Abstract
We have designed new hydroborane fullerene-based pincer ligands of BH-(NCH2PR2)2C60, R = H, CH3, tBu and Ph, and their metal complexes. It is found that the substitution of CH3 and tBu for hydrogens of PH2 in flanking arms of BH-(NCH2PH2)2C60 significantly increases the electrophilicity of the considered fullerene-based pincer ligands. The pincer-ligated metal complexes are obtained by the addition of transition metals to the pincer bites. Based on natural bonding orbital analysis (NBO), stability of the considered complexes can be attributed to competition of electron density from the donor moieties (LP orbitals of phosphorous atoms in flanking arms and LP of transition metals) to the acceptor moieties (the n* orbitals of transition metals and empty orbitals of borons).
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M. E. van der Boo and D. Milstein (2003). Chem. Rev. 103, 1759.
C. Gunanathan and D. Milstein (2014). Chem. Rev. 114, 12024.
H. A. Younus, N. Ahmad, W. Su, and F. Verpoort (2014). Coord. Chem. Rev. 276, 112.
M. E. O’Reilly and A. S. Veige (2014). Chem. Soc. Rev. 43, 6325.
Q.-H. Deng, R. L. Melen, and L. H. Gade (2014). Acc. Chem. Res. 47, 3162.
N. Selander and K. J. Szabó (2011). Chem. Rev. 111, 2048.
J. Choi, A. H. R. MacArthur, M. Brookhart, and A. S. Goldman (2011). Chem. Rev. 111, 1761.
G. van Koten and D. Milstein, Organometallic Pincer Chemistry (Springer, Berlin, 2013).
K. J. Szabo and O. F. Wendt, Pincer and Pincer-Type Complexes: Applications in Organic Synthesis and Catalysis (Wiley, Weinheim, 2014).
C. J. Moulton and B. L. Shaw (1976). J Chem Soc Dalton Trans. https://doi.org/10.1039/DT9760001020.
M. Asaya and D. Morales-Moralesa (2015). Dalton Trans. 44, 17432.
S. Wanniarachchi, B. J. Liddle, J. Toussaint, S. V. Lindeman, B. Bennett, and J. R. Gardinier (2010). Dalton Trans. 39, 3167.
A. M. Prokhorov, T. Hofbeck, R. Czerwieniec, A. F. Suleymanova, D. N. Kozhevnikov, and H. Yersin (2014). J. Am. Chem. Soc. 136, 9637.
E.S.-H. Lam, W. H. Lam, and V.W.-W. Yam (2015). Inorg. Chem. 54, 3624.
G. van Koten and M. Albrecht (2001). Angew. Chem. Int. Ed. 40, 3750.
E. Peris and R. H. Crabtree (2018). Chem. Soc. Rev. 47, 1959.
M. Gupta, C. Hagen, R. J. Flesher, W. C. Kaska, and C. M. Jensen (1996). Chem Commun. https://doi.org/10.1039/CC9960002083.
J. I. van der Vlugt and J. N. H. Reek (2009). Angew. Chem. Int. Ed. 48, 8832.
M. Albrecht and G. van Koten (2001). Angew. Chem. Int. Ed. 40, 3750.
M. A. W. Lawrence, K.-A. Green, P. N. Nelson, and S. C. Lorraine (2018). Polyhedron 143, 11.
Y. Segawa, M. Yamashita, and K. Nozaki (2009). J. Am. Chem. Soc. 131, 9201.
A. F. Hill, S. B. Lee, J. Park, R. Shang, and A. C. Willis (2010). Organometallics 29, 5661.
I. R. Crossley, A. F. Hill, G. R. Owen, A. J. P. White, D. J. Williams, and A. C. Willis (2008). Organometallics 27, 381.
M. Hasegawa, Y. Segawa, M. Yamashita, and K. Nozaki (2012). Angew. Chem. Int. Ed. 51, 5956.
A. M. Spokoyny, M. G. Reuter, C. L. Stern, M. A. Ratner, T. Seideman, and C. A. Mirkin (2009). J. Am. Chem. Soc. 131, 9482.
J. I. van der Vlugt (2010). Angew. Chem. Int. Ed. 49, 252.
L. S. H. Dixon, A. F. Hill, A. Sinha, and J. S. Ward (2014). Organometallics 33, 653.
Y. Segawa, M. Yamashita, and K. Nozaki (2009). Organometallics 28, 6234.
M. E. El-Zaria, H. Arii, and H. Nakamura (2011). Inorg. Chem. 50, 4149.
R. J. Burford, W. E. Piers, D. H. Ess, and M. Parvez (2014). J. Am. Chem. Soc. 136, 3256.
J. J. Davidson, J. C. DeMott, C. Douvris, C. M. Fafard, N. Bhuvanesh, C.-H. Chen, D. E. Herbert, C.-I. Lee, B. J. McCulloch, B. M. Foxman, and O. V. Ozerov (2015). Inorg. Chem. 54, 2916.
M. C. Haibach, D. Y. Wang, T. J. Emge, K. Krogh-Jespersen, and A. S. Goldman (2013). Chem. Sci. 4, 3683.
N. P. Mankad, E. Rivard, S. B. Harkins, and J. C. Peters (2005). J. Am. Chem. Soc. 127, 16032.
Y.-E. Kim, S. Oh, S. Kim, O. Kim, J. Kim, S. W. Han, and Y. Lee (2015). J. Am. Chem. Soc. 137, 4280.
H. Yang and F. P. Gabbaï (2014). J. Am. Chem. Soc. 136, 10866.
E. E. Korshin, G. Leitus, L. J. W. Shimon, L. Konstantinovski, and D. Milstein (2008). Inorg. Chem. 47, 7177.
M. C. MacInnis, D. F. MacLean, R. J. Lundgren, R. McDonald, and L. Turculet (2007). Organometallics 26, 6522.
S. J. Mitton, R. McDonald, and L. Turculet (2009). Organometallics 28, 5122.
J. Takaya and N. Iwasawa (2008). J. Am. Chem. Soc. 130, 15254.
M. T. Whited, A. M. Deetz, J. W. Boerma, D. E. DeRosha, and D. E. Janzen (2014). Organometallics 33, 5070.
Y. Zhao and D. G. Truhlar (2008). Theor. Chem. Account. 120, 215.
S. F. Boys and F. Bernardi (1970). Mol. Phys. 19, 553.
M. W. Schmidt, K. K. Baldridge, J. A. Boatz, S. T. Elbert, M. S. Gordon, J. H. Jensen, S. Koseki, N. Matsunaga, K. A. Nguyen, S. J. Su, T. L. Windus, M. Dupuis, and J. A. Montgomery (1993). J. Comput. Chem. 14, 1347.
M. S. Gordon, M. W. Schmidt, in C. E. Dykstra, G. Frenking, K. S. Kim, G. E. Scuseria (eds.), Theory and Applications of Computational Chemistry: The First Forty Years (Elsevier, Amsterdam, 2005)
A. E. Reed, L. A. Curtiss, and F. Weinhold (1988). Chem. Rev. 88, 899.
A. E. Reed, R. B. Weinstock, and F. Weinhold (1985). J. Chem. Phys. 83, 735.
K. Hedberg, L. Hedberg, D. S. Bethune, C. A. Brown, H. C. Dorn, R. D. Johnson, and M. Vries (1991). Science 254, 410.
J. M. Hawkins, A. Meyer, T. A. Lewis, S. D. Loren, and F. J. Hollander (1991). Science 252, 312.
G. P. Miller (2006). C. R. Chim. 9, 952.
Y. Li, D. Xu, and L. Gan (2016). Angew. Chem. Int. 128, 2529.
R. Seshadri, A. Govindaraj, R. Nagarajan, T. Pradeep, and C. N. R. Rao (1992). Tetrahedron Lett. 33, 2069.
D. Schuhknecht, F. Ritter, and M. E. Tauchert (2016). Chem. Commun. 52, 11823.
R. G. Parr, L. V. Szentpály, and S. Liu (1999). J. Am. Chem. Soc. 121, 1922.
R. G. Parr, R. A. Donnelly, M. Levy, and W. E. Palke (1978). J. Chem. Phys. 68, 3801.
N. Gunawardhana, S. L. Gipson, and A. Franken (2009). Inorg. Chim. Acta 362, 113.
M. A. Burton, D. T. Halfen, and L. M. Ziurys (2018). Chem. Phys. Lett. 708, 228.
L. R. Gray, A. L. Hale, W. Levason, F. P. McCullough, and M. Webster (1984). J Chem Soc Dalton Trans. https://doi.org/10.1039/DT9910003149.
Y. Sekiguchi, F. Meng, H. Tanaka, A. Eizawa, K. Arashiba, K. Nakajima, K. Yoshizawa, and Y. Nishibayashi (2018). Dalton Trans. 47, 11322.
A. Aloisi, J.-C. Berthet, and T. Cantat (2016). Dalton Trans. 45, 14774.
G. Leone, G. Zanchin, I. Pierro, A. Sommazzi, A. Forni, and G. Ricci (2017). Catalysts 7, 369.
C.-M. Lee, M. Sankaralingam, and C.-H. Chuo (2019). Dalton Trans. 48, 5203.
U. J. Kilgore, M. P. Stewart, M. L. Helm, W. G. Dougherty, W. S. Kassel, M. R. DuBois, D. L. DuBois, and R. M. Bullock (2011). Inorg. Chem. 7, 10908.
B. Jana, A. Ellern, O. Pestovsky, A. Sadow, and A. Bakac (2011). Inorg. Chem. 50, 3010.
A. Parveen, E. N. Rao, B. Adivaiah, P. Anees, and G. Vaitheeswaran (2018). Phys. Chem. Chem. Phys. 20, 5084.
X.-R. You and H.-J. Zhai (2018). ACS Omega 3, 11958.
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We gratefully acknowledge for the financial support from the Research Council of Alzahra University.
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Anafcheh, M., Zahedi, M. Computational Design of New Hydroborane Fullerene-Based Pincer Ligands. J Clust Sci 33, 1239–1248 (2022). https://doi.org/10.1007/s10876-021-02051-2
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DOI: https://doi.org/10.1007/s10876-021-02051-2