectonic model. Geological Society of America Bulletin, 127, 1238–1258.
Nyakairu, G.W.A., Koebrel, C., and Kurzweil, H., 2001, The Buwambo kaolin deposit in central Uganda: mineralogical and chemical composition. Chemical Journal, 35, 245–256.
Ockert, C., Gussone, N., Kaufhold, S., and Teichert, B.M.A., 2013, Isotope fractionation during Ca exchanges on clay minerals in a marine environment. Geochimica et Cosmochimica Acta, 112, 374–388.
Prudencio, M.I. and Gouveia, M.A., 1995, REE distribution in present-day and ancient surface environments of Basaltic Rocks, Central Portugal. Clay Minerals, 30, 239–248.
Psyrillos, A., Manning, D.A.C., and Burley, S.D., 1998, Geochemical constraints on kaolinization in St Austell Granite, Cornwall, England. Journal of the Geological Society, 155, 829–840.
Santos Jr., A.E.A., Rossetti, D.F.F., and Murray, H.H., 2007, Origins of the Rio Capim kaolinites (northern Brazil) revealed by δ18O and δD analyses. Applied Clay Science, 37, 281–294
Savin, S.M. and Epstein, S., 1970, The oxygen and hydrogen isotope geochemistry of clay minerals. Geochimica et Cosmochimica Acta, 34, 25–42.
Sheppard, S.M.F. and Gilg, H.A., 1996, Stable isotope geochemistry of clay minerals. Clay Minerals, 31, 1–24.
Sheppard, S.M.F., Nielsen, R.L., and Taylor, H.P., 1969, Oxygen and hydrogen isotope ratios of clay minerals from porphyry copper deposits. Economic Geology, 64, 755–777.
Tan, B.K., 1972, Geology and mineralisation of Kramat Pulai area, Perak. Unpublished B.Sc. Thesis, University of Malaya, Kuala Lumpur, 34 p
Taylor, S.R. and McLennan, S.M., 1985, The Continental Crust: Its Composition and Evolution. Blackwell, Oxford, 312 p.
Teh, G.H., 1969, The Geology of Tekka lode including an account of geochemical soil survey on hill, Tekka, Perak, West Malaysia. Unpublished B.Sc. Thesis, University of Malaya, Kuala Lumpur, 36 p.
Vidal, P., 1998, Géochimie. Série Géosciences, Dunod, Paris, 190 p.
Webster, J.D., Congdon, R.D., and Lyons, P.C., 1995, Determining preeruptive compositions of late Paleozoic magma from kaolinized volcanic ashes: analysis of glass inclusions in quartz microphenocrysts from tonsteins. Geochimica et Cosmochimica Acta, 59, 711–720.
Zirjanizadeh S., Rocha F., and Samiee S., 2018, Mineralogical, geochemical and stable isotope studies of kaolin deposits in north-west Gonabad district (eastern Iran), Geological Quarterly, 62, 385–399.
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The authors extend their appreciation to Researchers Supporting Project number (RSP-2020/139), King Saud University, Riyadh, Saudi Arabia.
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Baioumy, H., Farahat, M., Arifin, M.H. et al. Hypogene kaolin deposits from felsic intrusive rocks (Peninsular Malaysia) with special reference to rare earth elements and stable isotopes geochemistry. Geosci J 25, 863–876 (2021). https://doi.org/10.1007/s12303-021-0003-9
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DOI: https://doi.org/10.1007/s12303-021-0003-9