The equilibrium nonlinear stress–stretch relationships for a monodomain main-chain nematic elastomer (MNE) are investigated by varying the angle between the stretching and initial director axes (θ₀). Angle θ₀ has pronounced effects on the ultimate elongation as well as on the width of the low stress plateau regime (Λ_p) during director rotation, whereas θ₀ has no appreciable effect on the plateau stress (σ_p). In the stretching normal to the initial director (θ₀ = 90°), the plateau end exceeds 200% strain. At oblique angles of 90° > θ₀ ≥ 35°, Λ_p decreases with decreasing θ₀, whereas the definite plateau regime vanishes at θ₀ < 24°. Wide-angle X-ray scattering and polarized optical microscopy measurements reveal that the director rotates uniformly in the biased direction for the MNE of θ₀° ≪ 90°, whereas directors rotating clockwise and counterclockwise are coexistent for θ₀ = 90°. Over the entire plateau regime, the MNEs exhibit pure shear deformation characterized by a Poisson's ratio of zero in the direction of the rotation axis. The Λ_p for the corresponding polydomain NE (PNE) undergoing a transition to the monodomain alignment is smaller than that of the MNE of θ₀ = 90°, while the σ_p values for both NEs are almost similar. The semi-soft elasticity concept satisfactorily explains the effects of θ₀ on Λ_p, and the Λ_p value of the PNE, using a single anisotropy parameter which is evaluated from the degree of thermally induced deformation of MNEs.