Skip to main content
Log in

Deactivation of Materials and Articles in the Presence of Silver(II)

  • Published:
Radiochemistry Aims and scope

Abstract

Experimental results are presented to substantiate conditions and modes of the process of deactivation of materials and articles to remove the surface α-, and γ-radioactive contamination. Compositions of a deactivating solution based on a mixture of nitric and phosphoric acids with addition of divalent silver, which enable a 102–103-fold decrease in the surface radioactive contamination in one deactivation cycle at room temperature. A scheme of silver regeneration for its repeated use was developed. The scheme provides a silver yield of about 95% with a ~105 coefficient of purification to remove radioactive isotopes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Henning, K., Schulz, W., and Muller, M., VGB Kraftwerkstechn, 1984, vol. 64, no. 2, pp. 146–151.

    CAS  Google Scholar 

  2. Wood, C.J., Power, 1984, vol. 128, no. 2, pp. 83–87.

    CAS  Google Scholar 

  3. Savkin, A.E., Karlina, O.K., Vasil’ev, A.P., et al., Radioekol. Zh. Bezopasnost’ Okruzhayushchei Sredy, 2007, no. 3, pp. 38–41.

    Google Scholar 

  4. Savkin, A.E., Karlina, O.K., Vasil’ev, A.P., Radioekol. Zh. Bezopasnost’ Okruzhayushchei Sredy, 2010, no. 1, pp. 116–119.

    Google Scholar 

  5. Schenker, E., Buckley, D., Alder, N.R., Francioni, W., Heess, W., Couraht, A., Water Chemical Nuclear Reactor System: Proceedings of the Conference. Bournemonth, 23–27 Oct., 1989, vol. 2, London, pp. 186-187.

    Google Scholar 

  6. Bredtek, L., Bredberi, D., and Elder, D.R., Patent RU 2142172 C1 (Publ. 27.11.1999).

  7. Komarov, E.A., Kuzov, V.A., Khvostov, V.I., et al., Patent RU 2417467 (Publ. 27.04.2011).

  8. Turner, A.D. and Dell, R.M., Atom (UK), 1984, vol. 331, pp. 7–10.

    Google Scholar 

  9. Gauchon, J.P., Mordenti, P., Bezia, C., et al., Part of the Landolt–Börnstein Group VIII Advanced Materials and Technologies Book Ser, vol. 4: Radiological Protection, Berlin: Springer, 2005.

    Google Scholar 

  10. Westerberg, K. and Waltersten, T., Water Chem. Nucl. React. Syst., 1989, pp. 191–195.

    Google Scholar 

  11. Pujol Pozo, A.A., Bustos, E., and Monroy-Guzman, F., J. Hazard. Mater., 2019, vol. 361, pp. 357–366.

    Article  CAS  Google Scholar 

  12. Nikishin, G.D., Pimenova, M.A., Ivakhnyuk, G.K., and Smirnov, V.N., Vestn. Sankt-Peterb. Inst. Gosudarstvennoi Protivopozharnoi Sluzhby, 2005, no. 2(9), pp. 33–36.

    Google Scholar 

  13. Veiko, V.P., Shakhno, E.A., Veiko, V.P., and Smirnov, V.N., Opt. Zh., 2007, vol. 74, no. 8, pp. 33–36.

    Google Scholar 

  14. Zimon, A.D., Dezaktivatsiya (Decontamination), Moscow: Atomizdat, 1975.

    Google Scholar 

  15. Kritskii, V.G. and Rodionov, Yu.A., Osnovy dezaktivatsii. Sposoby i tekhnicheskie sredstva dezaktivatsii (Basics of Decontamination. Methods and Technical Means of Decontamination), St. Petersburg: KSI-Print, 2013.

    Google Scholar 

  16. Koryakovskii, Yu.S., Doil’nitsyn, V.A., Akatov, A.A., and Matveev, S.A., Izv. SPbGTI, 2014, no. 254, pp. 68–79.

    Google Scholar 

  17. Gosudarstvennyi standart Rossiiskoi Federatsii R 50830–95. Istochniki zakrytye radioaktivnye. Obshchie polozheniya (RF State Standard R 50830–95. Sealed Radioactive Sources. General Provisions), ISO 1677-77.

  18. Analiticheskaya khimiya transplutonievykh elementov (Analytical Chemistry of Transplutonium Elements), Vinogradov, A.P., Moscow: Nauka, 1972.

  19. Erin, E.A., Volkov, A.Yu., Baranov, A.A., Timofeev, G.A., and Chistyakov, V.M., Patent RU 2163039 (Publ. 10.02.2001).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. N. Momotov.

Ethics declarations

The authors state that they have no conflict of interest.

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 1, pp. 75–79, December, 2020 https://doi.org/10.31857/S0033831121010111

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Erin, E.A., Momotov, V.N. & Volkov, A.Y. Deactivation of Materials and Articles in the Presence of Silver(II). Radiochemistry 63, 72–76 (2021). https://doi.org/10.1134/S1066362221010112

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1066362221010112

Keywords:

Navigation