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Caloric Properties of RbBi2 Alloy in a Condensed State

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Abstract

A massive drop calorimeter with an isothermal shell was used to measure the enthalpy increment of the intermetallic compound RbBi2 in solid and liquid states in the temperature range of 432–1176 K. Approximating equations are obtained, and the isobaric heat capacity and enthalpy change on melting are determined. The estimated errors of the data on enthalpy and heat capacity were 0.4% and 1.0%, respectively. The enthalpy of alloy formation in the liquid state is determined. The obtained data are compared with the results of the calculations according to the law of ideal solutions.

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REFERENCES

  1. Xu, R., Kinderman, R., and van der Lugt, W., J. Phys.: Condens. Matter, 1991, vol. 3, p. 127.

    ADS  Google Scholar 

  2. Stankus, S.V., Abdullaev, R.N., and Khairulin, R.A., High Temp.—High Pressures, 2018, vol. 47, no. 5, p. 403.

    Google Scholar 

  3. Hochgesand, K. and Winter, R., J. Chem. Phys., 2000, vol. 112, p. 7551.

    Article  ADS  Google Scholar 

  4. Liu, M., Li, C., Du, Z., Guo, C., and Niu, C., Thermochim. Acta, 2013, vol. 551, p. 27.

    Article  Google Scholar 

  5. Petric, A., Pelton, A.D., and Saboungi, M.-L., J. Electrochem. Soc., 1988, vol. 135, p. 2754.

    Article  ADS  Google Scholar 

  6. Van der Lugt, W., Phys. Scr., 1991, vol. 39, p. 372.

    Article  Google Scholar 

  7. Stankus, S.V., Savchenko, I.V., Yatsuk, O.S., and Raschektaeva, E.P., Russ. J. Phys. Chem. A, 2018, vol. 92, no. 9, p. 1654.

    Article  Google Scholar 

  8. Stankus, S.V., Savchenko, I.V., and Yatsuk, O.S., High Temp., 2018, vol. 56, no. 1, p. 33.

    Article  Google Scholar 

  9. Pelton, A.D. and Petric, A., J. Phase Equilib., 1993, vol. 14, p. 368.

    Article  Google Scholar 

  10. Voronin, G.F., Gerasimov, Ya.I., and Mukhamedzhanova, N.M., Zh. Fiz. Khim., 1974, vol. 48, no. 12, p. 2941.

    Google Scholar 

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Funding

The study was supported by a grant from the Russian Science Foundation, project no. 16-19-10023-P.

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Correspondence to S. V. Stankus.

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Stankus, S.V., Savchenko, I.V., Yatsuk, O.S. et al. Caloric Properties of RbBi2 Alloy in a Condensed State. High Temp 58, 945–947 (2020). https://doi.org/10.1134/S0018151X20060218

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  • DOI: https://doi.org/10.1134/S0018151X20060218

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