Abstract
Intercalation of transition metal dichalcogenides (TMDs) by 3d or 4d transition metal elements are of considerable interest as the intercalated atoms can finely tune the physical and chemical properties of host TMDs. On addition, these intercalation complexes show interesting magnetic property and displays anomalous transport behavior at the magnetic ordering temperature. Here, we have synthesized and measured transport properties of single crystal vanadium intercalated Niobium Di-sulphide. At 300 K, electrical resistivity and thermal conductivity of V\(_{0.3}\)NbS\(_{2}\) is found to be \(\sim \) 10\(^{-6}\) \(\Omega \) m and 36 W m\(^{-1}\) K\(^{-1}\) respectively. Unlike phonon scattering, the spin scattering is found to affect both electrical and phonon conduction at low temperature. The electrical resistivity at temperature \({T} < 45\,\hbox {K}\) follows \(T^{3/2}\) behavior, whereas the electronic part of thermal conductivity shows exponent of 0.8. Using steady-state method, the temperature dependent lattice part of thermal conductivity shows exponents of 0.5 and − 0.5 at \({T} < 45\,\hbox {K}\) and \({T} > 45\,\hbox {K}\) respectively. Moreover, the peak of the total thermal conductivity also overlaps with the magnetic transition temperature, indicating the participation of spin dependent phonon dynamics below 45 K.
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Q H Wang, K K Zadeh, A Kis, J N Coleman and M S Strano Nat. Nanotechnol. 7 699 (2012)
A Kumar and P K Ahluwalia Eur. Phys. J. B 85 186 (2012)
R Mukherjee et al. Phys. Rev. Appl. 7, 034011 (2017)
D Sarkar et al. Nature 526, 91 (2015)
F Yin et al. Coord. Chem. Rev. 347 77 (2017)
S Polesya, S Mankovsky, D Ködderitzsch, W Bensch and H Ebert Phys. Status Solidi (RRL)-Rapid Res. Lett. 10 174423 (2016)
F Wu, T Lovorn, E Tutuc, I Martin and A H MacDonald Phys. Rev. Lett. 122 086402 (2019)
S F Ebadzadeh, H Goudarzi and M Khezerlou Phys. B Condens. Matter 559 32 (2019)
A A Tedstone, D J Lewis and P T O’Brien Chem. Mater. 28 1965 (2016)
H Fang et al. Proc. Natl. Acad. Sci. 111 6198 (2014)
S Fan, S Yun, Y Joon, W Jong and Y H Lee Adv. Sci. 7 1902751 (2020)
R Mukherjee Bull. Mater. Sci. 43 1–5 (2020)
Y Yu et al. ACS Nano 11 9390 (2017)
L Henan, S Yumeng, H C Ming and J L Lain Nano Energy 18 293 (2015)
J Lee, J H Shin, G H Lee and C H Lee Nanomaterials 6 193 (2016)
D Wickramaratne, F Zahid and R K Lake J. Chem. Phys. 140 124710 (2014)
M Zulfiqar, Y Zhao, G Li, Z C Li and J Ni Sci. Rep. 9 4571 (2019)
Q Cai et al. Sci. Adv. 5 eaav0129 (2019)
S G Jeon et al. Nanoscale 10 5985 (2018)
P G Arkadiusz et al. Sci. Rep. 9 13338 (2019)
H Li et al. Adv. Funct. Mater. 22 1385 (2012)
M T Pettes, J Insun, Y Zhen and S Li Nano Lett. 11 1195 (2011)
P Jiang, X Qian, X Gu and R Yang Adv. Mater. 29 1701068 (2017)
K Lu et al. Phys. Rev. Mater. 4 054416 (2020)
Z T Diao, S Tsunashima and M Jimbo J. Phys. Condens. Matter 10 6659 (1998)
J L Duvail, A Fert, L G Pereira and D K Lottis J. Appl. Phys. 75 7070 (1994)
P G Klemens, Thermal Conductivity, vol. 20. (Boston: Springer) p. 261 (1989)
I Pettes, M T Ou, E Wu, W Shi and L Jo Appl. Phys. Lett. 104 201902 (2014)
N Peimyoo, S Jingzhi, Y Weihuang, W Yanlong, C Chunxiao and Y Ting Nano Res. 8 1210 (2014)
Acknowledgements
I acknowledge Suryakanta Ghosh from NIT Warangal for useful discussions. Further, I admire the support from Lovely Professional University for providing the fund and other opportunities during the process of research.
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Sharma, B., Sharma, R., Kour, S. et al. Fractional exponents of electrical and thermal conductivity of vanadium intercalated layered 2H-NbS2 bulk crystal. Indian J Phys 96, 1335–1339 (2022). https://doi.org/10.1007/s12648-021-02045-w
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DOI: https://doi.org/10.1007/s12648-021-02045-w