Skip to main content
Log in

Geology and genesis of the Qi191 granite-hosted gold deposit in the southern margin of the North China Craton: constraints from SIMS zircon U–Pb, sericite 40Ar–39Ar, in-situ trace elements, and in-situ S–Pb isotopes

  • Original Paper
  • Published:
Mineralogy and Petrology Aims and scope Submit manuscript

Abstract

The Qi191 Au deposit is a newly discovered granite-hosted Au deposit in the Qiyugou Au orefield, located in the southern margin of the North China Craton (NCC). Gold ore bodies are hosted by both the Qi191 hornblende monzogranite and the Taihua Complex and are composed of disseminations and sparse veins. K-feldspar, quartz-sericite, and sericite-chlorite alteration formed outward from the center to the periphery of the mineralized granite. Principal ore minerals include galena, pyrite, and chalcopyrite, with minor sphalerite, hematite, pyrrhotite, gold, famatinite, and hessite. The Qi191 Au deposit formed over four successive stages of hydrothermal mineralization: a quartz stage (I), a quartz-pyrite-galena stage (II), an economic quartz-calcite-galena-pyrite stage (III), and a quartz-calcite stage (IV). The Qi191 hornblende monzogranite yields a SIMS zircon U–Pb age of 131.3 ± 1.0 Ma. Hydrothermal sericite yields a plateau 40Ar–39Ar age of 132.9 ± 1.4 Ma, which is consistent with the zircon U–Pb age, suggesting that the Qi191 Au deposit is generically related to the hornblende monzogranite. Trace element contents and S isotopic compositions of sulfides indicate that metals and S entered the hydrothermal fluid as pulses. The equilibrium temperature of S and the isotopic compositions of S–Pb reflect a magmatic source. Gold mainly precipitated as native gold in a relatively acidic and reducing environment. This work suggests that further exploration for magmatic hydrothermal gold deposits in the Qiyugou and more widely in the southern margin of the NCC should target hornblende monzogranites such as the Qi191 and Qi189 granitoids.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  • Bao Z, Chen L, Zong C, Yuan H, Chen K, Dai M (2017) Development of pressed sulfide powder tablets for in situ sulfur and lead isotope measurement using LA-MC-ICP-MS. Int J Mass Spectrom 421:255–262

    Article  Google Scholar 

  • Bi S, Li Z, Tang K, Gao K (2016) LA-ICP-MS in situ trace element analysis of pyrite from Dongtongyu gold deposit and its metallogenic significance, Xiaoqinling gold district. Earth Sci 41:1121–1140 (in Chinese with English abstract)

    Google Scholar 

  • Cao H-W, Zhang S-T, Santosh M, Zheng L, Tang L, Li D, Zhang X-H, Zhang Y-H (2015) The Luanchuan Mo–W–Pb–Zn–Ag magmatic–hydrothermal system in the east Qinling metallogenic belt, China: constrains on metallogenesis from C–H–O–S–Pb isotope compositions and Rb–Sr isochron ages. J Asia Earth Sci 111:751–780

    Article  Google Scholar 

  • Chao W, Ki H, Ye H, Mao J, Geng Y, Bi M, Wang P, Pei Q (2019) Geology, mineralogy, geochronology, and sulfur isotope constraints on the genesis of the Luanling gold telluride deposit, western Henan Province, Central China. Resour Geol 69:333–350

    Article  Google Scholar 

  • Chen W (1995) Lead isotope study of Xiongershan gold deposit and slver (lead) deposit in western Henan. J Precious Met Geol 4:168–176 (in Chinese with English abstract)

    Google Scholar 

  • Chen Y, Fu S (1992) Gold mineralization in West Henan. Seismological Press, Beijing (in Chinese with English abstract)

    Google Scholar 

  • Chen Y, Zhao Y (1997) Geochemical characteristics and evolution of REE in the early Precambrian sediments: evidence from the southern margin of the North China Craton. Epis 20:109–116

    Article  Google Scholar 

  • Chen Y, Guo G, Li X (1998) Metallogenic geodynamic background of Mesozoic gold deposits in granite-greenstone terrains of North China Craton. Sci China (Ser D) 41:113–120

    Article  Google Scholar 

  • Chen W, Zhang Y, Zhang Y, Jin G, Wang Q (2006) Late Cenozoic episode uplifting in southeastern part of the Tibetan plateau-evidence from Ar-Ar thermochronology. Acta Petrol Sin 22:867–872 (in Chinese with English abstract)

  • Chen Y-j, Pirajno F, Li N, Guo D-s, Lai Y (2009) Isotope systematics and fluid inclusion studies of the Qiyugou breccia pipe-hosted gold deposit, Qinling Orogen, Henan province, China: Implications for ore genesis. Ore Geol Rev 35:245–261

  • Coplen TB, Krouse HR (1998) Sulphur isotope data consistency improved. Nat 392:32

    Article  Google Scholar 

  • Deditius AP, Utsunomiya S, Reich M, Kesler SE, Ewing RC, Hough R, Walshe J (2011) Trace metal nanoparticles in pyrite. Ore Geol Rev 42:32–46

    Article  Google Scholar 

  • Deng J, Wang Q (2016) Gold mineralization in China: Metallogenic provinces, deposit types and tectonic framework. Gondwana Res 36:219–274

    Article  Google Scholar 

  • Deng J, Gong Q, Wang C, Carranza EJM, Santosh M (2014) Sequence of late Jurassic-early cretaceous magmatic-hydrothermal events in the Xiong’ershan region, Central China: an overview with new zircon U-Pb geochronology data on quartz porphyries. J Asia Earth Sci 79:161–172

    Article  Google Scholar 

  • Ding T, Valkiers S, Kipphardt H, Bièvre PD, Taylor PDP, Gonfiantini R, Krouse R (2001) Calibrated sulfur isotope abundance ratios of three IAEA sulfur isotope reference materials and V-CDT with a reassessment of the atomic weight of sulfur. Geochim Cosmochim Acta 65:2433–2437

    Article  Google Scholar 

  • Ding L-X, Ma C-Q, Li J-W, Robinson PT, Deng X-D, Zhang C, Xu W-C (2011) Timing and genesis of the adakitic and shoshonitic intrusions in the Laoniushan complex, southern margin of the North China Craton: implications for post-collisional magmatism associated with the Qinling Orogen. Lithos 126:212–232

    Article  Google Scholar 

  • Diwu C, Sun Y, Lin C, Liu X, Wang H (2007) Zircon U-Pb ages and Hf isotopes and their geological significance of Yiyang TTG gneisses from Henan province, China. Acta Petrol Sin 23:253–262 (in Chinese with English abstract)

    Google Scholar 

  • Diwu C, Sun Y, Zhao Y, Lai S (2014) Early Paleoproterozoic (2.45–2.20Ga) magmatic activity during the period of global magmatic shutdown: implications for the crustal evolution of the southern North China Craton. Precambrian Res 255:627–640

    Article  Google Scholar 

  • Fan H, Xi Y, Zhao R, Wang Y (1994) Stabel isotope geochemistry of rocks and gold deposits in the Xiongershan area western Henan Province. Contri Geol Miner Resour Res 9:54–64 (in Chinese with English abstract)

    Google Scholar 

  • Fan H-R, Hu F-F, Wilde SA, Yang K-F, Jin C-W (2011) The Qiyugou gold-bearing breccias pipes, Xiong’ershan region, Central China: fluid-inlcusion and stable-isotope evidence for an origin from magmatic fluids. Int Geol Rev 53:25–45

    Article  Google Scholar 

  • Gao J-F, Jackson SE, Dubé B, Kontak DJ, De Souza S (2015) Genesis of the Canadian Malartic, Côté gold, and Musselwhite gold deposits: Insights from LA-ICP-MS element mapping of pyrite. In: Dubé B, Mercier-Langevin P (eds) Targeted geoscience initiative 4: contributions to the understanding of precambrian lode gold deposits and implications for exploration, File 7852, vol Open. Geological Survey of Canada, Canada, pp 157–175

    Google Scholar 

  • Groves DI, Goldfarb RJ, Gebre-Mariam M, Hagemann SG, Robert F (1998) Orogenic gold deposits: Aproposed classification in the context of their crustal distribution and realtionship to other gold deposit types. Ore Geol Rev 13:7–27

    Article  Google Scholar 

  • Guillong M, Hametner K, Reusser E, Wilson SA, Günther D (2005) Preliminary characterisation of new glass reference materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by laser ablation-inductively coupled plasma-mass spectrometry using 193 nm, 213 nm and 266 nm wavelengths. Geostand Geoanal Res 29:315–331

    Article  Google Scholar 

  • Halicz L, Günther D (2004) Quantitative analysis of silicates using LA-ICP-MS with liquid calibration. J Anal At Spectrom 19:1539–1545

    Article  Google Scholar 

  • Han Y, Li X, Zhang S, Zhang Y, Chen F (2007) Single grain Rb-Sr dating of euhedral and cataclastic pyrite from the Qiyugou gold deposit in western Henan, Central China. Chin Sci Bull 52:1820–1826

    Article  Google Scholar 

  • Han Y, Zhang S, Pirajno F, Zhou X, Zhao G, Qü W, Liu S, Zhang J, Liang H, Yang K (2013) U–Pb and Re–Os isotopic systematics and zircon Ce4+/Ce3+ ratios in the Shiyaogou Mo deposit in eastern Qinling, Central China: insights into the oxidation state of granitoids and Mo (Au) mineralization. Ore Geol Rev 55:29–47

  • He Y, Zhao G, Sun M, Xia X (2009) SHRIMP and LA-ICP-MS zircon geochronology of the Xiong’er volcanic rocks: implications for the Paleo-Mesoproterozoic evolution of the southern margin of the North China Craton. Precambrian Res 168:213–222

    Article  Google Scholar 

  • He S, Li Z, Guo D, Wang Y, Zhang C, Guo J, Fan Z (2020) Early mineralization age of the Hengjian uranium deposit: constraints from zircon SIMS U–Pb dating. Acta Geol Sin (Engl Ed) 94:212–213

    Article  Google Scholar 

  • Heinrich CA, Ryan CG, Mernagh TP, Eadington P (1992) Segregation of ore metals between magmatic brine and vapor: a fluid inclusion study using PIXE microanalysis. Econ Geol 87:1566–1583

    Article  Google Scholar 

  • Heinrich CA, Günther D, Audétat A, Ulrich T, Frischknecht R (1999) Metal fractionation between magmatic brine and vapor, determined by microanalysis of fluid inclusions. Geol 27:755–758

    Article  Google Scholar 

  • Hu J, Jiang S-Y, Zhao H-X, Shao Y, Zhang Z-Z, Xiao E, Wang Y-F, Dai B-Z, Li H-Y (2012) Geochemistry and petrogenesis of the Huashan granites and their implications for the Mesozoic tectonic settings in the Xiaoqinling gold mineralization belt, NW China. J Asia Earth Sci 56:276–289

    Article  Google Scholar 

  • Hu X-K, Tang L, Zhang S-T, Santosh M, Spencer CJ, Zhao Y, Cao H-W, Pei Q-M (2019) In situ trace element and sulfur isotope of pyrite constrain ore genesis in the Shapoling molybdenum deposit, east Qinling Orogen, China. Ore Geol Rev 105:123–136

    Article  Google Scholar 

  • Huang D, Nie F, Wang Y, Jiang X (1984) Lead isotope compositions of molybdenum deposits in east Qinling as applied to the problem of ore sources. Mineral Deposita 3:20–28 (in Chinese with English abstract)

    Google Scholar 

  • Huang X-L, Wilde SA, Yang Q-J, Zhong J-W (2012) Geochronology and petrogenesis of gray gneisses from the Taihua complex at Xiong'er in the southern segment of the trans-North China Orogen: implications for tectonic transformation in the early Paleoproterozoic. Lithos 134-135:236–252

    Article  Google Scholar 

  • Jian W, Lehmann B, Mao J, Ye H, Li Z, Zhang J, Zhang H, Feng J, Ye Y (2014) Telluride and Bi-sulfosalt mineralogy of the Yangzhaiyu gold deposit, Xiaoqinling region, Central China. Can Mineral 52:883–898

    Article  Google Scholar 

  • Jian W, Lehmann B, Mao J, Ye H, Li Z, He H, Zhang J, Zhang H, Feng J (2015) Mineralogy, fluid characteristics, and Re-Os age of the late Triassic Dahu Au-Mo deposit, Xiaoqinling region, Central China: evidence for a magmatic-hydrothermal origin. Econ Geol 110:119–145

  • Jiang S, Dai B, Jing Y, Zhao H, Hou M (2009) Jiaodong and Xiaoqinling: two orogenic gold province fromed in different tectonic settings. Acta Petrol Sin 25:2727–2738 (in Chinese with English abstract)

    Google Scholar 

  • Jiang Z, Wang G, Xiao L, Diwu C, Liu J, Wu C (2011) Paleoproterozoic metamorphic P-T-t path and tectonic significance of the Luoning metamorphic complex at the southern terminal of the trans-North China Orogen, Henan Province. Acta Petrol Sin 27:3701–3017 (in Chinese with English abstract)

    Google Scholar 

  • Jin C, Chen WT, Gao X-Y, Li X-C, Bao Z-W, Zhao T-P (2019) Origin of the Wangpingxigou Pb-Zn deposit in east Qinling orogenic belt, China: distal response to the giant Donggou porphyry Mo system? Ore Geol Rev 109:101–116

    Article  Google Scholar 

  • Jochum KP, Willbold M, Raczek I, Stoll B, Herwig K (2005) Chemical characterisation of the usgs reference glasses GSA-1G, GSC-1G, GSD-1G, GSE-1G, BCR-2G, BHVO-2G and BIR-1G using EPMA, ID-TIMS, ID-ICP-MS and LA-ICP-MS. Geostand Geoanal Res 29:285–302

    Article  Google Scholar 

  • Koppers AAP (2002) ArArCALC-software for 40Ar/39Ar age calculations. Comput Geosci 28:605–619

    Article  Google Scholar 

  • Large RR, Maslennikov VV, Fo R, Danyushevsky LV, Chang Z (2007) Multistage sedimentary and metamorphic origin of pyrite and gold in the giant Sukhoi log deposit, Lena gold province, Russia. Econ Geol 102:1233–1267

    Article  Google Scholar 

  • Large RR, Danyushevsky L, Hollit C, Maslennikov V, Meffre S, Gilbert S, Bull S, Scott R, Emsbo P, Thomas H, Singh B, Foster J (2009) Gold and trace element zonation in pyrite using a laser imaging technique: implications for the timing of gold in orogenic and carlin-style sediment-hosted deposits. Econ Geol 104:635–668

    Article  Google Scholar 

  • Lee JY, Marti K, Severinghaus JP, Kawamura K, Yoo HS, Lee JB, Kim JS (2006) A redetermination of the isotopic abundances of atmospheric Ar. Geochim Cosmochim Acta 70:4507–4512

    Article  Google Scholar 

  • Li Y, Ren C (1990) The evolotion of lead isotope in the southern margin of the Huabei platform. J Xi’an Coll Geol 12:1–11 (in Chinese with English Abstract)

    Google Scholar 

  • Li Q, Chen Y, Zhong Z, Li W, Li S, Guo X, Jin B (2002) 40Ar-39Ar ages of the ore-forming processes of the Dongchuang gold deposit in the Xiaoqinling district, China. Geol Rev 48:122–126 (in Chinese with English abstract)

    Google Scholar 

  • Li X-H, Liu Y, Li Q-L, Guo C-H, Chamberlain KR (2009) Precise determination of Phanerozoic zircon Pb/Pb age by multicollector SIMS without external standardization. Geochem Geophys Geosyst 10:Q04010

    Google Scholar 

  • Li J-W, Bi S-J, Selby D, Chen L, Vasconcelos P, Thiede D, Zhou M-F, Zhao X-F, Li Z-K, Qiu H-N (2012a) Giant Mesozoic gold provinces related to the destruction of the North China Craton. Earth Planet Sci Lett 349-350:26–37

    Article  Google Scholar 

  • Li J-W, Li Z-K, Zhou M-F, Chen L, Bi S-J, Deng X-D, Qiu H-N, Cohen B, Selby D, Zhao X-F (2012b) The early cretaceous Yangzhaiyu lode gold deposit, North China Craton: a link between craton reactivation and gold veining. Econ Geol 107:43–79

    Article  Google Scholar 

  • Li N, Carranza EJM, Ni Z, Guo D (2012c) The CO2-rich magmatic-hydrothermal fluid of the Qiyugou breccia pipe, Henan Province, China: implication for breccia genesis and gold mineralization. Geochim Explor Environ Anal 12:147–160

    Article  Google Scholar 

  • Li X, Tang G, Gong B, Yang Y, Hou K, Hu Z, Li Q, Liu Y, Li W (2013) Qinghu zircon: a working reference for microbeam analysis of U-Pb age and Hf and O isotopes. Chin Sci Bull 58:4647–4654

    Article  Google Scholar 

  • Li D, Han J, Zhang S, Yan C, Cao H, Song Y (2015a) Temporal evolution of granitic magmas in the Luanchuan metallogenic belt, east Qinling Orogen, Central China: implications for Mo metallogenesis. J Asia Earth Sci 111:663–680

    Article  Google Scholar 

  • Li N, Chen Y-J, Santosh M, Pirajno F (2015b) Compositional polarity of Triassic granitoids in the Qinling Orogen, China: implication for termination of the northernmost paleo-Tethys. Gondwana Res 27:244–257

    Article  Google Scholar 

  • Li N, Chen YJ, McNaughton NJ, Ling XX, Deng XH, Yao JM, Wu YS (2015c) Formation and tectonic evolution of the khondalite series at the southern margin of the North China Craton: Geochronological constraints from a 1.85-Ga Mo deposit in the Xiong’ershan area. Precambrian Res 269:1–17

    Article  Google Scholar 

  • Li Z-K, Bi S-J, Li J-W, Zhang W, Cooke DR, Selby D (2017) Distal Pb-Zn-Ag veins associated with the world-class Donggou porphyry Mo deposit, southern North China craton. Ore Geol Rev 82:232–251

    Article  Google Scholar 

  • Li N, Chen Y-J, Santosh M, Pirajno F (2018) Late Mesozoic granitoids in the Qinling Orogen, Central China, and tectonic significance. Earth-Sci Rev 182:141–173

    Article  Google Scholar 

  • Li S-S, Li L, Li S-R, Santosh M, Yuan M-W, Zhi ZY, Wen Z-H (2019) Physicochemical conditions governing the formation of gold deposits along the southern margin of the North China Craton: a case study from the Chen'er deposit. Geol J 55:5812–5830

    Article  Google Scholar 

  • Li Y, Zhu G, Su N, Xiao S, Zhang S, Liu C, Xie C, Yin H, Wu X (2020) The Xiaoqinling metamorphic core complex: a record of early cretaceous backarc extension along the southern part of the North China Craton. GSA Bull 132:617–637

    Article  Google Scholar 

  • Liu Y, Hu Z, Gao S, Günther D, Xu J, Gao C, Chen H (2008) In situ analysis of major and trace elements of anhydrous minerals by LA-ICP-MS without applying an internal standard. Chem Geol 257:34–43

    Article  Google Scholar 

  • Liu D, Wilde SA, Wan Y, Wang S, Valley JW, Kita N, Dong C, Xie H, Yang C, Zhang Y, Gao L (2009) Combined U–Pb, hafnium and oxygen isotope analysis of zircons from meta-igneous rocks in the southern North China Craton reveal multiple events in the late Mesoarchean–early Neoarchean. Chem Geol 261:140–154

    Article  Google Scholar 

  • Liu Y, Gao S, Hu Z, Gao C, Zong K, Wang D (2010) Continental and oceanic crust recycling-induced melt-peridotite interactions in the trans-North China Orogen: U-Pb dating, Hf isotopes and trace elements in zircons from mantle xenoliths. J Petrol 51:537–571

    Article  Google Scholar 

  • Liu J, Wang Y, Huang S, Wei R, Sun Z, Hu Q, Hao J (2020) The gold occurrence in pyrite and Te–Bi mineralogy of the Fancha gold deposit, Xiaoqinling gold field, southern margin of the North China Craton: implication for ore genesis. Geol J 55:5791–5811

    Article  Google Scholar 

  • Ludwig KR (2012) User’s manual for isoplot 3.75: a geochronological toolkit for Microsoft excel. Berkeley geochronology center, California

    Google Scholar 

  • Mao J, Goldfarb R, Zhang Z, Xu W, Qiu Y, Deng J (2002) Gold deposits in the Xiaoqinling-Xiong'ershan region, Qinling Mountains, Central China. Mineral Deposita 37:306–325

    Article  Google Scholar 

  • Mao J, Zhang Z, Wang Y, Jia Y, Robert K (2003) Nitrogen isotope and content record of Mesozoic orogenic gold deposits surrounding the North China craton. Sci China (Ser D) 46:231–245

    Google Scholar 

  • Mao J, Zheng R, Ye H, Gao J, Chen W (2006) 40Ar/39Ar dating of fuchsite and sericite from altered rocks close to ore veins in Shagou large-size Ag-Pb-Zn deposit of Xiong'ershan area, western Henan Province, and its significance. Mineral Deposita 25:359–368 (in Chinese with English abstract)

    Google Scholar 

  • Mao JW, Xie GQ, Bierlein F, Qü WJ, Du AD, Ye HS, Pirajno F, Li HM, Guo BJ, Li YF, Yang ZQ (2008) Tectonic implications from Re–Os dating of Mesozoic molybdenum deposits in the east Qinling–Dabie orogenic belt. Geochim Cosmochim Acta 72:4607–4626

  • Mao J-W, Xie G-Q, Pirajno F, Ye H-S, Wang Y-B, Li Y-F, Xiang J-F, Zhao H-J (2010) Late Jurassic-early cretaceous granitoid magmatism in eastern Qinling, Central-Eastern China: SHRIMP zircon U-Pb ages and tectonic implications. Australian J Earth Sci 57:51–78

    Article  Google Scholar 

  • Mao JW, Pirajno F, Xiang JF, Gao JJ, Ye HS, Li YF, Guo BJ (2011) Mesozoic molybdenum deposits in the east Qinling–Dabie orogenic belt: characteristics and tectonic settings. Ore Geol Rev 43:264–293

    Article  Google Scholar 

  • Ni Z-Y, Chen Y-J, Li N, Zhang H (2012) Pb–Sr–Nd isotope constraints on the fluid source of the Dahu Au–Mo deposit in Qinling Orogen, Central China, and implication for Triassic tectonic setting. Ore Geol Rev 46:60–67

  • Ohmoto H (1972) Systematics of sulfur and carbon isotopes in hydrothermal ore deposits. Econ Geol 67:551–578

    Article  Google Scholar 

  • Palenik CS, Utsunomiya S, Reich M, Kesler SE, Wang L, Gwing RC (2004) “invisible” gold revealed: direct imaging of gold nanoparticles in a Carlin-type deposit. Am Mineral 89:1359–1366

    Article  Google Scholar 

  • Qi N, Wang P, Chen Y, Xu Q, Fang J, Zhou Z, Yan J, Deng K (2019a) Ore geology and fluid inclusion constraints on the origin of the 189# deposit in Qiyugou gold orefield, Henan Province. Geotecton Metallog 43:558–574 (in Chinese with English abstract)

    Google Scholar 

  • Qi N, Wang P, Yu J, Chen Y-J (2019b) Geochronology and origin of the Qi189 porphyry gold deposit in Qiyugou Orefield, Qinling Orogen, China. Ore Geol Rev 114:103121

    Article  Google Scholar 

  • Qiang S, Bi S, Deng X, Guo L, Li J (2013) Monazite U-Th-Pb ages of the Qinnan gold deposit, Xiaoqinling district: implications for regional metallogenesis and tectonic setting. Earth Sci J China Univ Geosci 38:43–56 (in Chinese with English abstract)

    Google Scholar 

  • Ren Z (2012) Mineralization characteristic and genesis of the Fancha and Yisishan gold deposit in the eastern Xiaoqinling district. Dissertation, China University of Geosciences (in Chinese)

  • Seal RR (2006) Sulfur isotope geochemistry of sulfide minerals. Rev Mineral Geochem 61:633–677

    Article  Google Scholar 

  • Shao K, Wang B, Wu X, Li S, Luan W, Yang Z (1992) Study of geological condition for the formation of explosive breccia gold deposits in Qiyugou area and targets for further exploration. J Hebei Coll Geol 15:105–195 (in Chinese)

    Google Scholar 

  • Sillitoe RH, Thompson JFH (1998) Intrusion–related vein gold deposits: types, tectono-magmatic settings and difficulties of distinction from orogenic gold deposits. Resour Geol 48:237–250

    Article  Google Scholar 

  • Sláma J, Košler J, Condon DJ, Crowley JL, Gerdes A, Hanchar JM, Horstwood MSA, Morris GA, Nasdala L, Norberg N, Schaltegger U, Schoene B, Tubrett MN, Whitehouse MJ (2008) Plešovice zircon — a new natural reference material for U–Pb and Hf isotopic microanalysis. Chem Geol 249:1–35

    Article  Google Scholar 

  • Steiger RH, Jäger E (1977) Subcommission on geochronology: convention on the use of decay constants in geo- and cosmochronology. Earth Planet Sci Lett 36:359–362

    Article  Google Scholar 

  • Su W, Zhang H, Hu R, Ge X, Xia B, Chen Y, Zhu C (2012) Mineralogy and geochemistry of gold-bearing arsenian pyrite from the Shuiyindong Carlin-type gold deposit, Guizhou, China: implications for gold depositional processes. Mineral Deposita 47:563–662

    Article  Google Scholar 

  • Tang K-F (2014) Characteristics, genisis, and geodynamic setting of representative gold deposit in the Xiong’ershan district, southern margin of the North China carton. representative gold deposit in the Xiong'ershan district, southern margin of the North China carton.

  • Tang K-F, Li J-W, Selby D, Zhou M-F, Bi S-J, Deng X-D (2013) Geology, mineralization, and geochronology of the Qianhe gold deposit, Xiong'ershan area, southern North China Craton. Mineral Deposita 48:729–747

    Article  Google Scholar 

  • Tang L, Hu X-K, Santosh M, Zhang S-T, Spencer CJ, Jeon H, Zhao Y, Cao H-W (2019) Multistage processes linked to tectonic transition in the genesis of orogenic gold deposit: a case study from the Shanggong lode deposit, east Qinling, China. Ore Geol Rev 111:102998

    Article  Google Scholar 

  • Thomas HV, Large RR, Bull SW, Maslennikov V, Berry RF, Fraser R, Froud S, Moye R (2011) Pyrite and pyrrhotite textures and composition in sediments, laminated quartz veins, and reefs at Bendigo gold mine, Australia: insights for ore genesis. Econ Geol 106:1–31

    Article  Google Scholar 

  • Thornton SF, Baker MK, Bottrell SH, Rofle SA, McNamee P, Forrest F, Duffield P, Willson RD, Fairburn AW, Cieslak LA (2014) Enhancement of in situ biodegradation of organic compounds in groundwater by targeted pump and treat intervention. Appl Geochem 48:28–40

    Article  Google Scholar 

  • Tian Y, Ye H, Mao J, Wang X, Jian W, Wang P, Ke C, Zhang X (2019) Geochronology and geochemistry of the Dianfang gold deposit, western Henan Province, Central China: implications for mineral exploration. Ore Geol Rev 111:102967

    Article  Google Scholar 

  • Wan L, Chen B (2017) Analysis of the metallogenic system of Qiyugou subvolcanic porphyry gold deposit and its prospecting significance. Gold 2:24–29 (in Chinese with English abstract)

    Google Scholar 

  • Wan Y, Wilde SA, Liu D, Yang C, Song B, Yin X (2006) Further evidence for ∼1.85 Ga metamorphism in the central zone of the North China Craton: SHRIMP U–Pb dating of zircon from metamorphic rocks in the Lushan area, Henan Province. Gondwana Res 9:189–197

    Article  Google Scholar 

  • Wang S (1983) Age determinations of 40Ar-40K, 40Ar-39Ar and radiogenic 40Ar released characteristics on K-Ar geostandards of China. Sci Geol Sin 4:315–323 (in Chinese with English abstract)

    Google Scholar 

  • Wang Y, Mao J, Lu X (2001) 40Ar-39Ar dating and geochronological constraints on the ore-forming epoch of the Qiyugou gold deposit in Songxian county, Henan Province. Geol Rev 47:551–555 (in Chinese with English abstract)

    Google Scholar 

  • Wang Y, Mao J, Lu X, Ye A (2002) 40Ar-39Ar dating and geological implication of auriferous altered rocks from the middle-deep section of Q875 gold quartz vein in Xiaoqinling area Henan China. Chin Sci Bull 47:1750–1755

    Article  Google Scholar 

  • Wang X-L, Jiang S-Y, Dai B-Z (2010) Melting of enriched Archean subcontinental lithospheric mantle: evidence from the ca. 1760 Ma volcanic rocks of the Xiong’er group, southern margin of the North China Craton. Precambrian Res 182:204–216

    Article  Google Scholar 

  • Wang C, He X, Yan C, Lü W, Sun W (2013) Ore geology, and H, O, S, Pb, Ar isotopic constraints on the genesis of the Lengshuibeigou Pb-Zn-Ag deposit, China. Geosci J 17:197–210

    Article  Google Scholar 

  • Wang J, Zhu L, Guo B, Zheng J, Jiang H, Xiong X (2015) Characteristics of Sr–Nd and Pb isotopic composition and its geological significance of granitic plutons in the Huashan, Laoniushan and Heyu area at the southern margin of North China carton. J Mineral Petrol 35:63–72 (in Chinese with English Abstract)

    Google Scholar 

  • Wang C, Chen L, Bagas L, Lu Y, He X, Lai X (2016a) Characterization and origin of the Taishanmiao aluminous A-type granites: implications for early cretaceous lithospheric thinning at the southern margin of the North China Craton. Int J Earth Sci 105:1563–1589

    Article  Google Scholar 

  • Wang C, Lu Y, He X, Wang Q, Zhang J (2016b) The Paleoproterozoic diorite dykes in the southern margin of the North China Craton: insight into rift-related magmatism. Precambrian Res 277:26–46

    Article  Google Scholar 

  • Wang C, He X, Carranza EJM, Cui C (2019) Paleoproterozoic volcanic rocks in the southern margin of the North China Craton, Central China: implications for the Columbia supercontinent. Geosci Front 10:1543–1560

    Article  Google Scholar 

  • Wang P, Jian W, Mao J-W, Ye H-S, Chao W-W, Tian Y-F, Yan JM (2020a) Geochronology and fluid source constraints of the Songligou gold-telluride deposit, western Henan Province, China: analysis of genetic implications. Resour Geol 70:169–187

    Article  Google Scholar 

  • Wang P, Mao J, Ye H, Jian W, Chen X, Tian Y, He S, Yan J, Wu S, Wan L (2020b) The Qiyugou Au orefield — an intrusion-related gold system in the eastern Qinling ore belt, China: constraints from SIMS zircon U-Pb, molybdenite Re-Os, sericite 40Ar-39Ar geochronology, in-situ S-Pb isotopes, and mineralogy. Ore Geol Rev 124:103636

  • Whitney DL, Evans BW (2010) Abbreviation for names of rock-forming minerals. Am Mineral 95:185–187

    Article  Google Scholar 

  • Williams-Jones AE (2005) 100th anniversary special paper: vapor transport of metals and the formation of magmatic-hydrothermal ore deposits. Econ Geol 100:1287–1312

    Article  Google Scholar 

  • Wilson SA, Ridley WI, Koenig AE (2002) Development of sulfide calibration standards for the laser ablation inductively-coupled plasma mass spectrometry technique. J Anal At Spectrom 17:406–409

    Article  Google Scholar 

  • Wood SA (1998) Calculation of activity-activity and log fO2-pH diagrams. In: Richards JP, Larson PB (eds) Techniques in hydrothermal ore deposits geology, vol 10. Society of Economic Geologists, Inc., Reviews in Economic Geology, pp 81–96

    Google Scholar 

  • Wu Z, Sun X, Xu H, Konishi H, Wang Y, Wang C, Dai Y, Deng X, Yu M (2016) Occurrences and distribution of “invisible” precious metals in sulfide deposits from the Edmond hydrothermal field, central Indian ridge. Ore Geol Rev 79:105–132

    Article  Google Scholar 

  • Wu Y-F, Li J-W, Evans K, Koenig AE, Li Z-K, O’Brien H, Lahaye Y, Rempel K, Hu S-Y, Zhang Z-P, Yu J-P (2018) Ore-forming processes of the Daqiao epizonal orogenic gold deposit, west Qinling Orogen, China: constraints from textures, trace elements, and sulfur isotopes of pyrite and marcasite, and raman spectroscopy of carbonaceous material. Econ Geol 113:1093–1132

    Article  Google Scholar 

  • Xie G, Mao J, Li R, Ye H, Zhang Y, Wan Y, Li H, Gao J, Zheng R (2007) SHRIMP zircon U-Pb dating for volcanic rocks of the Daying formation from Baofeng basin in eastern Qinling, China and its implications. Acta Petrol Sin 23:2387–2396 (in Chinese with English abstract)

    Google Scholar 

  • Xiong S-F, Jiang S-Y, Zhao K-D, Ma Y, Chen Q-Z, Jiang M-R (2019) Gold distribution and source of the J4 gold-bearing breccia pipe in the Qiyugou district, North China Craton: constraints from ore mineralogy and in situ analysis of trace elements and S-Pb isotopes. Ore Geol Rev 105:514–536

    Article  Google Scholar 

  • Xu X, Griffin WL, Ma X, O’Reilly SY, He Z, Zhang C (2009) The Taihua group on the southern margin of the North China craton: further insights from U–Pb ages and Hf isotope compositions of zircons. Mineral Petrol 97:43–59

    Article  Google Scholar 

  • Yao J, Zhao T, Li J, Sun Y, Yuan Z, Chen W, Han J (2009) Molybdenite Re-Os age and zircon U-Pb age and Hf isotope geochemistry of the Qiyugou gold deposit, Henan Province. Acta Petrol Sin 25:374–384 (in Chinese with English abstract)

  • Ye H (2006) The Mesozoic tectonic evolution and Pb-Zn-Ag metallogey in the south margin of North China craton. Dissertation, Chinese Academy of Geological Sciences (in Chinese)

  • Ye H, Mao J, Li Y, Guo B, Zhang C, Liu J, Yan Q, Liu G (2008) SHRIMP zircon U-Pb and molybdenite Re-Os dating for the superlarge Donggou porphyry molybdenum deposit in the east Qinling, China, and its geological implication. Acta Geol Sin 82:134–145

  • Yu X, Liu J, Li C, Chen S, Dai Y (2013) Zircon U–Pb dating and Hf isotope analysis on the Taihua complex: constraints on the formation and evolution of the trans-North China Orogen. Precambrian Res 230:31–44

    Article  Google Scholar 

  • Yuan J-H, Zhan X-C, Fan C-Z, Zhao L-H, Sun D-Y, Jia Z-R, Hu M-Y, Kuai L-J (2012) Quantitative analysis of sulfide minerals by laser ablation-inductively coupled plasma-mass spectrometry using glass reference materials with matrix normalization plus sulfur internal standardization calibration. Chin J Anal Chem 40:201–207

    Article  Google Scholar 

  • Zhang J, Zheng Y (1999) Multistage extension and age dating of the Xiaoqining metamorphic core complex Central China. Acta Geol Sin 73:139–147

    Article  Google Scholar 

  • Zhang J, H-s Y, Zhou K, Meng F (2014) Processes of ore genesis at the world-class Yuchiling molybdenum deposit, Henan province, China. J Asia Earth Sci 79:666–681

    Article  Google Scholar 

  • Zhao T, Zhai M, Xia B, Li H, Zhang Y, Wan Y (2004) Zircon U-Pb SHRIMP dating for the volcanic rocks of the Xiong’er group: constraints on the initial formation age of the cover of the North China Craton. Chin Sci Bull 49:2495–2502

    Article  Google Scholar 

  • Zhao H-X, Jiang S-Y, Frimmel HE (2012) A rare Bi-Pb tellurosulfide, PbBi4Te4S3, from the Wenyu gold deposit in the Xiaoqinling gold province, China. Can Mineral 49:1297–1304

    Article  Google Scholar 

  • Zhao S-R, Li JW, Lentz D, Bi S-J, Zhao X-F, Tang K-F (2019a) Discrete mineralization events at the Hongtuling Au-(Mo) vein deposit in the Xiaoqinling district, southern North China Craton: evidence from monazite U-Pb and molybdenite Re-Os dating. Ore Geol Rev 109:413–425

  • Zhao X, Li Z, Zhao S, Bi S, Li J (2019b) Early cretaceous regional-scale magmatic-hydrothermal metallogenic system at the southern margin of the North China carton. Earth Sci 44:52–68 (in Chinese with English abstract)

    Google Scholar 

  • Zhi Z-Y, Li L, Li S-R, Santosh M, Yuan M-W, Alam M (2019) Magnetite as an indicator of granite fertility and gold mineralization: a case study from the Xiaoqinling gold province, North China Craton. Ore Geol Rev 115:103159

    Article  Google Scholar 

  • Zhou Z-J, Chen Y-J, Jiang S-Y, Zhao H-X, Qin Y, Hu C-J (2014) Geology, geochemistry and ore genesis of the Wenyu gold deposit, Xiaoqinling gold field, Qinling Orogen, southern margin of North China Craton. Ore Geol Rev 59:1–20

    Article  Google Scholar 

  • Zhou Z-J, Chen Y-J, Jiang S-Y, Hu C-J, Qin Y, Zhao H-X (2015) Isotope and fluid inclusion geochemistry and genesis of the Qiangma gold deposit, Xiaoqinling gold field, Qinling Orogen, China. Ore Geol Rev 66:47–64

    Article  Google Scholar 

  • Zhu Z-Y, Cook NJ, Yang T, Ciobanu CL, Zhao K-D, Jiang S-Y (2016) Mapping of sulfur isotopes and trace elements in sulfides by LA-(MC)-ICP-MS: potential analytical problems, improvements and implications. Miner 6. https://doi.org/10.3390/min6040110

  • Zhu Z-Y, Jiang S-Y, Ciobanu CL, Yang T, Cook NJ (2017) Sulfur isotope fractionation in pyrite during laser ablation: implications for laser ablation multiple collector inductively coupled plasma mass spectrometry mapping. Chem Geol 450:223–234

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (41972094) and the Geological Survey Project of China (DD20190193).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Huishou Ye.

Ethics declarations

Declaration of interests

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Editorial handling: X. Xu

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary information

ESM 1

Representative LA–ICP–MS time-resolved depth profiles for different generations of pyrite, chalcopyrite, and sphalerite from the Qi191 Au deposit (EPS 3503 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, P., Li, H., Mao, J. et al. Geology and genesis of the Qi191 granite-hosted gold deposit in the southern margin of the North China Craton: constraints from SIMS zircon U–Pb, sericite 40Ar–39Ar, in-situ trace elements, and in-situ S–Pb isotopes. Miner Petrol 115, 343–363 (2021). https://doi.org/10.1007/s00710-021-00741-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00710-021-00741-3

Keywords

Navigation