Skip to main content
SpringerLink
Log in

Study of the Reactions of Fullerene С60 with the Palladium-Containing Clusters of Molybdenum {Mo3PdS4} by Spectroscopic and Calculation Methods

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The fabrication of hybrid materials combining the physicochemical properties of various classes is a complicated but promising trend for the development of the modern science. The formation of new hybrid cluster cations [Mo3Pd(C60)S4Cl3(R2Bipy)3]+ and [{Mo3PdS4Cl3(R2Bipy)3}2(C60)]2+ (Bipy is 2,2-bipyridine) containing fullerene C60 coordinated to the palladium atom by the reaction of [Mo3S4Cl3(R2Bipy)3]PF6 with Pd2(Dba)3 (Dba is dibenzylideneacetone) and C60 is shown by a complex of physicochemical methods. The reaction products are studied by IR and NMR (1H, 31Р, and C–H correlations) spectroscopy and mass spectrometry. The quantum-chemical calculations are performed by the DFT method for the correct interpretation of the spectroscopic data and elucidation of the electronic structures of the fullerene-containing compounds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.

Similar content being viewed by others

REFERENCES

  1. Krätschmer, W., Lamb, L.D., and Fostiropoulos, K.H.D.R., Nature, 1990, vol. 347, no. 6291, p. 354.

    Article  Google Scholar 

  2. Moody, A., Chem. Ind., 1991, p. 346.

  3. Echegoyen, L. and Herranz, M.A., Fullerenes: From Synthesis to Optoelectronic. Properties, Guid, D.M. and Martin, N., Eds., Dordrecht: Springer, 2002.

    Google Scholar 

  4. Balch, A.L. and Olmstead, M.M., Chem. Rev., 1998, vol. 98, no. 6, p. 2123.

    Article  CAS  Google Scholar 

  5. Pan, Y., Liu, X., Zhang, W., et al., Appl. Catal., B, 2020, vol. 265, p. 118579.

    Article  Google Scholar 

  6. Sulman, E., Matveeva, V., Semagina, N., et al., J. Mol. Catal. A: Chem., 1999, vol. 146, nos. 1–2, p. 257.

    Article  CAS  Google Scholar 

  7. Meng Ze-Da, Zhang Feng-Jun, Zhu Lei, et al., Mater. Sci. Eng. C., 2012, vol. 32, no. 8, p. 2175.

    Article  CAS  Google Scholar 

  8. Signorini, R., Bozio, R., and Prato, M., Fullerenes: From Synthesis to Optoelectronic Properties, Guidi, D.M. and Martin, N, Eds., Dordrecht: Springer, 2002, p. 295.

    Google Scholar 

  9. Rispens, M.T. and Hummelen, J.C., Fullerenes: From Synthesis to Optoelectronic Properties, Guidi, D.M. and Martin, N, Eds., Dordrecht: Springer, 2002, vol. 60, p. 387.

    Google Scholar 

  10. Makarova, T., Front. Magn. Mater., 2005, p. 209.

    Google Scholar 

  11. Johnston, H.J., Hutchison, G.R., Christensen, F.M., et al., Toxicol. Sci., 2009, vol. 114, no. 2, p. 162.

    Article  Google Scholar 

  12. Kausar, A., Polym. Plast. Technol. Eng., 2017, vol. 56, no. 6, p. 594.

    Article  CAS  Google Scholar 

  13. Konarev, D.V. and Lyubovskaya, R.N., Russ. Chem. Rev., 2016, vol. 85, no. 11, p. 1215.

    Article  CAS  Google Scholar 

  14. Megiatto, J.D., Guldi, D.M., and Schuster, D.I., Chem. Soc. Rev., 2020, vol. 49, no. 1, p. 8.

    Article  CAS  Google Scholar 

  15. Kleandrova, V.V., Luan, F., and Speck-Planche, A.C.M.N.D.S, Curr. Bioinform., 2015, vol. 10, no. 5, p. 565.

    Article  CAS  Google Scholar 

  16. Rašović, I., Mater. Sci. Technol., 2017, vol. 33, no. 7, p. 777.

    Article  Google Scholar 

  17. Espinet, P.A. and Albeniz, A.C., Comprehensive Organomet. Chem. III, 2007, no. 1995, p. 315.

  18. Ohki, Y., Hara, R., Munakata, K., et al., Inorg. Chem., 2019, vol. 58, no. 8, p. 5230.

    Article  CAS  Google Scholar 

  19. Petrov, P.A. and Sukhikh, T.S., Russ. J. Coord. Chem., 2019, vol. 45, no. 5, p. 333. https://doi.org/10.1134/S1070328419040079

    Article  CAS  Google Scholar 

  20. Pedrajas, E., Sorribes, I., Guillamón, E., et al., Chem. A Eur. J., 2017, vol. 23, no. 53, p. 13205.

    Article  CAS  Google Scholar 

  21. Ohki, Y., Uchida, K., Hara, R., et al., Chem. A Eur. J., 2018, vol. 24, no. 64, p. 17138.

    Article  CAS  Google Scholar 

  22. Gushchin, A.L., Laricheva, Y.A., Sokolov, M.N., et al., Russ. Chem. Rev., 2018, vol. 87, no. 7, p. 670. https://doi.org/10.1070/RCR4800

    Article  CAS  Google Scholar 

  23. Oriwaki, K.M., Oshida, R.Y., and Kashi, H.A., X-ray Struct. Anal. Online, 2014, vol. 30, p. 11.

    Google Scholar 

  24. Gushchin, A.L., Sokolov, M.N., Naumov, D.Yu., and Fedin, V.P. J. Struct. Chem., 2008, vol. 49, no. 4, p. 748.

    Article  CAS  Google Scholar 

  25. Murata, T., Mizobe, Y., Gao, H., et al., J. Am. Chem. Soc., 1994, vol. 116, no. 8, p. 3389.

    Article  CAS  Google Scholar 

  26. Murata, T., Gao, H., Mizobe, Y., et al., J. Am. Chem. Soc., 1992, vol. 114, no. 21, p. 8287.

    Article  CAS  Google Scholar 

  27. Tao, Y., Zhou, Y., Qu, J., et al., Tetrahedron Lett., 2010, vol. 51, no. 15, p. 1982.

    Article  CAS  Google Scholar 

  28. Tao, Y., Wang, B., Wang, B., et al., Org. Lett., 2010, vol. 12, no. 12, p. 2726.

    Article  CAS  Google Scholar 

  29. Tao, Y., Wang, B., Zhao, J., et al., Org. Chem., 2012, vol. 77, no. 6, p. 2942.

    Article  CAS  Google Scholar 

  30. Wakabayashi, T., Ishii, Y., Ishikawa, K., et al., Angew. Chem., Int. Ed. Engl., 1996, vol. 35, no. 18, p. 2123.

    Article  CAS  Google Scholar 

  31. Sokolov, M.N., Chubarova, E.V., Virovets, A.V., et al., J. Clust. Sci., 2003, vol. 14, no. 3, p. 227.

    Article  CAS  Google Scholar 

  32. Sokolov, M.N., Virovets, A.V., Dybtsev, D.N., et al., Communications, 2001, no. 4, p. 4816.

  33. Pino-Chamorro, J.A., Laricheva, Y.A., Guillamón, E., et al., New J. Chem., 2016, vol. 40, no. 9, p. 7872.

    Article  CAS  Google Scholar 

  34. Pedrajas, E., Sorribes, I., Gushchin, A.L., et al., ChemCatChem, 2017, vol. 9, no. 6, p. 1128.

    Article  CAS  Google Scholar 

  35. ADF 2017. SCM, Theoretical Chemistry, Amsterdam: Vrije Universiteit, 2017.

  36. Frisch, M.J., Trucks, G.W., Schlegel, H.B., et al., Gaussian I, 2016.

  37. Laricheva, Y.A., Gushchin, A.L., Abramov, P.A., et al., Polyhedron, 2018, vol. 154, p. 202.

    Article  CAS  Google Scholar 

  38. Takei, I., Suzuki, K., Enta, Y., et al., Organometallics, 2003, vol. 22, no. 10, p. 1790.

    Article  CAS  Google Scholar 

  39. Nagashima, H., Nakaoka, A., Saito, Y., et al., Chem. Commun., 1992, no. 4, p. 377.

  40. Basallote, M.G., Fernández-Trujillo, M.J., Pino-Chamorro, J.Á., et al., Inorg. Chem., 2012, vol. 51, no. 12, p. 6794.

    Article  CAS  Google Scholar 

  41. Algarra, A.G., Basallote, M.G., Fernandez-Trujillo, M.J., et al., Inorg. Chem., 2010, vol. 49, no. 13, p. 5935.

    Article  CAS  Google Scholar 

  42. Yanov, I., Leszczynski, J., Sulman, E., et al., Int. J. Quantum Chem., 2004, vol. 100, no. 5, p. 810.

    Article  CAS  Google Scholar 

  43. Brady, F.J., Cardina, D.J., and Domin, M., J. Organomet. Chem., 1995, vol. 491, nos. 1–2, p. 169.

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported by the Russian Foundation for Basic Research, projects nos. 18-33-20056 and 19-33-90097.

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    Yu. A. Laricheva, N. Yu. Shmelev, A. L. Gushchin & M. N. Sokolov

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    N. Yu. Shmelev

  3. Kazan Federal University, Kazan, Russia

    M. N. Sokolov

Authors
  1. Yu. A. Laricheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. Yu. Shmelev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. L. Gushchin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. N. Sokolov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. L. Gushchin.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by E. Yablonskaya

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Laricheva, Y.A., Shmelev, N.Y., Gushchin, A.L. et al. Study of the Reactions of Fullerene С60 with the Palladium-Containing Clusters of Molybdenum {Mo3PdS4} by Spectroscopic and Calculation Methods. Russ J Coord Chem 47, 196–203 (2021). https://doi.org/10.1134/S1070328421020032

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328421020032

Keywords:

Search

Navigation