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Electric Field Distribution of an Optical Nanocavity Embedded with a Single Molecule

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Abstract

Using state-of-the-art quantum mechanical calculations, we investigate the spatial profile of the electric field enhancements induced within an optical cavity embedded with a variety of organic molecules. We observed marked differences in the spectral positions, spectral intensities, maximum achievable electric field, and spatial profile of the electric field with a remarkable sensitivity to the embedded molecular type. In a broader perspective, our quantum mechanical calculations provide quantitative access to the molecule-dependent electric field distributions and unveil intricate and rich optical features.

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Data Availability

The data and materials generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

Code Availability

The computational codes employed in the current study are available from the corresponding author on reasonable request.

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Funding

The research reported in this publication was supported by funding from Kuwait College of Science And Technology (KCST).

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  1. Quantum Nanophotonics Simulations Lab, Department of Physics, Kuwait College of Science and Technology, P.O. Box 27235, Doha Area, 7th Ring Road, Doha, Kuwait

    Junais Habeeb Mokkath

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J. H. Mokkath contributed to conceptualization, data curation, formal analysis, writing—original draft, funding acquisition, project administration, resources, software, supervision, validation, writing—review, and editing.

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Correspondence to Junais Habeeb Mokkath.

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Mokkath, J.H. Electric Field Distribution of an Optical Nanocavity Embedded with a Single Molecule. Plasmonics 16, 1515–1524 (2021). https://doi.org/10.1007/s11468-021-01398-6

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