Abstract
Recently, the quality of food solar dried has been associated to solar irradiance, irradiation and UV-light. Different materials used as covering materials in direct solar dryers had different optical properties, thus, different quality should be expected in solar food drying. The objective of this study was to compare two direct solar dryers builder with different covering materials: Direct Solar Drying with Poly (methyl methacrylate) (DSD), and Greenhouse Solar Drying with polyethylene (SGD), based on their three aspects: chemical composition, heat-mass transference, economic-environmental effect. Chemical composition was evaluated as the total phenolic compounds (TPC), flavonoids (TF) anthocyanins (TA) and antioxidant activity (AA) of blackberry pulp (Rubus spp). Dehydrated blackberry pulp contains lower TA than raw samples because TA is sensitive to solar irradiation and UV solar irradiation. TPC, TF and AA averages do not show significant differences among all the drying processes. Evaluation of energy and heat transfer in the evaporative and diffusive periods of the drying technologies led to an assessment of the return of investment period for DSD and SGD technologies for different power sources. The results suggest payback periods between 39 and 121 months, considering only the 6 months of harvest duration without using the solar dryers the rest of the year.
Similar content being viewed by others
Data availability
All relevant data are available in this paper.
Abbreviations
- As :
-
Food product surface area (m2)
- Cpds :
-
Heat capacity of the dry solid (J/ (kg °C))
- Cpw :
-
Heat capacity of the water (J/ (kg °C))
- Cpha :
-
Heat capacity of the humid air (J/ (kg °C))
- Dab :
-
Molecular diffusivity of the water in the air (m2/s)
- DAx :
-
Diffusive coefficient (m2/s)
- Deff :
-
Effective moisture diffusivity (m2/s)
- Deff, var :
-
Variable effective moisture diffusivity (m2/s)
- hH :
-
Heat transfer coefficient (W/m2 K)
- hm :
-
Mass transfer coefficient (kg/m2 s)
- Iin :
-
Solar irradiance inside of the greenhouse dryer (W/m2)
- k a :
-
Air thermal conductivity (W/m2 K)
- l:
-
Characteristic length (m)
- l0 :
-
Sample thickness (m)
- MR:
-
Moisture content ratio (Dimensionless)
- mp :
-
Mass of the product (kg)
- mds :
-
Mass of dry solid (kg)
- qc :
-
Thermal energy transferred by convection (MJ)
- qs :
-
Energy loss due conduction heat (MJ)
- qv :
-
Thermal energy required for water evaporation (MJ)
- t:
-
Time (min)
- T:
-
Temperature (K)
- Ta :
-
Air drying temperature (K)
- Ts :
-
Temperature of the food sample (K)
- va :
-
Air velocity (m/s)
- Vair, in :
-
Air velocity inside the greenhouse dryer (m/s)
- X(t) :
-
Moisture content at any time (kgwater/kgdried solid)
- Xe :
-
Moisture content at the equilibrium (kgwater/kgdried solid)
- X0 :
-
Initial moisture content (kgwater/kgdried solid)
- α:
-
Absorptance the food product
- λ:
-
Latent heat of vaporization (kJ/kg)
- Ø:
-
Diameter (m)
- μ:
-
Viscosity (kg/m s)
- ρ:
-
Density (kg/m3)
- a:
-
Dry air
- Ex:
-
Experimental
- ha:
-
Humid air
- o:
-
Initial
- p:
-
Food product
- s:
-
Surface of the product
- Th:
-
Theoretical
- w:
-
Water
- ex:
-
Experimental
- Fo:
-
Fourier number
- Gr:
-
Grashof number
- \( \overline{\mathrm{Nu}} \) :
-
Nusselt number
- Pr:
-
Prandtl number
- Re:
-
Reynolds number
- Sc:
-
Schmidt number
- \( \overline{\mathrm{Sh}} \) :
-
Sherwood number
References
SIAP. (2019). Servicio de Información Agroalimentaria y Pesquera | Gobierno | gob.mx. Expectativas Agroalimentarias 2019
FAOSTAT (2019) FAOSTAT statistics database. In FAOSTAT Statistics Database - Food and Agriculture Organization of the United Nations https://doi.org/10.1002/embj.201488027
Fernandes L, Casal S, Pereira JA, Saraiva JA, Ramalhosa E (2017) Edible flowers: a review of the nutritional, antioxidant, antimicrobial properties and effects on human health. J Food Compos Anal 60:38–50. https://doi.org/10.1016/J.JFCA.2017.03.017
Kaume L, Howard LR, Devareddy L (2012) The blackberry fruit: a review on its composition and chemistry, metabolism and bioavailability, and health benefits. J Agric Food Chem. https://doi.org/10.1021/jf203318p
Cho MJ, Howard LR, Prior RL, Clark JR (2004) Flavonoid glycosides and antioxidant capacity of various blackberry, blueberry and red grape genotypes determined by high-performance liquid chromatography/mass spectrometry. J Sci Food Agric 84(13):1771–1782. https://doi.org/10.1002/jsfa.1885
Gu L, Kelm MA, Hammerstone JF, Beecher G, Holden J, Haytowitz D, Gebhardt S, Prior RL (2004) Concentrations of Proanthocyanidins in common foods and estimations of Normal consumption. J Nutr. https://doi.org/10.1093/jn/134.3.613
Connor AM, Finn CE, Alspach PA (2005) Genotypic and environmental variation in antioxidant activity and total phenolic content among blackberry and hybridberry cultivars. J Am Soc Horticultural Sci. https://doi.org/10.21273/jashs.130.4.527
Fan-Chiang H-J, Wrolstad RE (2006) Anthocyanin pigment composition of blackberries. J Food Sci. https://doi.org/10.1111/j.1365-2621.2005.tb07125.x
Frohnmeyer H, Staiger D (2003) Ultraviolet-B radiation-mediated responses in plants. Balancing damage and protection. Plant Physiology 133(4):1420 LP–1421428
Hatier J-HB, Gould KS (2009) Anthocyanin function in vegetative organs. In: Winefield C, Davies K, Gould K (eds) Anthocyanins: Biosynthesis, Functions, and Applications (pp. 1–19). Springer, New York. https://doi.org/10.1007/978-0-387-77335-3_1
López-Ortiz A, Méndez-Lagunas LL, Delesma C, Longoria A, Escobar J, Muñiz J (2020) Understanding the drying kinetics of phenolic compounds in strawberries: an experimental and density functional theory study. Innovative Food Sci Emerg Technol 60:102283. https://doi.org/10.1016/j.ifset.2019.102283
Fabani MP, Baroni MV, Luna L, Lingua MS, Monferran MV, Paños H, Tapia A, Wunderlin DA, Feresin GE (2017) Changes in the phenolic profile of Argentinean fresh grapes during production of sun-dried raisins. J Food Compos Anal. https://doi.org/10.1016/j.jfca.2017.01.006
Acosta-Montoya Ó, Vaillant F, Cozzano S, Mertz C, Pérez AM, Castro MV (2010) Phenolic content and antioxidant capacity of tropical highland blackberry (Rubus adenotrichus Schltdl.) during three edible maturity stages. Food Chem 119(4):1497–1501. https://doi.org/10.1016/J.FOODCHEM.2009.09.032
Wang SY, Chen CT, Wang CY (2009) The influence of light and maturity on fruit quality and flavonoid content of red raspberries. Food Chem 112(3):676–684. https://doi.org/10.1016/j.foodchem.2008.06.032
Morales Arellano, Y., & Cantillo Sánchez, E. (2017). Red de comercialización de zarzamora en Los Reyes, MichoacánTrade network of blackberry fruit in Los Reyes, Michoacan. In COMMERCIUM PLUS (Vol. 1, Issue 2). http://revistasacademicas.ucol.mx/index.php/commercium_plus/article/view/1575
Bustos MC, Rocha-Parra D, Sampedro I, De Pascual-Teresa S, León AE (2018) The influence of different air-drying conditions on bioactive compounds and antioxidant activity of berries. J Agric Food Chem 66(11):2714–2723. https://doi.org/10.1021/acs.jafc.7b05395
Méndez-Lagunas L, Rodríguez-Ramírez J, Cruz-Gracida M, Sandoval-Torres S, Barriada-Bernal G (2017) Convective drying kinetics of strawberry (Fragaria ananassa): effects on antioxidant activity, anthocyanins and total phenolic content. Food Chem 230:174–181. https://doi.org/10.1016/J.FOODCHEM.2017.03.010
López J, Vega-Gálvez A, Torres MJ, Lemus-Mondaca R, Quispe-Fuentes I, Di Scala K (2013) Effect of dehydration temperature on physico-chemical properties and antioxidant capacity of goldenberry (Physalis peruviana L.). Chilean J Agric Res 73(3):293–300. https://doi.org/10.4067/S0718-58392013000300013
Madrau MA, Piscopo A, Sanguinetti AM, Del Caro A, Poiana M, Romeo FV, Piga A (2009) Effect of drying temperature on polyphenolic content and antioxidant activity of apricots. Eur Food Res Technol 228(3):441–448. https://doi.org/10.1007/s00217-008-0951-6
Satanina V, Kalt W, Astatkie T, Havard P, Martynenko A (2014) Comparison of anthocyanin concentration in blueberries processed using Hydrothermodynamic technology and conventional processing technologies. J Food Process Eng 37(6):609–618. https://doi.org/10.1111/jfpe.12117
Nair PK, Espinosa-Santana AL, Guerrero-Martínez L, López-Ortiz A, Nair MTS (2020) Prospects toward UV-blue filtered solar drying of agricultural farm produce using chemically deposited copper chalcogenide thin films on cellular polycarbonate. Sol Energy 203:123–135. https://doi.org/10.1016/j.solener.2020.04.012
Lakshmi DVN, Muthukumar P, Ekka JP, Nayak PK, Layek A (2019) Performance comparison of mixed mode and indirect mode parallel flow forced convection solar driers for drying Curcuma zedoaria. J Food Process Eng 42(4). https://doi.org/10.1111/jfpe.13045
Castillo Téllez M, Pilatowsky Figueroa I, Castillo Téllez B, López Vidaña EC, López Ortiz A (2018) Solar drying of Stevia (Rebaudiana Bertoni) leaves using direct and indirect technologies. Sol Energy 159. https://doi.org/10.1016/j.solener.2017.11.031
Román-Roldán N, López-Ortiz A, Ituna-Yudonago J, García-Valladares O, Pilatowsky-Figueroa I (2019) Computational fluid dynamics analysis of heat transfer in a greenhouse solar dryer “chapel-type” coupled to an air solar heating system. Energy Sci Eng. https://doi.org/10.1002/ese3.333
Altuglas International. (2016) Plexiglas optical and transmission characteristics 1
Kaveh M, Taghinezhad E, Aziz M (2020) Effects of physical and chemical pretreatments on drying and quality properties of blackberry ( Rubus spp.) in hot air dryer. Food Science & Nutrition 8(7):3843–3856. https://doi.org/10.1002/fsn3.1678
Von TJ, Mabry KRM u MBT (1971) The Systematic Identification of Flavonoids. Von T. J. Mabry, K. R. Markham und M. B. Thomas. 354 S. mit 325 Abb., Springer-Verlag Berlin – Heidelberg – New York 1970, Preis: DM 98. Arch Pharm. https://doi.org/10.1002/ardp.19713040918
Zhishen J, Mengcheng T, Jianming W (1999) The determination of flavonoid contents in mulberry and their scavenging effects on superoxide radicals. Food Chem. https://doi.org/10.1016/S0308-8146(98)00102-2
Lee J, Durst RW, Wrolstad RE (2005) Determination of total monomeric anthocyanin pigment content of fruit juices, beverages, natural colorants, and wines by the pH differential method: collaborative study. J AOAC Int
Brand-Williams W, Cuvelier ME, Berset C (1995) Use of a free radical method to evaluate antioxidant activity. LWT Food Sci Technol 28(1):25–30. https://doi.org/10.1016/S0023-6438(95)80008-5
Sandoval Torres S, Allier González AL (2015) Linear and nonlinear drying behavior in tuberous crop slices. Dry Technol 33(5):559–569. https://doi.org/10.1080/07373937.2014.955919
Fu BA, Chen MQ, Li QH, Song JJ (2018) Non-equilibrium thermodynamics approach for the coupled heat and mass transfer in microwave drying of compressed lignite sphere. Appl Therm Eng 133:237–247. https://doi.org/10.1016/j.applthermaleng.2018.01.036
Zecchi B, Gerla P (2020) Effective diffusion coefficients and mass flux ratio during osmotic dehydration considering real shape and shrinkage. J Food Eng 274:109821. https://doi.org/10.1016/j.jfoodeng.2019.109821
Koua BK, Koffi PME, Gbaha P (2019) Evolution of shrinkage, real density, porosity, heat and mass transfer coefficients during indirect solar drying of cocoa beans. J Saudi Soc Agric Sci 18(1):72–82. https://doi.org/10.1016/j.jssas.2017.01.002
Farid M (2019) Heat and mass transfer in food processing. https://doi.org/10.1016/B978-0-12-814803-7.00017-8
Frisch HL (1970) Diffusion in polymers edited by J. Crank and G. S. Park, Academic Press, London and New York, 1968; 452 pg. J Appl Polym Sci 14(6):1657. https://doi.org/10.1002/app.1970.070140623
Karathanos VT, Villalobos G, Saravacos GD (1990) Comparison of two methods of estimation of the effective moisture diffusivity from drying data. J Food Sci. https://doi.org/10.1111/j.1365-2621.1990.tb06056.x
López-Ortiz A, Gallardo-Brígido JC, Silva-Norman A, Pilatowsky-Figueroa I, García-Valladares O, Rodríguez-Ramírez J (2018a) Moisture content modeling and effective moisture diffusivity determination during convective solar drying of blackberry (rubus spp) and basil (Ocimum basilicum L.). IDS’2018 – 21st International Drying Symposium, València, Spain, 11-14 September 2018, 11–14. https://doi.org/10.4995/ids2018.2018.7841
López-Ortiz A, Rodríguez-Ramírez J, Méndez-Lagunas LL, Martynenko A, Pilatowsky-Figueroa I (2018b) Non-isothermal drying of garlic slices (Allium sativum, L.): wave period and initial temperature of the heating/cooling effect. Food Bioprod Process 111:83–92. https://doi.org/10.1016/j.fbp.2018.06.005
Perry RH, Green DW (2004) Perrys’ chemical engineers’ handbook 7th. In Mcgraw-Hill/Interamericana editores, S.A. de C.V. https://doi.org/10.1036/0071511245
Serth RW, Lestina TG (2014) Process heat transfer: principles, applications and rules of thumb: second edition. In Process Heat Transfer: Principles, Applications and Rules of Thumb: Second Edition https://doi.org/10.1016/C2011-0-07242-3
Montgomery DC (2012) Design and analysis of experiments eighth edition. In Design (eighth Edi, Vol. 2). John Wiley & Sons, Inc. https://doi.org/10.1198/tech.2006.s372
Peñarrieta JM, Salluca T, Tejeda L, Alvarado JA, Bergenståhl B (2011) Changes in phenolic antioxidants during chuño production (traditional Andean freeze and sun-dried potato). J Food Compos Anal. https://doi.org/10.1016/j.jfca.2010.10.006
Geankoplis CJ (2003) Transport processes and separation process principles: includes unit operations. In Transport Processes and Separation Process Principles (Includes Unit Operations)
Chua KJ, Chou SK, Ho JC, Mujumdar AS, Hawlader MNA (2000) Cyclic air temperature drying of guava pieces: effects on moisture and ascorbic acid contents. Food Bioproducts Process: Trans Instit Chem Eng Part C 78(2):72–78. https://doi.org/10.1205/096030800532761
Martynenko A, Kudra T (2015) Non-isothermal drying of medicinal plants. Dry Technol 33(13):1550–1559. https://doi.org/10.1080/07373937.2015.1010209
Vagenas GK, Karathanos VT (1993) Prediction of the effective moisture diffusivity in gelatinized food systems. J Food Eng 18(2):159–179. https://doi.org/10.1016/0260-8774(93)90034-H
Sharma GP, Prasad S (2004) Effective moisture diffusivity of garlic cloves undergoing microwave-convective drying. J Food Eng. https://doi.org/10.1016/j.jfoodeng.2004.02.027
Eminoğlu MB, Yegül U, Sacilik K (2019) Drying characteristics of blackberry fruits in a convective hot-air dryer. HortScience 54(9):1546–1550. https://doi.org/10.21273/HORTSCI14201-19
INECC And SEMARNAT (2014) Factores de emisión para los diferentes tipos de combustibles fósiles y alternativos que se consumen en México
PEMEX. (2015). Hoja de datos de seguridad gas natural hds-pemex-tri-sac-9
CRE. (2017) Factor de emisión del sector eléctrico nacional
Banxico (n.d.) Banxico, banco central, Banco de México. Retrieved October 31, 2020, from https://www.banxico.org.mx/. Accessed 31 Oct 2020
Acknowledgments
This study was supported by the IER of the Universidad Nacional Autónoma de México and the CONACyT, Cátedras-CONACyT 352 project. The authors thanks to ESOLMET solar station in the IER-UNAM for the UV and solar irradiance data and IER’s solar drying laboratory for the infrastructure used. We thank Prof. P.K. Nair for enlightening comments on this paper. We thank Laura Guerrero Martínez for the determination of polyethylene optical properties. Also, we thank Iván Román Roldán for the schemes.
Funding
This study was supported by the IER of the Universidad Nacional Autónoma de México and the CONACyT, Cátedras-CONACyT 352 project.
Author information
Authors and Affiliations
Contributions
A. López Ortiz and Octavio García Valladares conceived the experiments, A. López Ortiz and Azucena Silva Norman performed the experiments and A. López Ortiz and Octavio García Valladares analyzed the results. All authors wrote and reviewed the manuscript.
Corresponding author
Ethics declarations
Conflicts of interest/competing interests
All authors declare not conflicts of interest.
Code availability
We do not use any special software for this work.
Additional information
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
López-Ortiz, A., Silva Norman, A. & García Valladares, O. Bioactive compounds conservation and energy-mass analysis in the solar greenhouse drying of blackberry pulps. Heat Mass Transfer 57, 1347–1361 (2021). https://doi.org/10.1007/s00231-021-03039-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00231-021-03039-4