Abstract
Samples of sodium aluminum iron phosphate glass were synthesized containing rhenium as a surrogate of technetium from radioactive waste. The phase composition, structure and water resistance of the obtained glasses were investigated. It was shown that the samples with the rhenium oxide inclusion up to 2.88 wt % are X-ray amorphous and homogeneous, and their anionic motif corresponds to the glassy one. It was found that the oxidation state of rhenium in the obtained glasses is Re(VII), and 97% of iron is in the form of Fe(III) and 3% in the form of Fe(II). The glass was established to be highly resistant to leaching at 90°C. The rate of Re leaching from glasses in accordance with the international product consistency test (PCT) and the semi-dynamic test of State Standard GOST R 52126-2003 is no more than 6 × 10–6 and 3 × 10–6 g/(cm2 day), respectively.
Similar content being viewed by others
REFERENCES
Spitsyn, V.I. and Kuzina, A.F., Tekhnetsii, Moscow: Nauka, 1981.
Soderquist, Ch.Z., Schweiger, M.J., Kim, D.S., Lukens, W.W., and McCloy, J.S., J. Nucl. Mater., 2014, vol. 449, p. 173.
Stefanovskii, S.V., Stefanovskaya, O.I., Vinokurov, S.E., Danilov, S.S., and Myasoedov, B.F., Radiochemistry, 2015, vol. 57, no. 4, p. 295. https://doi.org/10.1134/S1066362215040037
Danilov, S.S., Stefanovsky, S.V., Stefanovskaya, O.I., Vinokurov, S.E., Myasoedov, B.F., and Teterin, Yu.A., Radiochemistry, 2018, vol. 60, no. 4, p. 434. https://doi.org/10.1134/S1066362218040136
Stefanovskii, S.V., Maslakov, K.I., Teterin, Yu.A., Kalmykov, S.N., Danilov, S.S., Teterin, A.Yu., and Ivanov, K.E., Dokl. Akad. Nauk, 2018, vol. 478, no. 2, p. 175.
Stefanovskii, S.V., Stefanovskaya, O.I., Semenova, D.V., Kadyko, M.I., and Danilov, S.S., Steklo Keramika, 2018, no. 3, p. 9.
Stefanovsky, S.V., Sefanovsky, O.I., Myasoedov, B.F, Vinokurov, S.E., Danilov, S.S., Nikonov, B.S., Maslakov, K.I., and Teterin, Yu.A., J. Non-Cryst. Solids, 2017, vol. 471, p. 421.
Maslakov, K.I., Teterin, Yu.A., Stefanovsky, S.V., Kalmykov, S.N., Teterin, A.Yu., Ivanov, K.E., and Danilov, S.S., J. Non-Cryst. Solids, 2018, vol. 482, p. 23.
Mysen, B.O., Finger, L.W., Virgo, D., and Seifert, F.A., Am. Mineral., 1982, vol. 67, nos. 7–8, p. 686.
Shirley, D.A., Phys. Rev. B, 1972, vol. 5, no. 12, p. 4709.
ASTM Standard C 1285-94, Standard Test Methods for Determining Chemical Durability of Nuclear Waste Glasses: The Product Consistency Test (PCT), Philadelphia: ASTM, 1994.
GOST R 52126–2003. Otkhody radioaktivnye. Opredelenie khimicheskoi ustoichivosti otverzhdennykh vysokoaktivnykh otkhodov metodom dlitel’nogo vyshchelachivaniya (Radioactive waste. Determination of the chemical stability of solidified high-level waste by the long-term leaching method), Moscow: Gosstandart Rossii, 2003.
De Groot, G.J. and Van der Sloot, H.A., Stabilization and Solidification of Hazardous, Radioactive and Mixed Wastes, Gilliam, T.M. and Wiles, C.C., Philadelphia: ASTM, 1992.
Lazarev, A.N., Mirgorodskii, A.P., and Ignat’ev, I.S., Kolebatel’nye spektry slozhnykh okislov (Vibrational Spectra of Complex Oxides.), Leningrad: Nauka, 1975.
Plyusnina, I.I., Infrakrasnye spektry mineralov (Infrared Spectra of Minerals), Moscow: Izd. Mosk. Iniv, 1977.
Naumkin, A., Kraut-Vass, A., Gaarenstroom, S., and Powell, C., NIST X-ray Photoelectron Spectroscopy Database, US Secretary of Commerce, 2012. https://srdata.nist.gov/xps/Default.aspx.
Thorn, R.J., Carlson, K.D., Crabtree, G.W., and Wang, H.H., J. Phys. C: Solid State Phys., 1985, vol. 18, no. 28, p. 5501.
Maslakov, K.I., Teterin, Yu.A., Stefanovsky, S.V., Kalmykov, S.N., Teterin, A.Yu., and Ivanov, K.E., J. Alloys Compd., 2017, vol. 712, p. 36.
Laverov, N.P., Yudintsev, S.V., and Omel’yanenko, B.I., Geologiya rudn. mestorozhdenii, 2009, vol. 51, no. 4, p. 291.
Pirlet, V., Lemmens, K., and Van Iseghem, P., Proc. Scientific Basis for Nuclear Waste Management XXVII, Warrendale: MRS, 2004, vol. 824, p. 385.
Vlasova,, N.V., Remizov, M.B., Kozlov, P.V., and Belanova, E.A., Vopr. Radiats. Bezopasnosti, 2017, no. 3, p. 32.
Frugier, P., Gin, S., Minet, Y., Chave, T., Bonin, B., Gordon, N., Lartigue J.-E., Jollivet, P., Ayral, A., De Windt, L., and Santarini, G., J. Nucl. Mater., 2008, vol. 380, p. 8.
NP-019-15: Federal’nye normy i pravila v oblasti ispol’zovaniya atomnoi energii. Sbor, pererabotka, khranenie i konditsionirovanie zhidkikh radioaktivnykh otkhodov (NP-019-15: Federal Norms and Rules in the Field the Use of Atomic Energy. Collection, Treating, Storage, and Conditioning of liquid radioactive waste. Safety Requirements), Rostekhnadzor, 2015.
Al-Abed, S.R., Hageman, P.L., Jegadeesan, G., Madhavan, N., and Allen, D., Sci. Total Environ., 2006, vol. 364, p. 14.
Moon, D.H. and Dermatas, D., Eng. Geol., 2006, vol. 85, p. 67.
Torras, J., Buj, I., Rovira, M., and de Pablo, J., J. Hazard. Mater., 2011, vol. 186, p. 1954.
Frugier, P., Gin, S., Minet, Y., Chave, T., Bonin, B., Gordon, N., Lartigue, J.-E., Jollivet, P., Ayral, A., De Windt, L., and Santarini, G., J. Nucl. Mater., 2008, vol. 380, p. 8.
Martynov, K.V., Konstantinova, L.I., and Zakharova, E.V., Vopr. Radiats. Bezopasnosti, 2015, no. 4, p. 10.
Funding
The research was carried out within the framework of the state assignment of the GEOKHI RAS (0137-2019-0022). The studies used equipment purchased at the expense of the Development Program of the Moscow State University.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare no conflicts of interest.
Additional information
Translated from Zhurnal Prikladnoi Khimii, No. 6, pp. 512–518, December, 2020 https://doi.org/10.31857/S0033831120060076
Rights and permissions
About this article
Cite this article
Danilov, S.S., Frolova, A.V., Kulikova, S.A. et al. Immobilization of Rhenium as a Technetium Surrogate in Aluminum Iron Phosphate Glass. Radiochemistry 63, 99–106 (2021). https://doi.org/10.1134/S106636222101015X
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S106636222101015X