Abstract
We use dynamic numerical simulations to investigate the role of particle rotation in pairwise capillary interactions of particles trapped at a fluid interface. The fluid interface is modeled with a phase-field method which is coupled to the Navier–Stokes equations to solve for the flow dynamics. Numerical solutions are found using a finite element scheme in a bounded two-dimensional geometry. The interfacial deformations are caused by the buoyant weight of the particles, which are allowed to both translate and rotate due to the capillary and viscous forces and torques at play. The results show that the capillary attraction is faster between freely rotating particles than if particle rotation is inhibited, and the higher the viscosity mismatch, the greater the effect. To explain this result, we analyze the drag force exerted on the particles and find that the translational drag force on a rotating particle is always less than its non-rotating counterpart due to attenuated velocity gradients in the vicinity of the particle. We also find that the influence of interfacial deformations on particle rotation is minute.
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Data Availability Statement
This manuscript has associated data in a data repository. [Authors’ comment: The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.]
References
V. Lotito, T. Zambelli, Approaches to self-assembly of colloidal monolayers: a guide for nanotechnologists. Adv. Colloid Interface Sci. 246, 217–274 (2017)
P.A. Kralchevsky, K. Nagayama, Capillary interactions between particles bound to interfaces, liquid films and biomembranes. Adv. Colloid Interface Sci. 85, 145–192 (2000)
M. Oettel, S. Dietrich, Colloidal Interactions at Fluid Interfaces. Langmuir 24(4), 1425–1441 (2008)
K.D. Danov, P.A. Kralchevsky, Capillary forces between particles at a liquid interface: general theoretical approach and interactions between capillary multipoles. Adv. Colloid Interface Sci. 154, 91–103 (2010)
L. Botto, E.P. Lewandowski, M. Cavallaro Jr., K.J. Stebe, Capillary interactions between anisotropic particles. Soft Matter 8, 9957–9971 (2012)
S. Dasgupta, T. Aust, G. Gompper, Nano- and microparticles at fluid and biological interfaces. J. Phys. Condens. Matter 29(37), 373003 (2017)
I.B. Liu, N. Sharifi-Mood, K.J. Stebe, Capillary assembly of colloids: interactions on planar and curved interfaces. Annu. Rev. Condens. Matter Phys. 9, 283–305 (2018)
R. McGorty, J. Fung, D. Kaz, V.N. Manoharan, Colloidal self-assembly at an interface. Mater. Today 13(6), 34–42 (2010)
Q. Xie, G.B. Davies, J. Harting, Controlled capillary assembly of magnetic Janus particles at fluid–fluid interfaces. Soft Matter 12, 6566–6574 (2016)
N.D. Vassileva, D. van den Ende, F. Mugele, J. Mellema, Capillary forces between spherical particles floating at a liquid–liquid interface. Langmuir 21, 11190–11200 (2005)
M.P. Boneva, N.C. Christov, K.D. Danov, P.A. Kralchevsky, Effect of electric-field induced capillary attraction on the motion of particles at an oil–water interface. Phys. Chem. Chem. Phys. 9, 6371–6384 (2007)
M.P. Boneva, K.D. Danov, N.C. Christov, P.A. Kralchevsky, Attraction between particles at a liquid interface due to the interplay of gravity- and electric-field-induced interfacial deformations. Langmuir 25(16), 9129–9139 (2009)
A. Dani, G. Keiser, M. Yeganeh, C. Maldarelli, Hydrodynamics of particles at an oil–water interface. Langmuir 31, 13290–13302 (2015)
P. Singh, D.D. Joseph, Fluid dynamics of floating particles. J. Fluid Mech. 530, 31–80 (2005)
A. Dörr, S. Hardt, Driven particles at fluid interfaces acting as capillary dipoles. J. Fluid. Mech. 770, 5–26 (2015)
D.M. Kaz, R. McGorty, M. Mani, M.P. Brenner, V.N. Manoharan, Physical ageing of the contact line on colloidal particles at liquid interfaces. Nat. Mater. 11, 138–142 (2012)
A.M. Rahmani, A. Wang, V.N. Manoharan, C.E. Colosqui, Colloidal particle adsorption at liquid interfaces: capillary driven dynamics and thermally activated kinetics. Soft Matter 12, 6365–6372 (2016)
S. Das, J. Koplik, R. Farinato, D.R. Nagaraj, C. Maldarelli, P. Somasundaran, The translational and rotational dynamics of a colloid moving along the air-liquid interface of a thin film. Sci. Rep. 8, 8910 (2018)
P. Seppecher, Moving contact lines in the Cahn–Hilliard theory. Int. J. Eng. Sci. 34(9), 977–992 (1996)
D. Jacqmin, Contact-line dynamics of a diffuse fluid interface. J. Fluid Mech. 402, 57–88 (2000)
T. Qian, X.P. Wang, P. Sheng, Molecular hydrodynamics of the moving contact line in two-phase immiscible flows. Commun. Comput. Phys. 1, 1–52 (2006)
P. Yue, C. Zhou, J.J. Feng, Sharp-interface limit of the Cahn–Hilliard model for moving contact lines. J. Fluid Mech. 645, 279–294 (2010)
M. Wörner, Numerical modeling of multiphase flows in microfluidics and micro process engineering: a review of methods and applications. Microfluid Nanofluid 12, 841–886 (2012)
J.C. Loudet, M. Qiu, J. Hemauer, J.J. Feng, Drag force on a particle straddling a fluid interface: Influence of interfacial deformations. Eur. Phys. J. E 43, 13 (2020). https://doi.org/10.1140/epje/i2020-11936-1
D. Jacqmin, Calculation of two-phase Navier–Stokes flows using phase-field modeling. J. Comput. Phys. 155, 96–127 (1999)
P. Yue, J.J. Feng, C. Liu, J. Shen, A diffuse-interface method for simulating two-phase flows of complex fluids. J. Fluid Mech. 515, 293–317 (2004)
F. Pigeonneau, E. Hachem, P. Saramito, Discontinuous Galerkin finite element method applied to the coupled unsteady Stokes/Cahn-Hilliard equations. Int. J. Numer. Meth. Fluids 90, 267–295 (2019)
P. Yue, C. Zhou, J.J. Feng, C.F. Ollivier-Gooch, H.H. Hu, Phase-field simulations of interfacial dynamics in viscoelastic fluids using finite elements with adaptive meshing. J. Comput. Phys. 219, 47–67 (2006)
P. Singh, T.I. Hesla, The interfacial torque on a partially submerged sphere. J. Colloid Interface Sci. 280, 542–543 (2004)
COMSOL Multiphysics® v. 5.4 reference manual. https://www.comsol.com/documentation. COMSOL AB, Stockholm, Sweden
A. Khalili, B. Liu, Stokes’ paradox: creeping flow past a two-dimensional cylinder in an infinite domain. J. Fluid Mech. 817, 374–387 (2017)
J. Koplik, C. Maldarelli, Diffusivity and hydrodynamic drag of nanoparticles at a vapor–liquid interface. Phys. Rev. Fluids 2, 024303 (2017)
W.M. Deen, Analysis of Transport Phenomena (Oxford University Press, Oxford, 1998)
K.D. Danov, R. Dimova, B. Pouligny, Viscous drag of a solid sphere straddling a spherical or flat interface. Phys. Fluids 12, 2711–2722 (2000)
S. Nawar, J.K. Stolaroff, C. Ye, H. Wu, D.T. Nguyen, F. Xin, D.A. Weitz, Parallelizable microfluidic dropmakers with multilayer geometry for the generation of double emulsions. Lab Chip 20, 147–154 (2020)
M. Oettel, A. Domínguez, M. Tasinchevych, S. Dietrich, Effective interactions of colloids on nematic films. Eur. Phys. J. E 28, 99–111 (2009)
I.B. Liu, M.A. Gharbi, V.L. Ngo, R.D. Kamien, S. Yang, K.J. Stebe, Elastocapillary interactions on nematic films. Proc. Natl. Acad. Sci. USA 112, 6336–6340 (2015)
Acknowledgements
This work was financially supported by the EU Marie-Curie fellowship “CoPEC” under Grant No. 794837–H2020-MSCA-IF-2017 and by the NSERC Discovery Grant No. 2019-04162. One of us (J.-C.L.) is also indebted to the University of Bordeaux for further financial support thanks to the IdEx program entitled “Développement des carrières - Volet personnel de recherche.” We acknowledge CMC Microsystems for software licensing. The IT staff of the Mathematics department of the University of British Columbia is also gratefully acknowledged for their valuable help and support.
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J-CL and JJF designed the research. J-CL and JH performed the work; all authors analyzed the data, interpreted the results and collaborated to the manuscript written by J-CL.
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Hemauer, J., Qiu, M., Feng, J.J. et al. Particle rotation speeds up capillary interactions. Eur. Phys. J. E 44, 30 (2021). https://doi.org/10.1140/epje/s10189-021-00025-w
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DOI: https://doi.org/10.1140/epje/s10189-021-00025-w