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Application of Ni-W Sulfide Catalysts Prepared In Situ from Embryonic and Highly Crystalline ZSM-5 Zeolites in Hydrocracking Reaction of 1-Methylnaphthalene

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Abstract

The paper reports the synthesis of embryonic and highly crystalline ZSM-5 zeolites with SiO2/Al2O3 ratios of 50 to 400, as well as the examination and comparative evaluation of their physicochemical properties by XRD, low-temperature nitrogen adsorption/desorption, ammonia TPD, and TEM methods. The Ni-W sulfide catalysts prepared in situ from the embryonic and highly crystalline ZSM-5 were investigated in a hydrocracking reaction of 1-methylnaphthalene (50 atm H2, 380°C, 5 h). The catalytic systems based on embryonic ZSM-5 were found to promote, to a larger extent, the hydrogenation and migration of the methyl group on the naphthalene ring.

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Funding

The reported study was performed within the framework of the state assignment for TIPS RAS.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    V. A. Ostroumova, V. A. Severina & A. L. Maksimov

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  1. V. A. Ostroumova
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  2. V. A. Severina
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  3. A. L. Maksimov
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Correspondence to V. A. Ostroumova.

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Translated from Sovremennye Molekulyarnye Sita. Advanced Molecular Sieves, 2021, Vol. 3, No. 1, pp. 94–104.

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Ostroumova, V.A., Severina, V.A. & Maksimov, A.L. Application of Ni-W Sulfide Catalysts Prepared In Situ from Embryonic and Highly Crystalline ZSM-5 Zeolites in Hydrocracking Reaction of 1-Methylnaphthalene. Pet. Chem. 61, 341–349 (2021). https://doi.org/10.1134/S0965544121030191

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  • DOI: https://doi.org/10.1134/S0965544121030191

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