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Licensed Unlicensed Requires Authentication Published by De Gruyter February 3, 2021

Kinetic analysis of dual impellers on methane hydrate formation

  • Sotirios Nik Longinos and Mahmut Parlaktuna

Abstract

This study investigates the effects of types of impellers and baffles on methane hydrate formation. Induction time, water conversion to hydrates (hydrate yield), hydrate formation rate and hydrate productivity are components that were estimated. The initial hydrate formation rate is generally higher with the use of Ruston turbine (RT) with higher values 28.93 × 10−8 mol/s in RT/RT with full baffle (FB) experiment, but the decline rate of hydrate formation was also high compared to up-pumping pitched blade turbine (PBTU). Power consumption is higher also in RT/RT and PBT/RT with higher value 392,000 W in PBT/RT with no baffle (NB) experiment compared to PBT/PBT and RT/PBT experiments respectively. Induction time values are higher in RT/RT experiments compared to PBT/PBT ones. Hydrate yield is always smaller when there is no baffle in all four groups of experiments while the higher values exist in experiments with full baffle. It should be noticed that PBT is the same with PBTU, since all experiments with mixed flow have upward trending.


Corresponding author: Sotirios Nik. Longinos, Department of Petroleum and Natural Gas Engineering, Middle East Technical University, Ankara, Turkey, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

Ameur, H., Y. Kamla, and D. Sahel. 2016. “CFD Simulations of Mixing Characteristics of Radial Impellers in Cylindrical Reactors.” Chemistry Select 1: 2548–51, https://doi.org/10.1002/slct.201600579.Search in Google Scholar

Casco, M. E., M. Martínez-Escandell, E. Gadea-Ramos, K. Kaneko, J. Silvestre-Albero, and F. Rodríguez-Reinoso. 2015. “High-Pressure Methane Storage in Porous Materials: Are Carbon Materials in the Pole Position?” Chemistry of Materials 27: 959–64, https://doi.org/10.1021/cm5042524.Search in Google Scholar

Dendy Sloan, E.Jr. 2003. “Fundamentals Principles and Applications of Natural Gas Hydrates.” Nature Publishing Group 426: 353–9, https://doi.org/10.1038/nature02135.Search in Google Scholar

Douieb, S., L. Fradette, F. Bertrand, and B. Haunt. 2015. “Impact of the Fluid Flow Conditions on the Formation Rate of Carbon Dioxide Hydrates in a Semi-Batch Stirred Tank Reactor.” AIChE 61 (12): 43874401, https://doi.org/10.1002/aic.14952.Search in Google Scholar

Foukrach, M., and H. Ameur. 2019. “Effect of Baffles Shape on the Flow Patterns and Power Consumption in Stirred Vessels.” SN Applied Sciences 1: 1503, https://doi.org/10.1007/s42452-019-1550-9.Search in Google Scholar

Gudmundsson, J. S., and A. Brrehaug. 1996. “Frozen Hydrate for Transport of Natural Gas.” In Proceedings of the 2nd International Conference on Natural Gas Hydrates, Toulouse, 415–22. Yokohama, Japan.Search in Google Scholar

Gudmundsson, J. S., A. A. Khodakar, and M. Parlaktuna. 1990. “Storage of Natural Gas as Frozen Hydrate.” In Proceedings of the 67th Annual Technical Conference and Exhibition of SPE, 699–707. Yokohama, Japan.10.2118/24924-PASearch in Google Scholar

Handa, Y. 1986. “Calorimetric Determination of the Composition, Enthalpies of Dissociation and Heat Capacities in the Range of 80–270 K for Clathrate Hydrates of Xenon and Krypton.” Journal of Chemical Thermodynamics 18: 891–903, https://doi.org/10.1016/0021-9614(86)90124-2.Search in Google Scholar

Hao, W., J. Wang, S. Fan, and H. Wenbin. 2007. “Study on Methane Hydration Process in a Semi-Continuous Stirred Tank Reactor.” Energy Conversion and Management 48: 954–60, https://doi.org/10.1016/j.enconman.2006.08.007.Search in Google Scholar

Houari, A., B. Mohamed, and G. Abdellah. 2015. “Numerical Study of the Performance of Multistage Scaba 6SRGT Impellers for the Agitation of Yield Stress Fluids in Cylindrical Tanks.” Journal of Hydrodynamics 27 (3): 436–42.10.1016/S1001-6058(15)60501-7Search in Google Scholar

Kamla, Y., M. Bouzit, H. Ameur, M. I. Arab, and A. Hadjeb. 2017. “Effect of the Inclination of Baffles on the Power Consumption and Fluid Flows in a Vessel Stirred by a Rushton Turbine.” Chinese Journal of Mechanical Engineering 30 (4): 1008–16, https://doi.org/10.1007/s10033-017-0158-5.Search in Google Scholar

Kanda, H. 2006. “Economic Study on Natural Gas Transportation with Natural Gas Hydrate (NGH) Pellets.” In Proceeding of the 23rd World Gas Conference, Amsterdam. Yokohama, Japan.Search in Google Scholar

Koh, C. A., D. E. Sloan, A. K. Sum, and D. T. Wu. 2011. “Fundamentals and Applications of Gas Hydrates.” Annual Review of Chemical and Biomolecular Engineering 2: 237–57, https://doi.org/10.1146/annurev-chembioeng-061010-114152.Search in Google Scholar

Lang, X., S. Fan, and Y. Wang. 2010. “Intensification of Methane and Hydrogen Storage in Clathrate Hydrate and Future Prospect.” Journal of Natural Gas Chemistry 19: 203–9, https://doi.org/10.1016/s1003-9953(09)60079-7.Search in Google Scholar

Lee, B. I., and M. G. Kesler. 1975. “A Generalized Thermodynamic Correlation Based on Three Parameter Corresponding States.” AIChE 21: 510–27, https://doi.org/10.1002/aic.690210313.Search in Google Scholar

Longinos, S. N., and M. Parlaktuna. 2020. “The Effect of Experimental Conditions on Methane (95%)–Propane (5%) Hydrate Formation.” Energies 13 (24): 6710, https://doi.org/10.3390/en13246710.Search in Google Scholar

Longinos, S. N., and M. Parlaktuna. 2021. “Kinetic Analysis of Methane - Propane Hydrate Formation by the Use of Different Impellers.” ASC Omega 6: 1636–46, doi:https://doi.org/10.1021/acsomega.0c05615.Search in Google Scholar

Mao, W. L., A. F. Goncharov, V. V. Struzhkin, Q. Guo, J. Hu, J. Shu, R. J. Hemley, M. Somayazulu, and Y. Zhao. 2002. “Hydrogen Clusters in Clathrate Hydrate.” Science 297: 2247–9, https://doi.org/10.1126/science.1075394.Search in Google Scholar

Ripmeester, J. A., J. S. Tse, C. I. Ratcliffe, and B. M. Powell. 1987. “A New Clathratehydrate Structure.” Nature 325: 135–6, https://doi.org/10.1038/325135a0.Search in Google Scholar

Rossi, F., M. Filipponi, and B. Castellani. 2012. “Investigation on a Novel Reactor for Gas Hydrate Production.” Applied Energy 99: 167–72, https://doi.org/10.1016/j.apenergy.2012.05.005.Search in Google Scholar

Shirota, H., I. Aya, and J. Namie. 2002. “Measurement of Methane Hydrate Dissociation for Application to Natural Gas Storage and Transportation.” In Proceedings of the Fourth International Conference on Natural Gas Hydrates, Yokohama, 972–7. Yokohama, Japan.Search in Google Scholar

Sloan, E. D. 1998. Clathrate Hydrates of Natural Gases, Vol. 1. New York: Marcel Dekker.Search in Google Scholar

Stoots, C. M., and R. V. Calabrese. 1995. “Mean Velocity Field Relative to a Rushton Turbine Blade.” AIChE Journal 41: 1–11, https://doi.org/10.1002/aic.690410102.Search in Google Scholar

Sum, A. K., R. C. Burruss, and E. D. Sloan. 1997. “Measurement of Clathrate Hydrates via Raman Spectroscopy.” Journal of Physical Chemistry B 101: 7371–7, https://doi.org/10.1021/jp970768e.Search in Google Scholar

Takaoki, T., T. Iwasaki, Y. Katoh, T. Arai, and K. Horiguchi. 2002. “Use of Hydrate Pellets for Transportation of Natural Gas.” In Proceedings of the Fourth International Conference on Natural Gas Hydrates, Yokohama, 982–6. Yokohama, Japan.Search in Google Scholar

Veluswamy, H. P., A. Kumar, Y. Seo, J. D. lee, and P. Linga. 2018. “A Review of Solidified Natural Gas (SNG) Technology for Gas Storage via Clathrate Hydrates.” Applied Energy 216: 262–85, https://doi.org/10.1016/j.apenergy.2018.02.059.Search in Google Scholar

Yoon, H. S., D. F. Hill, S. Balachandar, R. J. Adrian, and M. Y. Ha. 2005. “Reynolds Number Scaling of Flow in a Rushton Turbine Stirred Tank. Part I—Mean Flow, Circular Jet and Tip Vortex Scaling.” Chemical Engineering and Science 60: 3169–83, https://doi.org/10.1016/j.ces.2004.12.039.Search in Google Scholar

Youcefi, S., M. Bouzit, H. Ameur, Y. Kamla, and A. Youcefi. 2013. “Effect of Some Design Parameters on the Flow Fields and Power Consumption in a Vessel Stirred by a Rushton Turbine.” Chemical and Process Engineering 34 (2): 293–307, https://doi.org/10.2478/cpe-2013-0024.Search in Google Scholar


Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/ijcre-2020-0231).


Received: 2020-11-28
Accepted: 2021-01-23
Published Online: 2021-02-03

© 2021 Walter de Gruyter GmbH, Berlin/Boston

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