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Influence of the Fluorinated Aromatic Fragments on the Structures of the Cadmium and Zinc Carboxylate Complexes Using Pentafluorobenzoates and 2,3,4,5-Tetrafluorobenzoates as Examples

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Abstract

A series of the cadmium and zinc carboxylate complexes with anions of pentafluorobenzoic (HРfbz) and 2,3,4,5-tetrafluorobenzoic (HТfbz) acids and N-donor ligands (1,10-phenanthroline (Phen) and quinoline (Quin)), [Cd(Pfbz)2(Phen)]n (I), [Cd(Рfbz)2(Рhen)2]·2MeCN (II), [Zn(H2O)-(Рfbz)2(Рhen)] (III), [Zn2Cd(Рfbz)6(Рhen)2]⋅2C6H6 (IV), [Cd2(H2O)2(Tfbz)4(Рhen)2] (V), [Cd2-(H2O)2(Tfbz)4(Quin)2] (VI), and [Cd(Tfbz)2(Phen)2]⋅HTfbz (VII), is synthesized. The structures of new complexes I–VII are determined by X-ray diffraction analysis (CIF files CCDC nos. 1871300, 2005461, 2005462, 2005464, 2005466, 2005465, and 2005459, respectively). The majority of the synthesized compounds is typical of intramolecular stacking interactions between the coordinated molecules of the aromatic N-donor ligands and fluorinated substituents of the carboxylate anions. These interactions lead to the formation of unusual compounds, which are different in the cases of pentafluorobenzoates and tetrafluorobenzoates, in particular, coordination polymer I and binuclear complexes V and VI with coordinated water molecules. The synthesized zinc and cadmium compounds differ in structure and composition.

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ACKNOWLEDGMENTS

The XRD studies (compounds II–VII), IR spectroscopy, and elemental analyses of the complexes were carried out on the equipment of the Center for Collective Use “Physical Methods of Investigation” at the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences) in terms of the state assignment of the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences) in the area of basic research. The study of the structure of complex I was supported by the Ministry of Science and Higher Education of the Russian Federation using the scientific equipment of the Center of Investigation of Structure of Molecules of the Nesmeyanov Institute of Organoelement Compounds (Russian Academy of Sciences). The authors are grateful to Prof. A.G. Starikov for help in discussion.

Funding

The syntheses and studies of complexes I–III, V, and VI were supported by the Russian Foundation for Basic Research (project no. 18-29-04043), and complexes IV and VII were synthesized and studied in the framework of the state assignment of the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences) in the area of basic research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119992, Moscow, Russia

    M. A. Shmelev, G. N. Kuznetsova, F. M. Dolgushin, Yu. K. Voronina, N. V. Gogoleva, M. A. Kiskin, V. K. Ivanov, A. A. Sidorov & I. L. Eremenko

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    F. M. Dolgushin & I. L. Eremenko

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  1. M. A. Shmelev
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  2. G. N. Kuznetsova
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  3. F. M. Dolgushin
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  4. Yu. K. Voronina
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  5. N. V. Gogoleva
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  6. M. A. Kiskin
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  7. V. K. Ivanov
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  9. I. L. Eremenko
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Correspondence to M. A. Shmelev.

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Translated by E. Yablonskaya

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Shmelev, M.A., Kuznetsova, G.N., Dolgushin, F.M. et al. Influence of the Fluorinated Aromatic Fragments on the Structures of the Cadmium and Zinc Carboxylate Complexes Using Pentafluorobenzoates and 2,3,4,5-Tetrafluorobenzoates as Examples. Russ J Coord Chem 47, 127–143 (2021). https://doi.org/10.1134/S1070328421020068

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