Organic matter characterization of the Lower Cretaceous tight reservoirs in the Danish North Sea

https://doi.org/10.1016/j.coal.2021.103714Get rights and content

Highlights

  • Migration of oil into the Lower Cretaceous reservoirs charged from Upper Jurassic–lowermost Cretaceous Farsund Formation.

  • Kerogen comcomprises immature marine algae, degraded bituminite and solid bitumen precipitated from the migrated late-oil, more abundant in the interbedded argillaceous Fischschiefer Member and Munk Marl Bed.

  • The heterogeneous lithology, diagenetic bituminite and formation of secondary solid bitumen at various levels are important attributes needed while considering petrophysical calculations.

Abstract

This paper presents the first detailed organic geochemistry and petrography of the Lower Cretaceous tight reservoir units from the Valdemar Field, Danish Central Graben. The Tuxen and Sola formation chalks and the interbedded argillaceous Munk Marl Bed and Fischschiefer Member, respectively, contain thermally immature marine Type II kerogen, mainly algal liptinites, degraded bituminite and late-oil solid bitumen. The more clay-rich Fischschiefer Member and Munk Marl Bed constitute a relatively efficient seal for vertical migration and have significantly higher kerogen content as compared to the more calcareous Sola and Tuxen reservoirs. Evidence for significant oil migration can be observed across all the lithounits, highest in the Tuxen Fm which also constitute the main reservoir. Microscopic observations show a widespread distribution of granular degraded bituminite, formed by microbial degradation and diagenetic alteration of liptinites, and late-oil solid bitumen precipitated from the migrated oils. Biomarkers from rock extracts indicate open-marine depositional conditions of the source rocks that charged the hydrocarbons, having a geochemical composition similar to oils charged from the Upper Jurassic–lowermost Cretaceous Farsund Formation. The solid bitumen within such heterogeneous reservoir units might influence both reservoir quality and petrophysical properties.

Introduction

The Lower Cretaceous Tuxen and Sola formations are low porosity and permeability chalk reservoirs in the Valdemar Field of the Danish Central Graben (DCG), North Sea (Japsen et al., 2003; Jakobsen et al., 2004; Van Buchem et al., 2018). The Valdemar Field lies in the central part of the DCG and is dominated by the N-S elongated North Jens-Bo anticline, divided into two structural highs around the North Jens-1 well in the north and the Bo-1 well in the south (Jakobsen et al., 2005) (Fig. 1). It consists of separate Danian/Upper Cretaceous chalk and Lower Cretaceous chalk reservoirs and contains an estimated reserve of 5 million m3 oil and 2 billion Nm3 gas (Danish Energy Agency, 2018), however, the field has complex reservoir properties, tectonic evolution and charging history (Jakobsen et al., 2005; Van Buchem et al., 2018; Ponsaing et al., 2020a, Ponsaing et al., 2020b). The Tuxen and Sola reservoirs comprise pelagic/hemipelagic chalks and marly units, interbedded by thin argillaceous units of the Munk Marl Bed and Fischschiefer Member, respectively (Van Buchem et al., 2018). The chalk reservoirs are faulted and highly fractured with signs of overpressure and undercompaction (Jakobsen et al., 2005; Van Buchem et al., 2018; Ponsaing et al., 2020a, Ponsaing et al., 2020b). Production from the extremely low-permeable reservoir is based on natural depletion but is challenging. However, commercial production is achieved by long horizontal wells and creation of numerous sand-filled fractures (Danish Energy Agency, 2014).

The Upper Jurassic-lowermost Cretaceous marine shales of the Farsund Formation are the primary source rocks of the crude oil in the Valdemar Field. Bulk organic geochemical and organic petrological studies of the Farsund Formation have documented different organofacies and source rock quality of the shales which can be related to different oil family types in the DCG (Petersen et al., 2010, Petersen et al., 2013, Petersen et al., 2017; Ponsaing et al., 2020a, Ponsaing et al., 2020b). Different oil families in the Valdemar Field reveal a complex charging history from different organofacies and kitchen areas (Petersen et al., 2016; Schovsbo et al., 2018; Ponsaing et al., 2020a, Ponsaing et al., 2020b). Geochemical and petrographic studies on the Lower Cretaceous reservoirs rocks of the Valdemar Field are lacking, whilst such studies have provided valuable information about the reservoir quality, elsewhere (Jarvie et al., 2007; Passey et al., 2010; Sanei et al., 2015).

This study is the first investigation of the organic geochemical and the petrological properties from the Lower Cretaceous chalk reservoirs and argillaceous units in the North Jens-1 well of the Valdemar Field, DCG. Documentation of abundance and type of organic matter is important as both indigenous organic matter and secondary formed solid bitumen might play an important role in affecting reservoir quality and petrophysical interpretations. Organic matter is investigated from the calcareous Tuxen and Sola formations, and interbedded argillaceous Munk Marl Bed and the Fischschiefer Member, respectively. Geochemical parameters, such as total organic carbon (TOC, wt%), thermal maturity (Tmax), oil content, kerogen type and lithology are studied using anhydrous pyrolysis geochemistry. The kerogen composition is studied by reflected white-light and fluorescence-inducing blue light organic petrography. Biomarkers from selected rock extracts are characterized to determine the source and genetic composition of the extractable petroleum fraction and compared with those from Ponsaing et al. (2020a).

Section snippets

Geological setting

The DCG represents the southernmost extension of the North Sea Central Graben system. Located at the westernmost part of the Danish offshore sector, it consists of NNW-SSE trending half-grabens and is bounded by the Coffee Soil Fault to the east and by the Mid North Sea High in the west (Fig. 1) (Van Buchem et al., 2018). Fig. 2 shows the Upper Jurassic-Lower Cretaceous stratigraphic scheme of the Valdemar Field with the source and reservoir elements and the studied section from the North

Methodology

A total of 16 core samples were collected from 2251.7 m to 2305.5 m interval in the North Jens-1 well, ranging from early-Barremian to early Aptian age (Van Buchem et al., 2018). Samples FS1-FS4 are from the Fischschiefer Member (2251.7 m to 2252.7 m), Sl5-Sl8 are from the Sola Formation (2256.7 m to 2275.3 m), below the Fischschiefer Member, Tx9-Tx11 are from the Tuxen Formation (2277.8 m to 2296.4 m) and MM12-MM16 are from the Munk Marl Bed (2303.7 m to 2305.5 m) (Table 1, Fig. 2).

All

Results

Bulk rock pyrolysis data are presented in Table 1. Briefly, the light hydrocarbon or S1 fraction ranges from 9.2 to 19.3 mg HC/g rock in the Munk Marl Bed, 6.6 to 25.8 mg HC/g rock in the Tuxen Fm, 0.2 to 11.2 mg HC/g rock in the Sola Fm, and 3.1 to 22.8 mg HC/g rock in the Fischschiefer Member. S2 ranges from 16.8 to 46.6 mg HC/g rock in the Munk Marl Bed, 6.9 to 14 mg HC/g rock in Tuxen Fm, 0.1 to 13.7 mg HC/g rock in Sola Fm, and 3.4 to 52.6 mg HC/g rock in the Fischschiefer Member. Overall

Bulk organic matter property

The bulk rock pyrolysis data show considerable variation within individual litho-units (Fig. 3, Table 1). Generally, the Fischschiefer Member and the Munk Marl Bed have relatively higher S2 and TOC values, with lower carbonate contents. The GR responses (Fig. 2) are highest in these two units due to radioactive elements present in the relatively organic-rich clay. Due to the distinct changes of the GR values in the upper and lower boundaries, these units can be correlated as regional

Conclusions

The Lower Cretaceous tight chalk reservoir units from the North Jens-1 well in the Valdemar Field, DCG, have heterogeneous lithology and show oil migration at various levels. Organic macerals are defined by immature marine algal liptinites, vitrinites and inertinites, degraded bituminite generated by the early diagenetic microbial alteration of liptinites and late-oil solid bitumen generated by retention of heavier fractions from the migrating oils. Both bituminite and late oil solid bitumen

Declaration of Competing Interest

None.

Acknowledgements

The authors kindly acknowledge the Danish Hydrocarbon Research and Technology Centre (DHRTC) under the Tight Reservoir Development (TRD), Lower Cretaceous programme for funding the research, the Danish Underground Consortium (TOTAL E&P Denmark, Noreco Oil Denmark A/S and Nordsøfonden) for providing the samples and granting the permission to publish this work. The Department of Geoscience is acknowledged for providing the infrastructure and support. Professor Shifeng Dai, editor, two anonymous

References (40)

  • J. Andsbjerg et al.

    Sequence stratigraphy of the Jurassic of the Danish Central Graben

    Geol. Surv. Denmark Greenland Bull.

    (2003)
  • Z. Chen et al.

    Correcting Tmax suppression: a numerical model for removing adsorbed heavy oil and Bitumen from Upper Ordovician Source Rocks, Arctic Canada

    Energy Fuel

    (2019)
  • Danish Energy Agency

    Oil and Gas Production in Denmark 2013

    (2014)
  • Danish Energy Agency

    Resource Assessment and Production Forecasts

    (2018)
  • GEUS
  • ICCP (International Committee for Coal and Organic Petrology)

    The new vitrinite classification (ICCP system 1994)

    Fuel

    (1998)
  • ICCP (International Committee for Coal and Organic Petrology)

    The new inertinite classification (ICCP system 1994)

    Fuel

    (2001)
  • J.R. Ineson et al.
  • F. Jakobsen et al.

    Characterization and zonation of a marly chalk reservoir: the Lower Cretaceous Valdemar Field of the Danish central graben

    Pet. Geosci.

    (2004)
  • F. Jakobsen et al.

    The Valdemar Field, Danish Central Graben: field compartmentalization and regional propspectivity of the Lower Cretaceous chalk play

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