Abstract
Intense luminescence and nanosecond relaxation of photocurrent upon strong optical excitation have been observed in CuIn5S8 crystals grown by slow melt cooling at a constant temperature gradient. Three emission bands with energies of 1.52, 1.48, and 1.465 eV are distinguished in the photoluminescence spectra. The crystal photoactivation in the range of 300–600 K is explained by an increase in the hole mobility in the valence band with an increase in temperature.
Similar content being viewed by others
REFERENCES
N. Khemiri, B. Khalfallah, D. Abdelkader, and M. Kanzari, Int. J. Thin Films Sci. Technol. 3, 7 (2014).
A. Usujima, S. Takeuchi, S. Endo, and T. Irie, Jpn. J. Appl. Phys. 20, L505 (1981).
A. Kudo and Y. Miseki, Chem. Soc. Rev. 38, 253 (2009).
A. F. Qasrawi and N. M. Gasanly, Cryst. Res. Technol. 36, 1399 (2001).
I. V. Bodnar and V. V. Shatalova, Semiconductors 46, 1122 (2012).
S. Ito and T. Ryo, Adv. Mater. Sci. Eng. 2012, 136092 (2012).
S. Kitamura, S. Endo, and T. Irie, J. Phys. Chem Solids 46, 881 (1985).
I. V. Bodnar, I. A. Victorov, M. A. Jaafar and S. A. Pauliukavets, Semiconductors 50, 154 (2016).
N. M. Gasanly, Pramana J. Phys. (2015).
H. Kumagai, T. Minegishi, Y. Moriya, J. Kubota, and K. Domen, J. Phys. Chem. C 118, 16386 (2014).
C. Stephan, S. Schorr, and H. Schock, MRS Proc. 1165, 1165-M09-08 (2009).
H. Haeuseler, E. Elitok, A. Memo, and R. Arzani, Z. Anorg. Allgem. Chem. 627, 1204 (2001).
J. Estevez, L. Duran, E. Hernandez, J. Castro, L. Melendez, J. R. Fermin, C. A. Durante Rincón, Rev. Tec. Ing. Univ. Zulia 32, 92 (2009).
M. Isik and N. Gasanly, J. Phys. Chem. Solids 91, 13 (2016).
A. G. Guseinov, V. M. Salmanov, R. M. Mamedov, A. A. Salmanova, F. Sh. Ahmadova, and N. D. Dashdamirova, J. Low Dim. Syst. 3, 9 (2019).
B. K. Ridley, Quantum Processes in Semiconductors, 5th ed. (Oxford Univ. Press, Oxford, 2013).
Funding
This study was supported by the Foundation for Science Development under the President of the Azerbaijan Republic (grant no. EİF/MQM/Elm-Tehsil-1-2016-1(26)-71/01/1).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflict of interest.
Additional information
Translated by A. Sin’kov
Rights and permissions
About this article
Cite this article
Guseinov, A.G., Salmanov, V.M., Mamedov, R.M. et al. Specific Features of Photoluminescence and Nanosecond Relaxation of Photocurrent in CuIn5S8 Crystals upon Strong Optical Excitation. Opt. Spectrosc. 128, 1978–1982 (2020). https://doi.org/10.1134/S0030400X20120905
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0030400X20120905