Abstract
The hard-to-synthesize lead-based zinc-bearing trio of Pb(Zn1/3Ta2/3)O3, Pb(Zn1/3Nb2/3)O3, and Pb(Zn1/2W1/2)O3 (PZT, PZN, and PZW) were investigated to understand their structural stability and phase formation. A structure field map is used to discuss the capability of the trio compositions and combinations thereof, to form the perovskite structure, with PbTiO3(PT) introduced as a perovskite stabilizer. We identified the potential omission of the (111) reflections in two International Centre for Diffraction Data (ICDD) sets of a complex-rutile structure, [(Zn1/3Ta2/3)1/2Ti1/2]O2 and [(Zn1/3Nb2/3)1/2Ti1/2]O2, and suggest that the intensities of the latter compound need to be re-examined. The perovskite structure started to develop at different fractions of PT, depending upon the species of the trio: PZN required the smallest amount of PT (< 20 mol%), whereas PZW required the greatest (≤ 80 mol%). The perovskite-stable composition area was the widest in PZT-PZN-PT and narrowest in PZW-PZT-PT, indicating the comparative ease/difficulty of perovskite formation among the trio compositions.
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G.A. Smolenskii, A.I. Agranovskaya, Sov. Phys.-Tech. Phys. 3(7), 1380–1382 (1958)
G.A. Smolenskii, A.I. Agranovskaya, S.N. Popov, Sov. Phys.-Solid State 1(1), 147–148 (1959)
G.A. Smolenskii, A.I. Agranovskaya, Sov. Phys.-Solid State 1(10), 1429–1437 (1960)
W.A. Bonner, L.G. VanUitert, Mater. Res. Bull. 2(1), 131–134 (1967)
G.A. Smolenskii, J. Phys. Soc. Jpn. 28(suppl), 26–37 (1970)
N. Setter, L.E. Cross, J. Crystal Growth 50(2), 555–556 (1980)
S.L. Swartz, T.R. Shrout, Mater. Res. Bull. 17(10), 1245–1250 (1982)
S. Nomura, T. Takahashi, Y. Yokomizo, J. Phys. Soc. Jpn. 27(1), 262 (1969)
Y. Yokomizo, S. Nomura, J. Phys. Soc. Jpn. 28(suppl), 150–152 (1970)
Y. Yokomizo, T. Takahashi, S. Nomura, J. Phys. Soc. Jpn. 28(5), 1278–1284 (1970)
S. Nomura, H. Arima, Jpn. J. Appl. Phys. 11(3), 358–364 (1972)
D.-H. Lee, N.-K. Kim, Mater. Lett. 34(3–6), 299–304 (1998)
M.-C. Chae, N.-K. Kim, J.-J. Kim, S.-H. Cho, J. Mater. Sci. 33(5), 1343–1348 (1998)
M.-C. Chae, N.-K. Kim, J.-J. Kim, S.H. Cho, Ferroelectrics 211(1–4), 25–39 (1998)
B.-Y. Ahn, N.-K. Kim, J. Am. Ceram. Soc. 83(7), 1720–1726 (2000)
B.-H. Lee, N.-K. Kim, Mater. Lett. 62(1), 137–139 (2008)
B.-Y. Ahn, T.-K. Park, N.-K. Kim, Ceram. Int. 37(2), 549–553 (2011)
V.A. Bokov, I.E. Myl’nikova, Sov. Phys.-Solid State 2(11), 2428–2432 (1961)
H.M. Jang, S.H. Oh, J.H. Moon, J. Am. Ceram. Soc. 75(1), 82–88 (1992)
Y. Matsuo, H. Sasaki, S. Hayakawa, F. Kanamaru, M. Koizumi, J. Am. Ceram. Soc. 52(9), 516–517 (1969)
J. Wang, D. Wan, J. Xue, W.B. Ng, J. Am. Ceram. Soc. 82(2), 477–479 (1999)
J. Wang, J. Xue, D. Wan, Solid State Ionics 127(1–2), 169–175 (2000)
B.-Y. Ahn, N.-K. Kim, Mater. Res. Bull. 35(10), 1677–1687 (2000)
M.-C. Chae, S.-M. Lim, N.-K. Kim, Ferroelectrics 242(1–4), 25–35 (2000)
B.-Y. Ahn, N.-K. Kim, J. Mater. Sci. 37(21), 4697–4701 (2002)
J.-S. Kim, N.-K. Kim, H. Kim, J. Am. Ceram. Soc. 86(6), 929–933 (2003)
J.-A. Lee, N.-K. Kim, Mater. Lett. 59(1), 32–35 (2005)
J.-A. Lee, N.-K. Kim, Mater. Res. Bull. 40(10), 1839–1846 (2005)
K.-H. Seo, B.-H. Lee, N.-K. Kim, J. Ko, J. Mater. Sci. 40(23), 6151–6156 (2005)
W.-J. Lee, N.-K. Kim, J. Mater. Sci. 43(10), 3608–3611 (2008)
W.-J. Lee, J.-S. Kim, N.-K. Kim, J. Eur. Ceram. Soc. 27(16), 4473–4478 (2007)
S.-H. Cho, B.-H. Lee, N.-K. Kim, Ceram. Int. 35(4), 1611–1616 (2009)
A. Halliyal, U. Kumar, R.E. Newnham, L.E. Cross, Am. Ceram. Soc. Bull. 66(4), 671–676 (1987)
T.R. Shrout, A. Halliyal, Am. Ceram. Soc. Bull. 66(4), 704–711 (1987)
C.A. Randall, A.S. Bhalla, T.R. Shrout, L.E. Cross, J. Mater. Res. 5(4), 829–834 (1990)
N. Wakiya, K. Shinozaki, N. Mizutani, J. Am. Ceram. Soc. 80(12), 3217–3220 (1997)
L. Zhou, P.M. Vilarinho, J.L. Baptista, Mater. Res. Bull. 29(11), 1193–1201 (1994)
B.-H. Lee, N.-K. Kim, J.-J. Kim, S.-H. Cho, Ferroelectrics 211(1–4), 233–247 (1998)
S. Ananta, N.W. Thomas, J. Eur. Ceram. Soc. 19(2), 155–163 (1999)
R.D. Shannon, Acta Crystallogr. A32(5), 751–767 (1976)
W.F. Smith, J. Hashemi, Foundations of materials science and engineering, 4th edn. (McGraw-Hill, Seoul, 2008), Fig. 2.9
Acknowledgements
This study was supported by the Kyungpook National University Research Fund, 2018-21. The authors also express gratitude to D.-H. Seo, who was involved in the early stage of the research.
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Lee, BH., Kim, NK. Phase developments in Pb(Zn[Ta,Nb,W])O3-PbTiO3 ternary ceramic compositions. J Electroceram 45, 111–118 (2020). https://doi.org/10.1007/s10832-021-00230-1
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DOI: https://doi.org/10.1007/s10832-021-00230-1