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Coating evaluation of polydimethylsiloxane-aminopropylsiloxane for stir bar sorptive extraction

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Abstract

In stir bar sorptive extraction (SBSE), a coating is typically used to isolate and preconcentrate organic compounds in aqueous samples. Here, a translucent coating based on polydimethylsiloxane and aminopropyltriethoxysilane was prepared by a sol–gel method. Characterization tests showed that the coating was homogeneous, relatively polar, and both thermally (≤ 400°C) and chemically stable. Coated stir bars were evaluated in SBSE experiments. Benzene derivatives and furanic compounds were successfully extracted/preconcentrated from aqueous and organic solutions. Furanic compounds and benzene derivatives were moderately extracted from water, but they were sufficiently extracted from isooctane.

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Acknowledgments

This work was supported by Consejo Nacional de Ciencia y Tecnología, CONACyT (CB-167800). The authors are grateful to Alfredo Rafael Vilchis-Néstor for his technical support in the SEM-EDS and Rita Sulub-Sulub for her technical support in the TGA measurements. We also thank Martha Burgos-Tan, Mariela Lope-Navarrete, and Saúl Ariel Medina Cetina for their assistance in the SBSE experiments.

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Authors and Affiliations

  1. Cuerpo Académico de Química Fundamental y Aplicada, Facultad de Ingeniería Química, Universidad Autónoma de Yucatán, Periférico Norte km 33.5, Tablaje Catastral 13615, Col. Chuburná de Hidalgo Inn, C.P. 97203, Mérida, YUC, México

    David Muñoz-Rodríguez, Yamile Pérez-Padilla, Alejandro Ávila-Ortega, Jesús Alberto Barrón-Zambrano & Cristian Carrera-Figueiras

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  1. David Muñoz-Rodríguez
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  2. Yamile Pérez-Padilla
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  3. Alejandro Ávila-Ortega
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  5. Cristian Carrera-Figueiras
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Correspondence to Cristian Carrera-Figueiras.

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Muñoz-Rodríguez, D., Pérez-Padilla, Y., Ávila-Ortega, A. et al. Coating evaluation of polydimethylsiloxane-aminopropylsiloxane for stir bar sorptive extraction. J Coat Technol Res 18, 1143–1151 (2021). https://doi.org/10.1007/s11998-021-00471-3

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  • DOI: https://doi.org/10.1007/s11998-021-00471-3

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