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Equilibrium States in Aqueous Solutions of Some Ionic Liquids

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Abstract—Physicochemical properties of aqueous solutions of a number of proton ionic liquids (electrical conductivity, dissociation parameters, pH, and concentration functions) are determined using specially designed equipment and the techniques of computer resistometry. The correlations between the physicochemical properties of water–organic mixtures and a possible structure of the organic phase are established.

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REFERENCES

  1. Koshel’, N.D., Magdych, E.A., and Akimov, A.M., Regeneration of an ion exchanger in an electric field in an ion exchange column, Vopr. Khim. Khim. Tekhnol., 2010, vol. 5, p. 137.

    Google Scholar 

  2. Newman, J.S., Electrochemical System, Englewood Cliffs, NJ: Prentice-Hall, 1973.

    Google Scholar 

  3. Zoski, C.G., Handbook of Electrochemistry, Amsterdam: Elsevier, 2007.

    Google Scholar 

  4. Demirbas, A., Pehlivan, E., Gode, F., Altun, T., et al., Adsorption of Cu(II), Zn(II), Ni(II), Pb(II), and Cd(II) from aqueous solution on Amberlite IR-120 synthetic resin, J. Colloid Interface Sci., 2005, vol. 282, no. 1, p. 20.

    Article  Google Scholar 

  5. Pehlivan, E. and Altun, T., Comparison of adsorption capacity of young brown coals and humic acids prepared from different coal mines in Anatolia, J. Hazard. Mater., 2006, vol. 134, nos. 1–3, p. 149.

    Article  Google Scholar 

  6. Sverdlikovśka, O.S., Perspective of ionics liquids on bisquaternary salts of ammonium of derivates morpholyne with anion of thetrafluorineborate, Eur. Appl. Sci., 2014, vol. 7, p. 73.

  7. Sun, J., Murthy Konda, N.V.S.N., Parthasarathi, R., Dutta, T., et al., One-pot integrated biofuel production using low-cost biocompatible protic ionic liquids, Green Chem., 2017, vol. 13. https://doi.org/10.1039/C7GC01179B

  8. Washburn, E.W., International Critical Tables of Numerical Data, Physics, Chemistry and Technology, New York: US Natl. Res. Conc., 2003, no. 6.

  9. McCleskey, B.R., Electrical conductivity of electrolytes found in natural waters from 5 to 90°C, J. Chem. Eng. Data, 2011, vol. 56, no. 2, p. 317.

    Article  Google Scholar 

  10. Hunt, R.C., How to Increase the Accuracy of Solution Conductivity Measurements, Santa Ana, CA: Sensor Dev., 1995. http://www.aitsouthwest.com.

    Google Scholar 

  11. Shaplov, A.S., Lozinskaya, E.I., Ponkratov, D.O., Malyshkina, I.A., et al., Bis(trifluoromethylsulfonyl) amide based “polymeric ionic liquids”: Synthesis, purification and peculiarities of structure–properties relationships, Electrochim. Acta, 2011, vol. 57, p. 74.

    Article  Google Scholar 

  12. Shaposhnik, V.A., Reshetnikova, A.K., Zolotareva, R.I., and Isaev, N.I., Water demineralization by electrodialysis using intermembrane filling of ion exchanger sections, Zh. Prikl. Khim., 1973, vol. 46, no. 12, p. 2659.

    Google Scholar 

  13. Özgür, A., Ümran, Y., Nalan, K., and Mithat, Y., Various applications of electrodeionization (EDI) method for water treatment—A short review, Desalination, 2014, vol. 342, p. 16.

    Article  Google Scholar 

  14. Smara, A., Delimi, R., Chai-Net, E., and Sandeaux, J., Removal of heavy metals from diluted mixtures by a hybrid ion-exchange/electrodialysis process, Sep. Purif. Technol., 2007, vol. 57, no. 1, p. 103.

    Article  Google Scholar 

  15. Davies, P.A. and Orfi, J., Self-powered desalination of geothermal saline groundwater: Technical feasibility, Water, 2014, vol. 6, no. 11, p. 3409. https://doi.org/10.3390/w6113409

    Article  Google Scholar 

  16. Alvarado, L. and Chen, A., Electrodeionization: principles, strategies and applications, Electrochim. Acta, 2014, vol. 132, p. 583.

    Article  Google Scholar 

  17. Dzyazko, Yu.S. and Belyakov, V.N., Purification of a diluted nickel solution containing nickel by a process combining ion exchange and electrodialysis, Desalination, 2004, vol. 162, p. 179.

    Article  Google Scholar 

  18. Shvedene, N.V., Chernyshov, D.V., and Pletnev, I.V., Ionic liquids in electrochemical sensors, Russ. J. Gen. Chem., 2008, vol. 78, no. 12, p. 2507.

    Article  Google Scholar 

  19. Spravochnik khimika. Tom 3. Khimicheskoe ravnovesie i kinetika svoistva rastvorov. Elektrodnye protsessy (Handbook of Chemist, Vol. 3: Chemical Balance and Kinetics of Solution Properties. Electrode Processes), 2nd ed., Moscow: Khimiya, 19651965.

  20. Koshel’, N.D. and Kostyrya, M.V., Conductance-measuring method for quantitative analysis of two-component electrolyte solutions, Surf. Eng. Appl. Electrochem., 2018, vol. 54, no. 1, p. 103.

    Article  Google Scholar 

  21. Koshel, N.D., Smyrnova, O.V., and Kostyrya, M.V., The study of ion exchange kinetics on the anionite in weak electric fields, Proc. 8th International Conf. “Materials Science & Condensed Matter Physics,” September 12–16, 2016, Abstracts of Papers, Chisinau, 2016, p. 340.

  22. Koshel, N.D., Smirnova, E.V., Burtovaya, V.P., and Koshel’, S.A., The exchange properties of the AN-2FN anionite by the computer resistometry, Vopr. Khim. Khim. Tekhnol., 2018, no. 5, pp. 23–30.

  23. Greaves, T.L. and Drummond, C.J., Protic ionic liquids: properties and applications, Chem. Rev., 2008, vol. 108, no. 1, p. 206.

    Article  Google Scholar 

  24. Drozd, G.I., Fosfaty organicheskie. Khimicheskaya entsiklopediya (Organic Phosphates. Chemical Encyclopedia), Moscow: Bol’shaya Rossiiskaya Entsiklopediya, 1998, vol. 5, pp. 131−132. https://ru.wikipedia.org/wiki/.

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Correspondence to N. D. Koshel.

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Translated by M. Myshkina

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Koshel, N.D., Koshel, S.A., Sverdlikovskaya, O.S. et al. Equilibrium States in Aqueous Solutions of Some Ionic Liquids. Surf. Engin. Appl.Electrochem. 57, 88–100 (2021). https://doi.org/10.3103/S1068375521010063

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  • DOI: https://doi.org/10.3103/S1068375521010063

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