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5-(Methoxymethyl)norbornene-Based Addition Polymer: Synthesis and Gas-Transport Properties

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Abstract

5-(Methoxymethyl)norbornene is synthesized from the commercial 5-norbornene-2-methanol via the Williamson reaction. Its addition polymerization is studied, and conditions for formation of a high molecular weight product with a high yield are determined. The gas-transport properties of the synthesized addition polynorbornene for a wide set of gases (He, H2, O2, N2, CO2, CH4) are investigated. Our data make it possible to infer that the ether group in the side chain of polynorbornenes affects their gas-transport properties. It is shown that the ether group contributes to a reduction in the level of gas permeability and an increase in the selectivity of separation of gas pairs CO2/N2 and CO2/CH4.

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Funding

Generalization and comparison of the data obtained in this study with the results available for epoxidized polymers were performed by R.Yu. Nikiforov and N.A. Belov within the framework of State Assignment for the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences.

This work was supported by the Russian Science Foundation (project no. 19-33-60035).

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Authors and Affiliations

  1. Mendeleev University of Chemical Technology, 125047, Moscow, Russia

    D. A. Alentiev

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    D. A. Alentiev, D. P. Zarezin, M. A. Rudakova, R. Yu. Nikiforov, N. A. Belov & M. V. Bermeshev

Authors
  1. D. A. Alentiev
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  2. D. P. Zarezin
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  3. M. A. Rudakova
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  4. R. Yu. Nikiforov
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  5. N. A. Belov
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  6. M. V. Bermeshev
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Correspondence to D. A. Alentiev.

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Translated by T. Soboleva

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Alentiev, D.A., Zarezin, D.P., Rudakova, M.A. et al. 5-(Methoxymethyl)norbornene-Based Addition Polymer: Synthesis and Gas-Transport Properties. Polym. Sci. Ser. B 63, 68–77 (2021). https://doi.org/10.1134/S1560090421010012

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  • DOI: https://doi.org/10.1134/S1560090421010012

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